Academic literature on the topic 'Ruthenium Metal Complexes'

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Journal articles on the topic "Ruthenium Metal Complexes"

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Sava, Gianni, Sabrina Pacor, Francesca Bregant, Valentina Ceschia, and Giovanni Mestroni. "Metal complexes of ruthenium." Anti-Cancer Drugs 1, no. 2 (1990): 99–108. http://dx.doi.org/10.1097/00001813-199012000-00001.

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Phillips, Ian G., and Peter J. Steel. "Mono- and Bi-nuclear Complexes of the Doubly Bidentate, Bridging Ligand 4,6-Di(2-pyridyl)pyrimidine." Australian Journal of Chemistry 51, no. 5 (1998): 371. http://dx.doi.org/10.1071/c97127.

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Thirteen mononuclear, homobinuclear and heterobinuclear transition metal complexes of 4,6-di(2- pyridyl)pyrimidine have been prepared. Assignments of the 1H n.m.r. spectra of the molybdenum(0) and ruthenium(II) complexes were achieved by a combination of one- and two-dimensional n.m.r. techniques, especially 1D-TOCSY. For the ruthenium complexes, electronic absorption spectroscopy and cyclic voltammetry were used to probe the nature of the metal{ligand and, for the binuclear complexes, metal-metal interactions. The complexes have low HOMO−LUMO energy gaps. Meta-metal interactions are shown to
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Gałczyńska, Katarzyna, Zuzanna Drulis-Kawa, and Michał Arabski. "Antitumor Activity of Pt(II), Ru(III) and Cu(II) Complexes." Molecules 25, no. 15 (2020): 3492. http://dx.doi.org/10.3390/molecules25153492.

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Metal complexes are currently potential therapeutic compounds. The acquisition of resistance by cancer cells or the effective elimination of cancer-affected cells necessitates a constant search for chemical compounds with specific biological activities. One alternative option is the transition metal complexes having potential as antitumor agents. Here, we present the current knowledge about the application of transition metal complexes bearing nickel(II), cobalt(II), copper(II), ruthenium(III), and ruthenium(IV). The cytotoxic properties of the above complexes causing apoptosis, autophagy, DNA
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Hoshino, Yoshimasa. "Molecular Design for Long-Range Electronic Communication between Metals." Platinum Metals Review 45, no. 1 (2001): 2–11. http://dx.doi.org/10.1595/003214001x451211.

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To construct molecular devices it is necessary to use mixed-valence metal complexes which have a large metal-metal separation distance and which exhibit strong coupling between the metals, so that errors which might arise from electrostatic interaction between the metal ions are prevented. Bridges, or spacers, are needed between two metal terminal sites to operate as effective molecular wires when one metal terminal site is in the excited state, and/or when both the terminal components are in the ground state. Binuclear ruthenium complexes, consisting of tris(β-diketonato)ruthenium(III) units,
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Houbrechts, Stephan, Carlo Boutton, Koen Clays, et al. "Novel Organometallic Compounds for Nonlinear Optics." Journal of Nonlinear Optical Physics & Materials 07, no. 01 (1998): 113–20. http://dx.doi.org/10.1142/s0218863598000090.

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Hyper-Rayleigh scattering is used to investigate the nonlinear optical properties of novel metal (ruthenium, nickel and gold) σ-arylacetylide complexes. The influence of the organometallic donor group and conjugating bridge on the quadratic hyperpolarizability is studied. For all organic ligands, the addition of the metal (donor) group is shown to increase the static hyperpolarizability by a factor of 2, 4 and 7 for gold, nickel and ruthenium complexes, respectively. Moreover, replacement of phenyl with a heterocyclic ring is demonstrated to enlarge the hyperpolarizability in the case of gold
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Voutyritsa, Errika, Ierasia Triandafillidi, Nikolaos V. Tzouras, et al. "Photocatalytic Atom Transfer Radical Addition to Olefins Utilizing Novel Photocatalysts." Molecules 24, no. 9 (2019): 1644. http://dx.doi.org/10.3390/molecules24091644.

