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Dissertations / Theses on the topic 'Pentacyanoferrate'

Author: Grafiati

Published: 4 June 2021

Last updated: 26 July 2025

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1

Nieh, Chi-Hua. "Study on Oxidase/Peroxidase-based Biosensors with Pentacyanoferrate-bound Polymer." Kyoto University, 2013. http://hdl.handle.net/2433/180512.

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Kyoto University (京都大学)<br>0048<br>新制・課程博士<br>博士(農学)<br>甲第17895号<br>農博第2018号<br>新制||農||1017(附属図書館)<br>学位論文||H25||N4791(農学部図書室)<br>30715<br>京都大学大学院農学研究科応用生命科学専攻<br>(主査)教授加納健司, 教授三芳秀人, 教授小川順<br>学位規則第4条第1項該当

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2

Jin, Victor Xinhua. "Syntheses and characterization of Ã- and ß-cyclodextrin rotaxanes with dinuclear platinum(II) and pentacyanoferrate(II) stoppers." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 2001. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp04/NQ56083.pdf.

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3

Santiago, Marcelo Oliveira. "SÃntese e caracterizaÃÃo de compostos mono e binucleares de rutÃnio e ferro com o LIGANTE 1,3-BIS(3-PIRIDILMETIL)2-TIOURÃIA (BPMT)." Universidade Federal do CearÃ, 1998. http://www.teses.ufc.br/tde_busca/arquivo.php?codArquivo=1420.

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FundaÃÃo de Amparo a Pesquisa do Estado de SÃo Paulo<br>Os complexos mononucleares, formados a partir das reaÃÃes do 1,3-bis(3-piridilmetil)-2-tiourÃia (BPMT) com os Ãons [Ru(NH3)5OH2]2+ e [Fe(CN)5NH3]3-, foram isolados e caracterizados por microanÃlise, espectroscopia eletrÃnica, vibracional na regiÃo do infravermelho, MÃssbauer e por tÃcnicas eletroquÃmicas (Voltametria cÃclica e voltametria de pulso diferencial). Nos complexos de pentaaminas de rutÃnio, foram evidenciadas maiores interaÃÃes de retrodoaÃÃo, dπ(M) → pπ*BPMT, que nos complexos de pentacianoferrato sendo justifi

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4

Winnischofer, Herbert. "Porfirinas pentacianoferrato e estruturas supramoleculares auto-organizadas." Universidade de São Paulo, 2000. http://www.teses.usp.br/teses/disponiveis/46/46134/tde-22062009-085859/.

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No presente trabalho estão descritas a síntese e as propriedades espectroscópicas e eletroquímicas da meso-{tetrakis-(3-piridilpentacianoferrato)} porfirinato e dos materiais do tipo Azul da Prússia, obtidos pela reação de \"auto-formação\" da nova porfirina com íons de metais de transição. Os novos materiais foram caracterizados por espectroscopia de massa, UV -Vis, Infravermelho, Raman ressonante e Mossbauer de 57Fe, cronoamperometria, voltametria cíclica e de pulso diferencial, espectroscopia de impedância eletroquímica e espectroeletroquímica. A PPCF foi obtida através da reação do 3-TPyP

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5

Frin, Karina Passalacqua Morelli. "Propriedades fotoquímicas de alguns complexos de ferro(II) e rênio(I)." Universidade de São Paulo, 2008. http://www.teses.usp.br/teses/disponiveis/46/46134/tde-17052016-143939/.

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Neste trabalho, foram estudadas as propriedades fotoquímica e/ou fotofísica de alguns compostos de coordenação de rênio(l) e ferro(I I). A irradiação dos complexos fac-[Re(CO)3(NN)(trans-L)]+, NN= 4,7-difenil-1,10- fenantrolina (ph2phen) ou 5-cloro-1,10-fenantrolina (Clphen) e L = 1,2-bis(4-piridil)etileno (bpe) ou 4-estirilpiridina (stpy), em acetonitrila ou em filme de poli(metacrilato de metila) (PMMA) resulta em variações espectrais condizentes com a fotoisomerização trans-cis do ligante coordenado. A determinação dos rendimentos quânticos para a fotorreação pela variação espectral resulto

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6

Sai, Jen-Shing, and 施振祥. "Pentacyanoferrate of Sydnone Derivatives." Thesis, 1993. http://ndltd.ncl.edu.tw/handle/14928984590939571158.

