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Relevant bibliographies by topics / Phenyl isocyanate

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Academic literature on the topic 'Phenyl isocyanate'

Author: Grafiati

Published: 4 June 2021

Last updated: 1 February 2022

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Journal articles on the topic "Phenyl isocyanate"

1

Xiao, Hong, Han X. Xiao, Kurt C. Frisch, and Nelson Malwitz. "Kinetic studies of the reactions between isocyanates and carboxylic acids." High Performance Polymers 6, no. 3 (1994): 235–39. http://dx.doi.org/10.1088/0954-0083/6/3/006.

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Reaction kinetic studies between isocyanates and carboxylic acids were undertaken to evaluate the kinetic parameters. Various isocyanates (phenyl isocyanate, cyclohexyl isocyanate) and carboxylic acids (acetic acid, n-butyric acid, isobutyric acid, dimethylbutyric acid and benzoic acid) were used to study the kinetics of the reactions at different temperatures and in different solvents. It was found that these reactions followed the rate law of second-order reaction. From the Arrhenius plot, the activation energies of these reactions were computed.

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Habibi, Davood, Mohammad Ali Zolfigol, and Maliheh Safaee. "Synthesis of 1,4-Dihydropyridines Bearing a Carbamate Moiety on the 4-Position." Journal of Chemistry 2013 (2013): 1–6. http://dx.doi.org/10.1155/2013/495982.

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A good range of 1,4-dihydropyridines bearing a carbamate moiety on the 4-position were synthesized from the primary reaction of different hydroxyaldehydes with phenyl isocyanates and the subsequent reaction of the obtained carbamates with methyl acetoacetate in the presence of ammonium fluoride. When phenyl isothiocyanate was used in place of phenyl isocyanate in the same condition, the reaction did not take place.

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3

Kaenhin, Lalita, Pairote Klinpituksa, Adisai Rungvichaniwat, and Jean Francois Pilard. "Waterborne Polyurethane: Effect of Functional Groups in Aromatic Isocyanate and the Chain Length of Hydroxyl Terminated Natural Rubber." Advanced Materials Research 415-417 (December 2011): 2032–35. http://dx.doi.org/10.4028/www.scientific.net/amr.415-417.2032.

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Waterborne polyurethane (WPU) has its main applications in coatings and adhesives. Compared with the competing PU products from solvent-based processes, it has a more environmentally friendly manufacturing process. Its economic competitiveness could also be improved by the use of aromatic isocyanates that are widely available and cheaper than the currently used aliphatic isocyanates. We report on the synthesis and properties of WPU, based on natural rubber (NR) whose molecular structure has been altered, in combination with an aromatic isocyanate. The NR modification is by hydroxyl termination

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Abushammala, Hatem, and Jia Mao. "A Review of the Surface Modification of Cellulose and Nanocellulose Using Aliphatic and Aromatic Mono- and Di-Isocyanates." Molecules 24, no. 15 (2019): 2782. http://dx.doi.org/10.3390/molecules24152782.

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Nanocellulose has been subjected to a wide range of chemical modifications towards increasing its potential in certain fields of interest. These modifications either modulated the chemistry of the nanocellulose itself or introduced certain functional groups onto its surface, which varied from simple molecules to polymers. Among many, aliphatic and aromatic mono- and di-isocyanates are a group of chemicals that have been used for a century to modify cellulose. Despite only being used recently with nanocellulose, they have shown great potential as surface modifiers and chemical linkers to graft

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Buckley, C. J., C. Phanopoulos, N. Khaleque, A. Engelen, M. E. J. Holwill, and A. G. Michette. "Examination of the Penetration of Polymeric Methylene Di-Phenyl-Di-Isocyanate (pMDI) into Wood Structure Using Chemical-State X-Ray Microscopy." Holzforschung 56, no. 2 (2002): 215–22. http://dx.doi.org/10.1515/hf.2002.035.