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Photocatalysis is a rapidly evolving area of research in modern organic synthesis. Among the traditional photocatalysts, metal-complexes based on ruthenium or iridium are the most common. Herein, we present the synthesis of two photoactive, ruthenium-based complexes bearing pyridine-quinoline or terpyridine ligands with extended aromatic conjugation. Our complexes were utilized in the atom transfer radical addition (ATRA) of haloalkanes to olefins, using bromoacetonitrile or bromotrichloromethane as the source of the alkyl group. The tailor-made ruthenium-based catalyst bearing the pyridine-qu
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Vatansever, Hafize Seda, Hilal Kabadayı, Mehmet Korkmaz, Feyzan Özdal-Kurt, Serdar Batıkan Kavukcu, and Hayati Türkmen. "Apoptotic Properties of Rutheinum Complexes on Different Type of Cancer Cell Lines." Proceedings 2, no. 25 (2018): 1593. http://dx.doi.org/10.3390/proceedings2251593.

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Among chemotherapeutic agents, cisplatin and the other platinum-based drugs have occupied for 35 years an enviable position. The limitations of platinum-based drugs, dose dependent side effects and development of drug resistance mechanisms, have boosted the research for finding other metal-based drugs. Among metals, ruthenium is probably the one showing the greatest promises. Ruthenium (Ru) appears to be less toxic than platinum and several biological studies have indicated that ruthenium complexes possess diverse modes of action. The redox chemistry of ruthenium is rich and compatible with bi
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Vadivel, T., M. Dhamodaran, S. Kulathooran, M. Kavitha, and K. Amirthaganesan. "In Vitro Evaluation of Antifungal Activities by Permeation of Ru(III) Complexes Derived from Chitosan-Schiff Base Ligand." Current Applied Polymer Science 3, no. 3 (2020): 212–20. http://dx.doi.org/10.2174/2452271603666191016130012.

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Background: The transition metal complexes are derived from a natural biopolymer which is a very potent material in various research areas of study. Objective: This study aims to show the preparation of ruthenium(III) complexes from chitosan Schiff base ligand for effective application in antifungal studies. Methods: Chemical modification was carried out through a condensation reaction of chitosan with some aromatic aldehydes, which resulted in the formation of a bidentate Schiff base ligand. The Ru(III) complexes were prepared by complexation of ruthenium metal ion with bidentate ligands. The
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Enow, Charles A., Charlene Marais, and Barend C. B. Bezuidenhoudt. "Catalytic epoxidation of stilbenes with non-peripherally alkyl substituted carbonyl ruthenium phthalocyanine complexes." Journal of Porphyrins and Phthalocyanines 16, no. 04 (2012): 403–12. http://dx.doi.org/10.1142/s1088424612500459.

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A number of novel carbonyl(1,4,8,11,15,18,22,25-octaalkylphthalocyaninato)-ruthenium(II) complexes were prepared by metal insertion with Ru3(CO)12. The new compounds have been characterized by1H NMR,13C NMR, IR, UV-vis and mass spectroscopy. This study demonstrated that this type of complexes and specifically carbonyl(1,4,8,11,15,18,22,25-octahexylphthalo-cyaninato)ruthenium(II) and carbonyl[1,4,8,11,15,18,22,25-octa(2-cyclohexylethyl)phthalocyaninato]-ruthenium(II), exhibit high catalytic activity and stability in the epoxidation of stilbenes with 2,6-dichloropyridine N-oxide as oxidant.
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Burmeister, Hilke, Pascal Dietze, Lutz Preu, Julia E. Bandow, and Ingo Ott. "Evaluation of Ruthenium(II) N-Heterocyclic Carbene Complexes as Antibacterial Agents and Inhibitors of Bacterial Thioredoxin Reductase." Molecules 26, no. 14 (2021): 4282. http://dx.doi.org/10.3390/molecules26144282.

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A series of ruthenium(II) complexes with N-heterocyclic carbene (NHC) ligands of the general type (arene)(NHC)Ru(II)X2 (where X = halide) was prepared, characterized, and evaluated as antibacterial agents in comparison to the respective metal free benzimidazolium cations. The ruthenium(II) NHC complexes generally triggered stronger bacterial growth inhibition than the metal free benzimidazolium cations. The effects were much stronger against Gram-positive bacteria (Bacillus subtilis and Staphylococcus aureus) than against Gram-negative bacteria (Escherichia coli, Acinetobacter baumannii, Pseud
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Dissertations / Theses on the topic "Ruthenium Metal Complexes"

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Barthram, Anita Marie. "Metal-metal interactions in polynuclear complexes of ruthenium and osmium." Thesis, University of Bristol, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.326683.