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碩士<br>中原大學<br>化學學系<br>81<br>3-甲基及3-苯基雪梨酮五氰鐵錯合物,有很明顯的金屬至配位基之電荷轉移吸收, 分別在 λmax=442nm(3360/莫耳/公分,3-甲基雪梨酮)及λmax= 494nm(9530/莫耳/公分,3-苯基雪梨酮)。 3-甲基及3-苯基雪梨酮五氰鐵錯合物之還原電位分別為 0.67Volts 及 0.65Volts v.s N.H.E.(μ=0.10 M過.blksq.酸鋰, pH=5(acetate)。電化學結果顯示, 3-甲基雪梨酮五氰鐵(Ⅱ)錯合物被氧化成三價時,金屬中心有自雪梨酮 N-2 位置轉移至 C= O 之氧原子的結合異構化現象 , 當Fe(Ⅲ)還原成 Fe(Ⅱ) 時 ,金屬中心又再度回至 N-2 位置, 此為五氰鐵錯合物第一個具結合異構化現象的例子。五氰鐵(Ⅱ)錯合物的取代反應屬解離機構,形成及水離反應速率常數, 在25℃,pH=5,0.10M 過.blksq.酸鋰條件下分別為kf=(5.4±0.2) ×0.01

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7

Wu, Ming-Chu, and 吳明珠. "Pentacyanoferrate(II,III) Complexes of Nucleic Acids." Thesis, 1994. http://ndltd.ncl.edu.tw/handle/46856761573728400342.

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碩士<br>中原大學<br>化學學系<br>82<br>3-,4-羥基▋啶及肌▋五氰鐵二價錯合物可以Fe(CN)5OH23-與過量配位基在水溶液中直接作用而得.在T=25C,pH=5.0(acetate),μ=0.1MLiClO4條件下,3-,4-羥基▋啶及肌▋五氰鐵錯合物分別在λmax=363nm(3960cm-1 M-1),414nm(4360cm-1M- 1)及320nm(1950cm-1M-1)有MLCT吸收.而其三價錯合物則在λmax=503nm( 132cm-1M-1),565nm(500cm-1M-1),497nm(324 cm-1M-1)分別有LMCT吸收.五氰鐵二價錯合物取代反應動力學的結果顯示不論形成或水離反應,均屬解離機構.其中4-羥基▋啶錯合物之形成反應速率較其它配位之錯合物慢約三次冪,乃由於4-羥基▋啶之醇酮異構平衡的影響,而非反應機構的差異, 若考慮羥基▋啶之醇酮異構平衡的因素,則在 T=25C, pH=5.0 ( acetate),μ=0.1MLiClO4條件下,五氰鐵二價

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8

Wu, Ming-Zhu, and 吳明珠. "Pentacyanoferrate (II,III) complexes of nucleic acidszeng." Thesis, 1994. http://ndltd.ncl.edu.tw/handle/64178377235083835165.

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9

LU, GING-BAO, and 呂清保. "Imidazolate bridged binuclear complex of pentacyanoferrate and pentaammineruthenium." Thesis, 1987. http://ndltd.ncl.edu.tw/handle/30460127669012279729.

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碩士<br>中原大學<br>化學研究所<br>75<br>[(CN)FeNONRu (NH)](I) 及[(CN)FeNONRu (NH)(OH)〕(II) 錯合物可由Fe（CN）OH與Ru（NH）Im ／ 直接作用而得，可見光譜：λmax （ε）＝３６３nm（３１００），５７２nm（８０８）及紅外光譜νcn＝２０５０ｃｍ，σ（NH）ym ＝１３１０ｃｍ 的鑑定均顯示混價分子（Ⅱ）屬於定域性，其金屬價數為（Ⅱ）及（Ⅲ）。混價分子（Ⅱ）之水離反應速率的探討，證明錯合經由Fe（Ⅱ）-L鍵結斷裂，其反應速率常數為６．５４×１０sec ，在PH＝１０，μ＝０．１０ＭＬｉＣｌＯ條件下，電化學結果亦顯示，雙核錯合物（Ⅱ）有兩組環路電位波在－０．２０３V 及０．３１２V 分別屬於〔２，２〕→〔２，３〕＋e 及〔２，３〕→〔３，３〕＋e 之氧化電位電化學結果可供我們進一步求得反應〔２，２〕＋〔３，３〕２〔２，３〕

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10

Sun, Bin-Guo, and 孫彬國. "Hydroxypyridine and inosine of pentacyanoferrate (II,III) complexes." Thesis, 1991. http://ndltd.ncl.edu.tw/handle/97369842777031371727.

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11

ZHAO, FENG-XIAN, and 趙鳳仙. "Purine base molecules of pentacyanoferrate (II, III) complexes." Thesis, 1989. http://ndltd.ncl.edu.tw/handle/60349412964402316484.

