Academic literature on the topic 'Poly-ligand electrolyte'

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Journal articles on the topic "Poly-ligand electrolyte"

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Hapon, Yuliana, Maryna Chyrkina, Dmytro Tregubov, and Olesia Romanova. "Co-Mo-W Galvanochemical Alloy Application as Cathode Material in the Industrial Wastewater Treatment Processes." Materials Science Forum 1038 (July 13, 2021): 251–57. http://dx.doi.org/10.4028/www.scientific.net/msf.1038.251.

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The article deals with the role of electrodes materials in improving the industrial wastewater treatment from pollutants by electrochemical action. The instability constants of the complexes and coordinated ligand molecules were calculated. Based on the research conducted regarding the rationalisation of the poly-ligand electrolytes and electrolysis modes, a variative flow scheme of the coatings deposition by triple alloy has been developed. The corrosion resistance characteristics of the coatings obtained in the form of alloy, that were obtained from complex electrolyte that satisfy the neces
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Karushev, Mikhail, Evgenia Smirnova, and Irina Chepurnaya. "Nickel(II) Complex of N4 Schiff Base Ligand as a Building Block for a Conducting Metallopolymer with Multiple Redox States." Molecules 26, no. 9 (2021): 2646. http://dx.doi.org/10.3390/molecules26092646.

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Metal–ligand interactions in monomeric and polymeric transition metal complexes of Schiff base ligands largely define their functional properties and perspective applications. In this study, redox behavior of a nickel(II) N4-anilinosalen complex, [NiAmben] (where H2Amben = N,N′-bis(o-aminobenzylidene)ethylenediamine) was studied by cyclic voltammetry in solvents of different Lewis basicity. A poly-[NiAmben] film electrochemically synthesized from a 1,2-dichloroethane-based electrolyte was investigated by a combination of cyclic voltammetry, electrochemical quartz crystal microbalance, in situ
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Li, Sibo, Mengying Tian, Jirong Wang, Feipeng Du, Liang Li, and Zhigang Xue. "Poly (Ethylene Oxide)-Based Block Copolymer Electrolytes Formed via Ligand-Free Iron-Mediated Atom Transfer Radical Polymerization." Polymers 12, no. 4 (2020): 763. http://dx.doi.org/10.3390/polym12040763.

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The Br-terminated poly (ethylene oxide) (PEO-Br) is used as a green and efficient macroinitiator in bulk Fe-catalyzed atom transfer radical polymerization (ATRP) without the addition of any organic ligands. The polymerization rate is able to be mediated by PEO-Br with various molecular weights, and the decrease in redox potential of FeBr2 in cyclic voltammetry (CV) curves indicates that an increased coordination effect is deteriorated with the depressing reaction activity in the longer ethylene oxide (EO) chain in PEO-Br. In combination with the study of different catalysts and catalytic conte
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Nenastina, T., M. Sakhnenko, S. Oksak, et al. "Study of Complexation Patterns in the System Ni2+, MoO42–, P2O74–, Cit3–for the Development of Poly-Ligand Electrolytes (Study of complexation patterns)." Eurasian Chemico-Technological Journal 26, no. 3 (2024): 155–60. http://dx.doi.org/10.18321/ectj1638.

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The complexation behavior in systems containing Ni2+, MoO42−, P2O74−, Cit3− - ions have been thoroughly investigated. The study determined the composition and instability constants of both mono- and biligand complex compounds at a constant ionic strength of the solution (Ic=1). By analyzing the concentration ratios of the complexing agent and ligands, the composition of mono- and polyligand complexes was elucidated. The complexation study utilized the potentiometric method, which is based on the functional dependence of the potential of the indicator electrode on the concentration of the compl
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Gaddie, Ross S., Christopher B. Moss, and C. Michael Elliott. "Cyclic Voltammetric Study of Cobalt Poly-4-t-butylpyridine Ligand Complexes on Glassy Carbon Electrodes: Electrolyte Dependence and Mechanistic Considerations." Langmuir 29, no. 2 (2013): 825–31. http://dx.doi.org/10.1021/la304262a.

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Feng, Jun, Jin Li, Jian Feng, Zhong Wei, Ziqing Wang, and Xiaoling Song. "Synthesis of Aliphatic Polycarbonates from Diphenyl Carbonate and Diols over Zinc (II) Acetylacetonate." Molecules 27, no. 24 (2022): 8958. http://dx.doi.org/10.3390/molecules27248958.

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APCs (aliphatic polycarbonates) are one of the most important types of biodegradable polymers and widely used in the fields of solid electrolyte, biological medicine and biodegradable plastics. Zinc-based catalysts have the advantages of being low cost, being non-toxic, having high activity, and having excellent environmental and biological compatibility. Zinc (II) acetylacetonate (Zn(Acac)2) was first reported as a highly effective catalyst for the melt transesterification of biphenyl carbonate with 1,4-butanediol to synthesize poly(1,4-butylene carbonate)(PBC). It was found that the weight-a
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Watabe, Yusuke, Masahiro Fujita, Yuko Takeoka, and Masahiro Rikukawa. "Synthesis and Evaluation of Silica Particles Grafted with Electrolyte Unit (VI)-Improvement of Polymer Introduction Rate." ECS Meeting Abstracts MA2024-02, no. 43 (2024): 2893. https://doi.org/10.1149/ma2024-02432893mtgabs.