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Greguric, Ivan. "Molecular recognition of DNA by metal co-ordination complexes /." [Campbelltown, N.S.W.] : University of Western Sydney, Macarthur, Faculty of Informatics, Science and Technology, 1999. http://library.uws.edu.au/adt-NUWS/public/adt-NUWS20030624.114833/index.html.

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Morewood, Catherine Alexandra. "π-complexes of osmium and ruthenium organometallic clusters". Thesis, University of Cambridge, 1995. https://www.repository.cam.ac.uk/handle/1810/272792.

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Luther, Thomas Alan. "Dicationic dihydrogen complexes of osmium and ruthenium /." Thesis, Connect to this title online; UW restricted, 1997. http://hdl.handle.net/1773/11540.

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Wong, Chun-yuen. "Ruthenium-carbon bonding interaction synthesis and spectroscopic studies of ruthenium-acetylide, -carbene, -vinylidene and -allenylidene complexes." Click to view the E-thesis via HKUTO, 2004. http://sunzi.lib.hku.hk/hkuto/record/B31040858.

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Stuart, Clare Anne. "Reactions of ruthenium(II) diphosphine complexes with silver(I) salts." Thesis, University of Liverpool, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.366948.

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Humphrey, Paul Andrew. "A study of transition metal complexes /." Title page, contents and summary only, 1990. http://web4.library.adelaide.edu.au/theses/09PH/09phh9262.pdf.

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Wong, Chun-yuen, and 黃駿弦. "Ruthenium-carbon bonding interaction synthesis and spectroscopic studies of ruthenium-acetylide, -carbene, -vinylidene and -allenylidene complexes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2004. http://hub.hku.hk/bib/B31040858.

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Vanover, Eric. "Photochemical Oxidation Studies of Porphyrin Ruthenium Complexes." TopSCHOLAR®, 2012. http://digitalcommons.wku.edu/theses/1201.

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In nature, transition metal containing enzymes display many biologically important, attractive and efficient catalytic oxidation reactions. Many transition metal catalysts have been designed to mimic the predominant oxidation catalysts in nature, namely, the cytochrome P450 enzymes. Ruthenium porphyrin complexes have been the center of this research and have successfully been utilized, as catalysts, in major oxidation reactions, such as the hydroxylation of alkanes. The present work focuses on photocatalytic studies of aerobic oxidation reactions with well characterized ruthenium porphyrin com
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Guest, Ruth Winifred. "Synthesis and reactions of iron and rutheniuim dinitrogen complexes." Connect to full text, 2008. http://ses.library.usyd.edu.au/handle/2123/3533.

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Thesis (Ph. D.)--University of Sydney, 2008.<br>Includes tables. Includes list of publications: leaves i-ii. Title from title screen (viewed October 30, 2008). Submitted in fulfilment of the requirements for the degree of Doctor of Philosophy to the School of Chemistry, Faculty of Science. Includes bibliographical references. Also available in print form.
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Books on the topic "Ruthenium Metal Complexes"

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Baulieu, Etienne, Donald T. Forman, Magnus Ingelman-Sundberg, et al., eds. Ruthenium and Other Non-Platinum Metal Complexes in Cancer Chemotherapy. Springer Berlin Heidelberg, 1989. http://dx.doi.org/10.1007/978-3-642-74760-1.

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E, Alessio, Clarke M. J, Società chimica italiana, Università degli studi di Trieste., and Symposium on Ruthenium and Other Non-Platinum Metal Complexes in Cancer Chemotherapy., eds. Ruthenium and other non-platinum metal complexes in cancer chemotherapy. Spriger Verlag, 1989.

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Kellen, John A., Etienne Baulieu, Lothar Jaenicke, et al. Ruthenium and Other Non-Platinum Metal Complexes in Cancer Chemotherapy. Springer, 2011.

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Ruthenium and Other Non-Platinum Metal Complexes in Cancer Chemotherapy. Springer London, Limited, 2013.

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Hinman, Justin Grant. Acidity of neutral transition metal polyhydride complexes and the study of anionic rhenium and ruthenium polyhydride dimers. 2001.