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碩士<br>中原大學<br>化學研究所<br>77<br>Fe（CN）L （L = guanosine （guo ），aniline （an），xanthosine（xan ），caffeine（caff），cytidine（cyt ），inosine （ino ））可由Fe（CN）OH 與配位基直接作用而得。除了cytidine外，所有錯合物之吸收光譜均屬於A 到 E （１）的d －d 躍遷，吸收位置在４１０－４５０nm之間，而其extinction coefficient 均在~１０M cm  範圍內Fe（CN）－cytidine 錯合物在λ = ３６６nm（εmax = １．３* １０）有一很強的吸收，屬dπ至π^* 之電荷轉移，anili-ne及cytidine之Fe（Ⅱ）錯合物氧化成Fe（Ⅲ）時，在低能量處均有一吸收峰，分別為在λmax = ６６０nm，εmax = １．９３* １０cmM（an ）λ max = ５３３nm，εmax = １．０７* １０M（cyt）此LMCT吸

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12

HUANG, HONG-YI, and 黃弘毅. "Binuclear complexes of pentacyanoferrate and pentaammineruthenium through cyanopyridine." Thesis, 1989. http://ndltd.ncl.edu.tw/handle/01190096471633253641.

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13

YANG, ZHENG-CHAO, and 楊政晁. "Binuclear complexes of pentacyanoferrate and pentaammineruthenium through dicyanobenzene." Thesis, 1989. http://ndltd.ncl.edu.tw/handle/73745322559146972208.

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14

Lin, LuMing, and 林律銘. "Reductions of Pentacyanoferrate(III) Complexes by Ascorbic Acid." Thesis, 2002. http://ndltd.ncl.edu.tw/handle/38557564560232789838.

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碩士<br>東海大學<br>化學系<br>90<br>The reductions of ascorbic acid on Fe(CN)5L2-(L=CN-, 4,4'-bpy) complexes undergo outer-sphere electron transfer mechanism. The rates of the reduction depend greatly on the pH of the solution for the reason that ascorbic acid exists in different forms, namely H2A，HA- and A2-, at various pH values. The kinetic studies of the reactions at [H+]= 0.01~0.10 M and pH=4~9 yield specific rate constants of reduction as k0(H2A)=0.42 ±0.02 (L=CN-), 2.5 ±0.2 (L=4,4'-bpy), k1 (HA-)= (5.2 ±0.1)´102 (L=CN-), (9.6 ±0.1)´103 (L=4,4'-bpy) ; k2 (A2-)= (2.03 ±0.07)´107 (L=CN-) M-1s-1，re

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15

Chen, Mine Hong, and 陳敏鴻. "The Oxitadion of 4-Aminopyridion pentacyanoferrate(II) By Peroxydisulfate." Thesis, 1994. http://ndltd.ncl.edu.tw/handle/73259581320389761517.

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碩士<br>中原大學<br>化學學系<br>82<br>Redox reactions of Fe(CN)5L3- [ L=4-aminopyridine(4-Ampy)、 pyridine(py)、4,4'-bipyridine (4,4'-py)、pyrazine(pz)、N- methyl- pyrazinium(Mpz+) ] with S2O82- according to Eq(1) Fe( CN)5L3- ＋ S2O82- ↹ Fe(CN)5L2- ＋ SO4- ＋ SO42- (1) has been interpreted on the basis of an outer-sphere electron transfer mechanism. The results k1=(2.90±0.02) 1/(sec* M)(4-Ampy )、(0.180±0.003) 1/(sec*M) (py)、(0.141±0.003) 1/(sec*M)(4,4'- bpy)、(0.0568±0.0002) 1/(sec*M)(pz)、(0.0226

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周致祥. "Syntheses,Characterization and Propeties of Sodium[(prydyl-ferrocene)pentacyanoferrate(Ⅱ)]." Thesis, 1997. http://ndltd.ncl.edu.tw/handle/01604521963200088519.

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碩士<br>輔仁大學<br>化學學系<br>85<br>Two binuclear complexs, Sodium (3-pyridyl-ferrocen) pentacyanoferrate(II) and Sodium (4-pyridyl-ferrocen) pentacyanoferrate(II) were synthesized and characterized. MLCT exists in both complexes, in which Fe(II) to 4-pyridyl shifts to longer wave length. As indicated from CV and NIR studies low lying TC orbital in 4-pyridyl play important roles in exhancing electronic coupling between metal centers.