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Summary The penetration behaviour of isocyanate-based wood resins was evaluated using x-ray microscopy. Aspen wood pieces were bonded together in a controlled manner. These were embedded in a methacrylate-based resinand thin sections were prepared, cut from the transverse face of thewoodcomposite. X-ray images of these sections were prepared at several selected x-ray energies to allow the isocyanate, cellulose, lignin and the embedding agent distributions to be mapped. The isocyanate resin was found to penetrate deeply into the wood. The resin enters large cell lumen, and wicks along the inner

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Er, Hui-Teng, David L. Pole, and John Warkentin. "(Alkylthio)- and (phenylthio)methoxycarbenes from oxadiazolines." Canadian Journal of Chemistry 74, no. 8 (1996): 1480–89. http://dx.doi.org/10.1139/v96-165.

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Four 2-methoxy-5,5-dimethyl-Δ3-1,3,4-oxadiazolines bearing an alkylthio or arylthio group at C2 were prepared. The oxadiazolines undergo thermolysis at 60–80 °C in solution to afford the corresponding oxythiocarbene intermediates. In the absence of carbene traps, dimers of the carbenes were formed. The carbenes were trapped with ethyl crotonate, with dichloromaleic anhydride, with dimethyl acetylenedicarboxylate, and with phenyl isocyanate. Phenyl isocyanate traps methoxy(methylthio)carbene to form two types of adducts, both fundamentally different from the product obtained from reaction of di

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7

??pírková, Milena, Miroslav Kubín, Pavel ??pa??ek, Ivan Krakovský, and Karel Du??ek. "Cyclotrimerization of isocyanate groups. I. Catalyzed reactions of phenyl isocyanate." Journal of Applied Polymer Science 52, no. 7 (1994): 895–904. http://dx.doi.org/10.1002/app.1994.070520708.

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Kasten, W., and H. Dreizler. "Nitrogen Quadrupole Coupling in the Microwave Spectra of Phenyl Isocyanate and Phenyl Isothiocyanate." Zeitschrift für Naturforschung A 42, no. 1 (1987): 79–82. http://dx.doi.org/10.1515/zna-1987-0113.

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The microwave spectra of phenyl isocyanate, C6H5NCO, and phenyl isothiocyanate, C6H5NCS, have been measured by microwave Fourier transform spectroscopy between 4.7 and 8.0 GHz and analysed for nuclear quadrupole hyperfine splitting due to 14N.

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Pole, David L., Pradeep K. Sharma, and John Warkentin. "Methoxy-(2-trimethylsilyl)ethoxycarbene. Reactions with Michael acceptors, with hydroxylic compounds, and with miscellaneous functional groups." Canadian Journal of Chemistry 74, no. 7 (1996): 1335–40. http://dx.doi.org/10.1139/v96-149.

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Methoxy-(2-trimethylsilyl)ethoxycarbene reacts with two equivalents of dimethyl acetylene dicarboxylate, methyl propiolate, phenyl acetylene, or phenyl isocyanate without rearrangement of the carbene group. N-Phenylmaleimide captures the carbene with 1:1 -stoichiometry. The structure of the product implies that a migration of the trimethylsilylethyl group from oxygen to carbon accompanies that reaction. A mechanism for that complex rearrangement is proposed. Phenol and tert-butyl alcohol afford the orthoformates expected from overall insertion of the carbene into the OH bond. Key words: dialko

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10

Mohammed, Issam A., and Govindarajan Sankar. "Synthesis, deblocking and cure reaction studies of secondary alcohol-blocked isocyanates." High Performance Polymers 23, no. 7 (2011): 535–41. http://dx.doi.org/10.1177/0954008311421833.

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A series of 1,3-dichloro-2-propanol-blocked diisocyanates, based on diisocyanates including 4,4′-methylene di(phenyl isocyanate), toluene-2,4-diisocyanate, isophorone diisocyanate and 1,6-diisocyanatohexane, were prepared and characterized thoroughly by Fourier transform infrared, 1 H-NMR, 13 C-NMR spectroscopic methods and elemental analysis (CHN). The blocking reaction of 1,3-dichloro 2-propanol with aromatic diisocyanates occurs faster than with the aliphatic isocyanates. The deblocking temperature of blocked isocyanates was determined by thermogravimetric analysis, differential scanning ca

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Dissertations / Theses on the topic "Phenyl isocyanate"

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Pokrajac, Lisa A. "Fundamental studies of polyurethane - aluminum adhesion, phenyl isocyanate interaction with prepared aluminum oxide surfaces." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1998. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape10/PQDD_0006/MQ40733.pdf.