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Next-generation PEFC electrolyte membranes will require high proton conductivity and durability under high temperature and low relative humidity conditions. Core-shell organic-inorganic hybrid materials are expected to utilize the characteristics of organic and inorganic materials to overcome the problems of conventional PEM materials. In this study, silica particles (SiPs) were selected as the inorganic core to increase mechanical properties and thermal resistance, and the polymers having sulfo groups were selected as the organic shell to develop proton conductivity. Surface-grafted polymeriz
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Moges, Endalkachew Asefa Asefa, Meng-Che Tsai, Wei-Nien Su, and Bing Joe Hwang. "Homoleptic and Heteroleptic Coordination Environment of Palladium Molecular Catalysts for Oxygen Reduction to Hydrogen Peroxide." ECS Meeting Abstracts MA2024-02, no. 56 (2024): 3756. https://doi.org/10.1149/ma2024-02563756mtgabs.

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Hydrogen peroxide (H2O2) serves a wide range of purposes in industries such as chemical manufacturing, energy production, and wastewater treatment, either alone or in combination with other oxidizers. The demand for H2O2 has seen a notable increase due to its heightened use in disinfection amid the COVID-19 pandemic. Currently, industrial synthesis of H2O2 relies on anthraquinone technology, a complex process involving multiple steps including the use of H2 gas, transfer of H2O2 between solvents, distillation of concentrated H2O2, and potentially hazardous transportation. Thus, advancements in
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Wang, Wentao, Fadi Aldeek, Xin Ji, Birong Zeng, and Hedi Mattoussi. "A multifunctional amphiphilic polymer as a platform for surface-functionalizing metallic and other inorganic nanostructures." Faraday Discuss. 175 (2014): 137–51. http://dx.doi.org/10.1039/c4fd00154k.

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We designed a new set of polymer ligands that combine multiple metal-coordinating groups and short polyethylene glycol (PEG) moieties in the same structure. The ligand design relies on the controlled grafting of a large number of amine-terminated histamines and PEG short chains onto a poly(isobutylene-alt-maleic anhydride) backbone,viaa one-step nucleophilic addition reaction. This addition reaction is highly efficient, can be carried out in organic media and does not require additional reagents. We show that when imidazole groups are used the resulting polymer ligand can strongly ligate onto
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Okazawa, Atsushi, Takayuki Kakuchi, Keisuke Akahori, Kosuke Kawai, and Masashi Okubo. "Solubility-Enhanced Iron Complex Posolytes for Redox Flow Batteries." ECS Meeting Abstracts MA2024-02, no. 1 (2024): 16. https://doi.org/10.1149/ma2024-02116mtgabs.

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Redox flow batteries (RFBs) are promising stationary energy storage devices for renewables. Commercial RFBs possess potential disadvantages such as cost and resource constraint due to the use of vanadium. Therefore, organic compounds and metal coordination complexes have drawn much attention as redox active materials for RFB electrolytes. We focus on less expensive terpyridine iron complexes that have higher redox potential of approximately 1 V (vs. SHE) as an active material for both aqueous and non-aqueous RFB posolytes.[1] However, terpyridine iron complexes generally possess low solubility
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Dissertations / Theses on the topic "Poly-ligand electrolyte"

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Гапон, Юліана Костянтинівна. "Функціональні покриття тернарними сплавами кобальту з тугоплавкими металами". Thesis, НТУ "ХПІ", 2017. http://repository.kpi.kharkov.ua/handle/KhPI-Press/27602.

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Дисертація на здобуття наукового ступеня кандидата технічних наук за спеціальністю 05.17.03 – технічна електрохімія. – Національний технічний університет "Харківський політехнічний інститут", м. Харків, 2017 р. Дисертацію присвячено розробці технології гальванохімічного синтезу покриттів тернарними сплавами кобальт-молібден-вольфрам з полілігандних електролітів для одержання матеріалів з поліпшеними фізико-механічними властивостями. Визначено константи нестійкості та склад моно- та білігандних комплексів кобальту та запропоновано цитратно-дифосфатну та амонійно-цитратну системи для осадження
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Гапон, Юліана Костянтинівна. "Функціональні покриття тернарними сплавами кобальту з тугоплавкими металами". Thesis, НТУ "ХПІ", 2017. http://repository.kpi.kharkov.ua/handle/KhPI-Press/27601.

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Дисертація на здобуття наукового ступеня кандидата технічних наук за спеціальністю 05.17.03 – технічна електрохімія. – Національний технічний університет "Харківський політехнічний інститут", м. Харків, 2017 р. Дисертацію присвячено розробці технології гальванохімічного синтезу покриттів тернарними сплавами кобальт-молібден-вольфрам з полілігандних електролітів для одержання матеріалів з поліпшеними фізико-механічними властивостями. Визначено константи нестійкості та склад моно- та білігандних комплексів кобальту та запропоновано цитратно-дифосфатну та амонійно-цитратну системи для осадження
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