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Progress in Clinical Biochemistry and Medicine: Ruthenium and Other Non-Platinum Metal Complexes in Cancer Chemotherapy (Progress in Clinical Bioche). Springer, 1989.

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Trace, Rhonda. A new synthetic methodology applied to the preparation of some novel, alkyl substituted, cyclic carbene complexes of ruthenium, tungsten, and rhenium. 1991.

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Cundari, Thomas R. Molecular orbital investigations of metal-oxo catalyzed oxidations. 1990.

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Goldstein, Alan S. Catalytic oxidations of organic substrates by transition metal salts. 1991.

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Book chapters on the topic "Ruthenium Metal Complexes"

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Bullock, Jimmie L., and Alvin A. Holder. "Photodynamic Therapy in Medicine with Mixed-Metal/Supramolecular Complexes." In Ruthenium Complexes. Wiley-VCH Verlag GmbH & Co. KGaA, 2017. http://dx.doi.org/10.1002/9783527695225.ch7.

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Mlodnicka, Teresa, and Brian R. James. "Oxidations Catalyzed by Ruthenium Porphyrins." In Catalysis by Metal Complexes. Springer Netherlands, 1994. http://dx.doi.org/10.1007/978-94-017-2247-6_4.

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Roper, W. R. "Carbyne Complexes of Ruthenium and Osmium." In Transition Metal Carbyne Complexes. Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-011-1666-4_20.

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Griffith, William P. "The Chemistry of Ruthenium Oxidation Complexes." In Catalysis by Metal Complexes. Springer Netherlands, 2009. http://dx.doi.org/10.1007/978-1-4020-9378-4_1.

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Farrell, Nicholas. "Metal Complexes as Radiosensitizers." In Ruthenium and Other Non-Platinum Metal Complexes in Cancer Chemotherapy. Springer Berlin Heidelberg, 1989. http://dx.doi.org/10.1007/978-3-642-74760-1_5.

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Süss-Fink, Georg. "Multicenter Ligand Transformations of Tetramethyl-Thiourea on Ruthenium Clusters." In Transition Metal Carbyne Complexes. Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-011-1666-4_19.

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Chan, P. K. L., K. A. Skov, B. R. James, and N. P. Farrell. "Studies on Ruthenium Nitroimidazoles Complexes as Radiosensitizers." In Platinum and Other Metal Coordination Compounds in Cancer Chemotherapy. Springer US, 1988. http://dx.doi.org/10.1007/978-1-4613-1717-3_70.

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Braunstein, Pierre, Jacky Rose, and David C. Busby. "Stepwise Syntheses of Ruthenium Mixed-Metal Cluster Complexes." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132579.ch64.

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Lentzen, Olivier, Cécile Moucheron, and Andrée Kirsch-De Mesmaeker. "44Ru Perspectives of Ruthenium Complexes in Cancer Therapy." In Metallotherapeutic Drugs and Metal-Based Diagnostic Agents. John Wiley & Sons, Ltd, 2005. http://dx.doi.org/10.1002/0470864052.ch19.

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Ezhova, Maria B., and Brian R. James. "Catalytic oxidations using ruthenium porphyrins." In Advances in Catalytic Activation of Dioxygen by Metal Complexes. Springer US, 2003. http://dx.doi.org/10.1007/0-306-47816-1_1.

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Conference papers on the topic "Ruthenium Metal Complexes"

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Međedović, Milica, Dejan Lazić, Milan Vraneš, Ghodrat Mahmoudi, Biljana Petrović, and Ana Rilak Simović. "Kinetic studies of the Ru(II) polypyridyl complex with biologically relevant ligands." In 2nd International Conference on Chemo and Bioinformatics. Institute for Information Technologies, University of Kragujevac, 2023. http://dx.doi.org/10.46793/iccbi23.523m.