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Riedlinger, Darren Andrew. "Characterization of PF Resol/Isocyanate Hybrid Adhesives." Thesis, Virginia Tech, 2008. http://hdl.handle.net/10919/31366.

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Water-based resol phenol formaldehyde, PF, and organic polymeric methylenebis(phenylisocyanate), pMDI, are the two primary choices for the manufacture of exterior grade wood-based composites. This work addresses simple physical blends of pMDI dispersed in PF as a possible hybrid wood adhesive. Part one of this study examined the morphology of hybrid blends prepared using commercially available PF and pMDI. It was found that the blend components rapidly reacted such that the dispersed pMDI droplets became encased in a polymeric membrane. The phase separation created during liquid/liquid blendi

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Schmidt, Robert G. "Aspects of Wood Adhesion: Applications of 13C CP/MAS NMR and Fracture Testing." Diss., Virginia Tech, 1998. http://hdl.handle.net/10919/30352.

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Phenol Formaldehyde (PF) and polymeric isocyanate (pMDI) are the two main types of adhesives used in the production of structural wood-based composites. Much is unknown about various aspects of adhesion between these two types of resins and wood. The present research describes the development of techniques which will permit an enhanced understanding of 1.) the extent of cure of PF within a wood based composite, 2.) the scale of molecular level interactions between PF and pMDI and wood, 3.) mechanical performance and durability of wood-adhesive bonds. Correlations were established between con

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Beji, Mohamed. "Heterocumulenes alpha -sulfonyles et leurs applications a la synthese de nouvelles structures heterocycliques : alkylation des esters sulfamiques en catalyse par transfert de phase." Paris 7, 1987. http://www.theses.fr/1987PA077183.

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Dupont, Jairton. "Activation-fonctionnalisation intramoleculaire de liaisons c-h par le palladium." Université Louis Pasteur (Strasbourg) (1971-2008), 1988. http://www.theses.fr/1988STR13197.

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Ma, Kuo-Chen, and 馬國誠. "Thermal Chemistry of Benzyl Isocyanate and Phenyl Isocyanate on Cu(111)." Thesis, 2011. http://ndltd.ncl.edu.tw/handle/61515634264988435689.

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碩士<br>國立中山大學<br>化學系研究所<br>99<br>Nitrenes are reactive intermediates for many organic reactions, such as Curtius rearrangement. The thermo- or photochemical- decomposition of azides or isocyanates was known to generate nitrenes. We investigated the thermal chemistry of nitrene adsorbed on Cu(111) using benzyl azide (Bz-N=N=N), benzyl isocyanate (Bz-N=C=O) and phenyl isocyanate (ph-N=C=O) as precursors under ultrahigh vacuum conditions using temperature-programmed reaction/desorption (TPR/D), reflectionabsorption infrared spectroscopy (RAIRS) and X-ray photoelectron spectroscopy (XPS). Our study

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Lin, Wen-Jun, and 林玟君. "Thermal and Photochemical Reactions of 1H-1,2,3-Triazole and Phenyl Isocyanate on Graphene Matrix and Copper Surface." Thesis, 2017. http://ndltd.ncl.edu.tw/handle/677ey8.

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碩士<br>國立中山大學<br>化學系研究所<br>106<br>Abstract In the thermochemical study of 1H-1,2,3-Triazole adsorbed on graphene, TPD showed both molecular desorption and decomposition occur at 217 K. The ring is parallel to the basal plane of graphene via π-π interaction, resulting in a surface higher desorption peak temperature than that on clean Cu (111). While the former molecules adsorb in a layer by layer fusion, the latter is deposited by an island growth mode. In the photochemical studies, using two different UV light sources, RAIRS observed no reactions to take place during four hours irradiation

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Cheng, Cheng-Hung, and 鄭正宏. "Thermal Chemistry of Benzyl Azide to Phenyl Isocyanide on Cu(111):Evidence for a Surface Imine Intermediate." Thesis, 2010. http://ndltd.ncl.edu.tw/handle/49586666281401765071.