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17

Yvonne-Chen and 陳美玲. "Acid Catalyzed Dissociation of 4-Aminopyridine Complex of Pentacyanoferrate(II)." Thesis, 1999. http://ndltd.ncl.edu.tw/handle/17478563561798867447.

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碩士<br>東海大學<br>化學系<br>87<br>For Fe(CN)5(4-Ampy)3- complex begins to be unstable in the solutions at pH <5 is subjected to the dissociation of the complex. The rates of the dissociation as a function of acid concentration follow the saturation kinetics. The first step of the protonation of the complex which is followed by the dissociation of the prontonated species, The rate law of the reaction is -dFe(II)/dt = (kd*K*[H+]/1+K*[H+])[Fe(II)] For 2.73< pH < 5; K=(1.730.3)*103 kd=0.550.03 sec-1; For pH < 2 K=31.90.7 M-1, kd=4.920.02 sec-1. The results at higher pH values correspond

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18

Te, Chu Wen, and 朱文得. "The Investigation of Pyrazine Bridge Binuclear Complexes of Isonicotinamidetetraammineruthenium and Pentacyanoferrate." Thesis, 2010. http://ndltd.ncl.edu.tw/handle/87693291118630292608.

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碩士<br>東海大學<br>化學系<br>98<br>The binuclear complex trans-(isn)(NH3)4Ru(pz)Fe(CN)5- (I) was prepared by mixing the equimolar of trans-Ru(NH3)4(isn)(pz)2+ and Fe(CN)5OH23- in pH=5 aqueous solution. The mixed valence complex trans-(isn)(NH3)4Ru(pz)Fe(CN)5 (II) was obtained by the oxidation of (I) with one equivalent peroxy disulfate ion. The absorption spectra of I and II both show a MLCT absorption in the visible region with significant bathochromatic shifts as compare to the mononuclear Ru(II) and Fe(II) complexes. The cyclic voltammogram of II exhibits one electron reversible waves with E1/2＝0.5

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19

LIN, ZHANG-SHENG, and 林長昇. "Preparation and characterization of sydnone complexes of pentacyanoferrate(II) and pentaammineruthenium(II)." Thesis, 1991. http://ndltd.ncl.edu.tw/handle/40638759834609415443.

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20

CHEN, WEN-ZHENG, and 陳文徵. "The nuclear magnetic resonance studies of imidazole complexes of pentacyanoferrate (II)/(III)." Thesis, 1987. http://ndltd.ncl.edu.tw/handle/83684959725508472042.

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21

MingHuiLien and 連明惠. "The Investigation of the Redox Reactions between Ascorbic Acid and Pentacyanoferrate(III) Complexes." Thesis, 2004. http://ndltd.ncl.edu.tw/handle/42078847441605534467.

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碩士<br>東海大學<br>化學系<br>92<br>The oxidation of ascorbic acid by [Fe(CN)5L]2‾(L=py, isn) complexes undergoes outer-sphere electron transfer mechanism. The rate of the reduction depends on the pH of the solution for the reason that ascorbic acid exists in different forms, namely H2A, HA‾ and A2‾, at various pH values. The kinetic studies of the reactions at [H+]= 0.01~0.10 M and pH=4~7.5 yield specific rate constants of reduction as k0(H2A)= 1.8 ( L=py ),7.0 (L=isn)；k1(HA-)=1.6×103 ( L=py ),4.5×103 (L=isn)；k2(A2-)=6.5×108 ( L=py ),8.8×108 (L=isn)M-1s-1,respectively at m=0.10 M HClO4/LiClO4 and T=

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22

Cheng, Guan-hao, and 程冠豪. "Kinetic Studies of the Oxidations of Catechols by Pentaammineruthenium(Ⅲ) and Pentacyanoferrate(Ⅲ) Complexes." Thesis, 2009. http://ndltd.ncl.edu.tw/handle/93715181990800957522.

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碩士<br>東海大學<br>化學系<br>97<br>The reactions of 4-methyl catechol and protocatechuic acid with Ru(NH3)5L3+( L= methylpyrazinium, pzCH3+；pyrazine, pz；isonicotinamide, isn ) and Fe(CN)5(py)2-( py= pyridine ) complexes proceed through an outer-sphere electron transfer mechanism. The rate of the reaction decreases with increasing [H+]. The kinetics of the oxidation suggests that the reaction process involves the rate determining one-electron oxidation of the catechols in the forms of H2X (k0), HX－(k1) and X2－(k2) by Ru(NH3)5L3+ and Fe(CN)5(py)2- complexes to form the corresponding semiquinone radicals

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23

Wei, Sky, and 魏世凱. "Kinetic Study of the Ru(II) Catalyzed Oxidation of Pentacyanoferrate(II) Complexes by Peroxydisulfate." Thesis, 1999. http://ndltd.ncl.edu.tw/handle/05376862491965169300.