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In a group of transition metal complexes that scientists have synthesized to find a good replacement for cisplatin, ruthenium complexes, with various good properties, occupy a very important place. In this group, ruthenium polypyridyl complexes showed promising properties and became leading candidates for use as anticancer agents. In this study, we have synthesized a new ruthenium (II) polypyridyl complex of general formula [Ru(L)(N-N)Cl]Cl, where L is 2,2’:6’,2’’-terpyridine with the additional functional group in the 4’-position: 2-thienly and N-N=bpy (2,2’-bypiridine). The kinetics of the s
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Rebane, Aleksander K., Charles Stark, Juri Pahapill, Alexander Mikhaylov, and Matt Rammo. "Probing metal-to-ligand charge transfer transitions in ruthenium complexes by quantitative two-photon absorption spectroscopy." In Organic Photonic Materials and Devices XX, edited by Christopher E. Tabor, François Kajzar, Toshikuni Kaino, and Yasuhiro Koike. SPIE, 2018. http://dx.doi.org/10.1117/12.2290363.

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Radovanović, Marko, Ignjat Filipović, Maja Đukić, Marija Ristić, Ivan Jakovljević, and Zoran D. Matović. "Molecular docking study of ruthenium-p-cymene complexes with isothiazole derivatives as SARS-CoV-2 main protease inhibitors." In 2nd International Conference on Chemo and Bioinformatics. Institute for Information Technologies, University of Kragujevac, 2023. http://dx.doi.org/10.46793/iccbi23.387r.

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Since proper treatment for COVID-19 still has not been developed, exploration of novel options is required. Activities of different metal complexes, promising results gained from examining different thiazole derivatives, and research in the field of natural products like p-cymene, produced an idea to test piano stool ruthenium p-cymene complexes with isothiazole derivatives as ligands. In silico methods are often used as the first step in a series of experiments during the development of new drugs, and docking simulations are a quick way to determine the feasibility of novel compounds as poten
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Záliš, S., R. S. Winter, M. Linseis, et al. "DFT modeling of Spectral and Redox Properties of Di-and Tetranuclear Ruthenium Transition Metal Complexes with Bridging Ligands." In COMPUTATIONAL METHODS IN SCIENCE AND ENGINEERING: Advances in Computational Science: Lectures presented at the International Conference on Computational Methods in Sciences and Engineering 2008 (ICCMSE 2008). AIP, 2009. http://dx.doi.org/10.1063/1.3225297.

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Atanasković, Ana, Thomas Eichhorn, Dejan Milenković, Dušan Dimić, Goran Kaluđerović, and Jasmina Dimitrić Marković. "Synthesis, spectroscopic, and theoretical analysis of Ru(II)-phenylhydrazine complex." In 2nd International Conference on Chemo and Bioinformatics. Institute for Information Technologies, University of Kragujevac, 2023. http://dx.doi.org/10.46793/iccbi23.395a.

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In recent decades, metal-based chemotherapeutics have attracted considerable attention and excitement within the oncology research community, with ruthenium(II) complexes emerging as a particularly promising class of anticancer agents. In this study, the synthesis of a new ruthenium complex was performed, followed by its structural characterization using NMR and IC spectroscopy. The compound’s infrared spectrum reveals characteristic bands corresponding to N-H and C-H stretching vibrations from sp2 and sp3 hybridized carbon atoms, vibrations of aromatic rings and additional vibrations related
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Murtaza, Zakir, and Joseph R. Lakowicz. "Lifetime-based sensing of glucose using luminescent ruthenium (II) metal complex." In BiOS '99 International Biomedical Optics Symposium, edited by Joseph R. Lakowicz, Steven A. Soper, and Richard B. Thompson. SPIE, 1999. http://dx.doi.org/10.1117/12.347552.

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Cantrel, Laurent, Thierry Albiol, Loïc Bosland, et al. "IRSN R&D Actions on FP Behaviour for RCS, Containment and FCVS in Severe Accident Conditions." In 2016 24th International Conference on Nuclear Engineering. American Society of Mechanical Engineers, 2016. http://dx.doi.org/10.1115/icone24-61104.

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This paper deals with near past, ongoing and planned R&amp;D works on fission products (FPs) behaviour in Reactor Cooling System (RCS), containment building and in Filtered Containment Venting Systems (FCVS) for severe accident (SA) conditions. For the last topic, in link with the Fukushima post-accident management and possible improvement of mitigation actions for such SA, the FCVS topic is again on the agenda (see Status Report on Filtered Containment Venting, OECD/NEA/CSNI, Report NEA/CSNI/R(2014)7, 2014.) with a large interest at the international scale. All the researches are collaborativ
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