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碩士<br>國立中山大學<br>化學系研究所<br>98<br>Abstract The Copper Catalyzed Azide-Alkyne Cycloaddition (CuAAC) is a paradigm of “click” chemistry which has been applied in different fields. To understand the interaction between organic azides and a copper surface, we use benzyl azide (Bn－Nα－Nβ≡Nγ) as an adsorbate on Cu(111) under ultrahigh vacuum conditions. The thermal reaction process was explored by a combination of temperature-programmed desorption (TPD), reflection absorption infrared spectroscopy (RAIRS), and X-ray photoemission spectroscopy (XPS) techniques. The TPD profiles show a multilayer desorpt

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Books on the topic "Phenyl isocyanate"

1

Pokrajac, Lisa A. Fundamental studies of polyurethane-aluminum adhesion: Phenyl isocyanate interaction with prepared aluminum oxide surfaces. Dept of Chemistry, U of Toronto, 1998, 1998.

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Book chapters on the topic "Phenyl isocyanate"

1

"Phenyl isocyanate." In Toxicological Evaluations. Springer Berlin Heidelberg, 1999. http://dx.doi.org/10.1007/978-3-642-60138-5_5.

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"Phenyl isocyanate." In Toxicological Evaluations. Springer Berlin Heidelberg, 1992. http://dx.doi.org/10.1007/978-3-642-84693-9_7.

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"Comparison of the toxic effects of phenyl isocyanate, 4-chlorophenyl isocyanate and 4-isopropylphenyl isocyanate." In Toxicological Evaluations. Springer Berlin Heidelberg, 1999. http://dx.doi.org/10.1007/978-3-642-60138-5_4.

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4

Hemming, K. "By Using an Aliphatic Nitrile Oxide Generated from a Nitroalkane and Phenyl Isocyanate." In Five-Membered Hetarenes with Three or More Heteroatoms. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-013-00180.

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5

Schantl, J. G. "Thermally Induced [3 + 2] Cycloelimination of Phenyl Isocyanate from 1-Methylene-3,5-dioxo-4-phenyl-1,2,4-triazolidin-1-ium-2-ide Followed by [3 + 2] Cycloaddition To Give 1-Methylene-5-oxo-1-pyrazol-1-ium-2-ides." In Heteroatom Analogues of Aldehydes and Ketones. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-027-00714.

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Taber, Douglass. "Intermolecular and Intramolecular C-H Functionalization." In Organic Synthesis. Oxford University Press, 2011. http://dx.doi.org/10.1093/oso/9780199764549.003.0014.

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Peter Legzdins of the University of British Columbia has described (J. Am. Chem. Soc. 2007, 129, 5372) a stoichiometric tungsten complex that speciﬁcally functionalized the primary H of an alkane 1 to give the organometallic 2. Neither the scope of the reactivity of 2 nor the functional group compatibility of this process have as yet been explored. Ruggero Curci of the Università di Bari has reported (Tetrahedron Lett. 2007, 48, 3575) the stereospecific hydroxylation of 1,3-dimethyl cyclohexane 4 to the diol 6. Yasuyuki Kita of Osaka University has developed (Organic Lett. 2007, 9, 3129) conditions for specific benzylic oxidation, converting 7 into 8 with high diastereocontrol. Larry E. Overman of the University of California, Irvine has established (Organic Lett. 2007, 9, 5267) that by using a slow H-atom donor, it was possible to effect intramolecular H abstraction, leading, by oxidation of the intermediate captodatively-stabilized radical, from 9 to the acetate 10. The target C-H of 9 is activated by being adjacent to the ring nitrogen. There are many other ways that nitrogen, easily oxidized, has been used to activate a C-H for bond formation. Takehiko Yoshimitsu and Tetsuaki Tanaka of Osaka University have established (Organic Lett. 2007, 9, 5115) a free-radical route for the homologation of a tertiary amine such as 11 with phenyl isocyanate 12. Chuan He of the University of Chicago has devised (Angew. Chem. Int. Ed. 2007, 46, 5184) an Ag catalyst for the oxidative cyclization of sulfamates such as 15. M. Christina White of the University of Illinois has developed (J. Am. Chem. Soc. 2007, 129, 7274) a ligand system that allows the diastereoselective Pd-mediated allylic oxidation of 16 to 17. The cyclization of 18 to 19 developed (J. Org. Chem. 2007, 72, 8994) by Renhua Fan of Fudan University is thought to be proceeding via H atom abstraction by an intermediate nitrogen radical. The oxidation of the amine 20 to the endocyclic enamine 21 reported (J. Am. Chem. Soc. 2007, 129, 14544) by Maurice Brookhart of the University of North Carolina depended on the ease of oxidative addition of an intermediate alkenyl Co complex into the C-H bond adjacent to the nitrogen. The multistep cyclization of 22 to 23 devised (Organic Lett. 2007, 9, 4375) by Philippe Renaud of the Universität Bern depended on the ease of H atom abstraction adjacent to nitrogen.