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碩士<br>東海大學<br>化學系<br>87<br>Abstract The oxidation reactions of Fe(CN)5L3-(L=4-aminopyridine, 3-aminopyridine, pyridine, 4,4-dipyridylammine) complexes by S2O82- were catalyzed upon the addition of a trace amount of Ru(NH3)5L2+ (L=pz, py or dcb) complex, and the reaction becomes zero-order in Fe(II). The reaction time is ~102 folds faster than the simple Fe(CN)5L3-- S2O82- system. The mechanism of this Ru(II) catalyzed redox reaction is proposed as Ru(NH3)5L2+ + 1/2 S2O82- -->Ru(NH3)5L3+ + SO42- Ru(NH3)5L3+ + Fe(CN)5L3- -->Ru(NH3)5L2+ + Fe(CN)5L2-

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24

JIAN, QIU-FEN, and 簡秋芬. "The reactions of (ethylenediaminetetraacetato) cobaltate(III) with 4,4'-dipyridylamine pentacyanoferrate(II) and pentaammineruthenium(II) complexes." Thesis, 1991. http://ndltd.ncl.edu.tw/handle/05557776991758135866.

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碩士<br>中原大學<br>化學研究所<br>79<br>Fe（CN） L -（L=4,4'-dipyridylamine ）及Ru（NH ） L （L＝4,4'-dipyridyla- mine, 4-及3-aminopyridine ）與Coedta的外圈電子轉移反應: ML ＋Coedta ML ＋Coedta ……………(1) （M＝Fe（CN）或Ru（NH ））其反應速率式為Rate＝k Q 〔Ru（NH ） L 〕〔Coedta 〕／1＋Q 〔Coedta 〕。在25℃ pH＋8（tris）及離子強度為0.1M情況下, 對Ru（Ⅱ）—Co（Ⅲ）系統而言，所得動力學結果為，k ＝93.9±0.7、694±14 及56.7±0.5S 及Q ＝10.6±0.7 、3.7±0.7及6.4±0.8M 分別屬於dpa, 4- 及3-Aminopyridine 配位, 對Fe（Ⅱ） —Co（Ⅲ）系統而言，由於Q 較小, 反應速率式簡化為Rate＝kf〔Fe（CN） L 〕

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25

Pan, Amanda, and 潘家穎. "The Kinetic Studies of the Outer-Sphere Electron Transfer Reaction between Protocatechuic Acid and Pentacyanoferrate(III) Complexes." Thesis, 2006. http://ndltd.ncl.edu.tw/handle/42768263851637946221.

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碩士<br>東海大學<br>化學系<br>95<br>The reductions of [Fe(CN)5L]2-(L=4-cyano-pyridine, isonicotinamide, 4,4’-bipyridine, pyridine, pyrazine)complexes by protocatechuic acid have been subjected to a detailed kinetic study in the range of pH 5 – 9. The rate law of the reaction is interpreted as a rate determining reaction between Fe(III) complexes and the protocatechuic acid in the form of H2cat-COO-(k1), Hcat-COO2-(k2), and cat-COO3-(k3), depending on the pH of the solution, follow by a rapid scavenge of the protocatechuic acid radicals by Fe(III) complex. With given Ka1, Ka2, and Ka3, the rate constant

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Shann, Yuan-Rong, and 單媛蓉. "Ionic Strength Dependency upon the Oxidation Reaction of Complexes of Pentaammineruthenium(Ⅱ) and Pentacyanoferrate(Ⅱ) by Peroxydisulfate Ion." Thesis, 2003. http://ndltd.ncl.edu.tw/handle/30514430640707246549.

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碩士<br>東海大學<br>化學系<br>91<br>Kinetic studies of the oxidations of Fe(CN)5L3- and Ru(NH3)5L2+ (L= pyridine( py )、isonicotinamide( isn )、4-aminopyridine( 4-ampy ) complexes by peroxydisulfate ion (S2O82-) have been carried out at different ionic strengths. For Fe(CN)5L3- complexes, rate constants increase with increasing ionic strengths. On the contrary, rate constants decrease with increasing ionic strengths for Ru(NH3)5L2+. Linear relationship was observed for the plots, logk vs. , in agreement with Debye-Hückel theory. The rate constants of oxidation at μ＝0 can be obtained from the intercepts

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