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Taber, Douglass F. "Carbon-Carbon Bond Formation." In Organic Synthesis. Oxford University Press, 2013. http://dx.doi.org/10.1093/oso/9780199965724.003.0025.

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Akiya Ogawa of Osaka Prefecture University found (Tetrahedron Lett. 2010, 51, 6580) that the Sm-mediated reductive coupling of a halide 1 with CO2 to give the carboxylic acid 2 was strongly promoted by visible light. Gregory C. Fu of MIT designed (Angew. Chem. Int. Ed. 2010, 49, 6676) a Ni catalyst for the coupling of a primary borane 4 with a secondary alkyl halide 3. James P. Morken of Boston College devised (Org. Lett. 2010, 12, 3760) conditions for the carbonylative conjugate addition of a dialkyl zinc to an enone 6 to give the 1,4-dicarbonyl product 7. Louis Fensterbank of the Institut Parisien de Chimie Moléculaire developed (Angew. Chem. Int. Ed. 2010, 49, 8721; not illustrated) a protocol for the conjugate addition of alkyl boranes to enones. Hyunik Shin of LG Life Science, Daejeon, and Sang-gi Lee of Ewha Womans University showed (Tetrahedron Lett. 2010, 51, 6893) that the intermediate from Blaise homologation of a nitrile 8 was a powerful nucleophile, smoothly opening an epoxide 10 to deliver 11. Sébastien Reymond and Janine Cossy of ESPCI ParisTech found (J. Org. Chem. 2010, 75, 5151) that FeCl3 smoothly catalyzed the coupling of an alkenyl Grignard 13 with the primary iodide 12. The Ti-mediated coupling of an alkyne 16 with an allylic alkoxide 15 (J. Am. Chem. Soc. 2010, 132, 9576) developed by Glenn C. Micalizio of Scripps/Florida was the key step in the total synthesis (J. Am. Chem. Soc. 2010, 132, 11422) of lehualide B. Huanfeng Jiang of the South China University of Technology observed (Chem. Commun. 2010, 46, 8049) that KI added to a bromoalkyne 18 to give the dihalide 19 with high geometric control. Haruhiko Fuwa of Tohoku University improved (Org. Lett. 2010, 12, 5354) the selective hydroiodination of a methyl alkyne 20 to 21. Takuya Kurahashi and Seijiro Matsubara of Kyoto University devised (Chem. Commun. 2010, 46, 8055) the Ni-catalyzed three-component coupling of an alkyne 22, methyl acrylate 23, and phenyl isocyanate to give the doubly homologated lactam 24. Patrick H. Toy of the University of Hong Kong showed (Synlett 2010, 1997; Org. Lett. 2010, 12, 4996 for a polymer with covalently attached base) that resin-bound triphenylphosphine participated efficiently in the Wittig coupling of 26 with an aldehyde 25.

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Taber, Douglass F. "Substituted Benzenes: The Subba Reddy Synthesis of 7-Desmethoxyfusarentin." In Organic Synthesis. Oxford University Press, 2015. http://dx.doi.org/10.1093/oso/9780190200794.003.0064.

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Andrey P. A ntonchick of the Max-Planck-Institut Dortmund devised (Org. Lett. 2012, 14, 5518) a protocol for the direct amination of an arene 1 to give the amide 3. Douglass A. Klumpp of Northern University showed (Tetrahedron Lett. 2012, 53, 4779) that under strong acid conditions, an arene 4 could be carboxylated to give the amide 6. Eiji Tayama of Niigata University coupled (Tetrahedron Lett. 2012, 53, 5159) an arene 7 with the α-diazo ester 8 to give 9. Guy C. Lloyd-Jones and Christopher A. Russell of the University of Bristol activated (Science 2012, 337, 1644) the aryl silane 11 to give an intermediate that coupled with the arene 10 to give 12. Ram A. Vishwakarma and Sandip P. Bharate of the Indian Institute of Integrative Medicine effected (Tetrahedron Lett. 2012, 53, 5958) ipso nitration of an areneboronic acid 13 to give 14. Stephen L. Buchwald of MIT coupled (J. Am. Chem. Soc. 2012, 134, 11132) sodium isocyanate with the aryl chloride 15 (aryl triflates also worked well) to give the isocyanate 16, which could be coupled with phenol to give the carbamate or carried onto the unsymmetrical urea. Zhengwu Shen of the Shanghai University of Traditional Chinese Medicine used (Org. Lett. 2012, 14, 3644) ethyl cyanoacetate 18 as the donor for the conversion of the aryl bromide 17 to the nitrile 19. Kuo Chu Hwang of the National Tsig Hua University showed (Adv. Synth. Catal. 2012, 354, 3421) that under the stimulation of blue LED light the Castro-Stephens coupling of 20 with 21 proceeded efficiently at room temperature. Lutz Ackermann of the Georg-August-Universität Göttingen employed (Org. Lett. 2012, 14, 4210) a Ru catalyst to oxidize the amide 23 to the phenol 24. Both Professor Ackermann (Org. Lett. 2012, 14, 6206) and Guangbin Dong of the University of Texas (Angew. Chem. Int. Ed. 2012, 51, 13075) described related work on the ortho hydroxylation of aryl ketones. George A. Kraus of Iowa State University rearranged (Tetrahedron Lett. 2012, 53, 7072) the aryl benzyl ether 25 to the phenol 26. The synthetic utility of the triazene 27 was demonstrated (Angew. Chem. Int. Ed. 2012, 51, 7242) by Yong Huang of the Shenzen Graduate School of Peking University.

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Eagle, P. A. C. "Iminoplumbanes from Triorganoplumbanes by Reactions with Phenyl Isocyanide." In Compounds of Group 14 (Ge, Sn, Pb). Georg Thieme Verlag KG, 2003. http://dx.doi.org/10.1055/sos-sd-005-00741.

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Conference papers on the topic "Phenyl isocyanate"

1

Schwarz, Cara, Robert McMahon, R. Woods, Brian Esselman, Benjamin Haenni, and Brent Amberger. "MILLIMETER-WAVE SPECTROSCOPY OF PHENYL ISOCYANATE." In 70th International Symposium on Molecular Spectroscopy. University of Illinois at Urbana-Champaign, 2015. http://dx.doi.org/10.15278/isms.2015.mg10.

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Edwards, Peter A., Michael Price, Nick Nimchuk, and Jeff Mahon. "Novel Water Loving Coatings (WLC) Lubricious and Durable Guidewires." In 2017 Design of Medical Devices Conference. American Society of Mechanical Engineers, 2017. http://dx.doi.org/10.1115/dmd2017-3434.

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Hydrophilic coatings applied to guidewires or catheters, lower friction of the device thus improves handling and reduces damage to the vessel walls during access, delivery and retrieval. Peripheral guidewires typically consist of a polymer jacket, basecoat and topcoat. The polymer jacket is highly radiopaque for fluoroscopy visualization. Basecoat adheres to the polymer jacket and hydrophilic topcoat. Basecoat and topcoat play important roles towards coating device durability and lubricity. Water Loving Coatings (WLC) are the first developed 510(k) clearance guidewires utilizing epoxy polyuret

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Iswanto, Apri Henri, Irawati Azhar, Tito Sucipto, and Fazila Oktaviani Tarigan. "Com-Ply Board Properties Made from Oil Palm Trunk Bonded with Isocyanate, Phenol Formaldehyde and Urea Formaldehyde." In International Conference on Natural Resources and Technology. SCITEPRESS - Science and Technology Publications, 2019. http://dx.doi.org/10.5220/0008386500050007.

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