Academic literature on the topic 'Solid Acids Catalyst'

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Journal articles on the topic "Solid Acids Catalyst"

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Manayil, Jinesh, Adam Lee, and Karen Wilson. "Functionalized Periodic Mesoporous Organosilicas: Tunable Hydrophobic Solid Acids for Biomass Conversion." Molecules 24, no. 2 (2019): 239. http://dx.doi.org/10.3390/molecules24020239.

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The catalytic deoxygenation of bio-based feedstocks to fuels and chemicals presents new challenges to the catalytic scientist, with many transformations either performed in or liberating water as a byproduct during reaction. The design of catalysts with tunable hydrophobicity to aid product and reactant adsorption or desorption, respectively, is vital for processes including (trans)esterification and condensation reactions employed in sustainable biodiesel production and bio-oil upgrading processes. Increasing surface hydrophobicity of catalyst materials offers a means to displace water from t
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Lotfi, Samira, Daria C. Boffito, and Gregory S. Patience. "Gas–solid conversion of lignin to carboxylic acids." Reaction Chemistry & Engineering 1, no. 4 (2016): 397–408. http://dx.doi.org/10.1039/c6re00053c.

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Wilson, Karen, and James H. Clark. "Solid acids and their use as environmentally friendly catalysts in organic synthesis." Pure and Applied Chemistry 72, no. 7 (2000): 1313–19. http://dx.doi.org/10.1351/pac200072071313.

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Tightening environmental legislation is driving the fine and speciality chemicals industries to consider alternative processes that avoid the use of conventional mineral acids. The use of heterogeneous catalysts in these processes would vastly simplify catalyst removal, minimizing the amount of waste formed. However, diffusion limitation of liquids within porous solids dictates that effective solid acids for liquid-phase reactions require the use of mesoporous materials <20_100Å. Recent developments in materials chemistry has led to the discovery of a family of ordered mesoporous silica
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Li, Wei Xing, Ying Xiang Ni, and Wei Hong Xing. "Synthesis of Sulfated Zirconia Solid Acids and their Activities for Hydrolysis of Ethyl Lactate." Advanced Materials Research 233-235 (May 2011): 1529–33. http://dx.doi.org/10.4028/www.scientific.net/amr.233-235.1529.

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A kind of solid acid (sulfated zirconia) was proposed to be used as the catalyst for the hydrolysis of ethyl lactate because esterification-hydrolysis was usually applied to produce lactic acid of high purity. The sulfated zirconia was prepared via a simple chemical precipitation and impregnation approach. The prepared catalysts were characterized by means of XRD, TG-DSC, FT-IR, and NH3-TPD. Catalytic activity of the prepared catalysts was evaluated by the hydrolysis reaction of ethyl lactate. The characterization results showed that the prepared sulfated zirconia was of tetragonal phase at th
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Stojkovic, N., M. Vasic, M. Marinkovic, et al. "A comparative study of n-hexane isomerization over solid acids catalysts: Sulfated and phosphated zirconia." Chemical Industry and Chemical Engineering Quarterly 18, no. 2 (2012): 209–20. http://dx.doi.org/10.2298/ciceq110602062s.

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Two series of zirconia based catalysts promoted with either sulfates or phosphates were prepared, calcined at different temperatures (600 and 700?C) and evaluated for the n-hexane isomerization reaction. The catalysts with different concentrations of sulfates or phosphates (4 or 10 wt. %) were characterized by BET, XRD, SEM methods, and total acidity was evaluated by using the Hammett indicators. Their final catalytic performances were correlated with their physical-chemical properties (surface, structural, textural and morphological). It was found that sulfated zirconia catalyst calcined at l
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Badday, Ali Sabri, Ahmad Zuhairi Abdullah, and Keat Teong Lee. "Application of Heteropolyacid-Based Heterogeneous Catalysts for Conversion of Oleochemicals into Renewable Fuels and other Value-Added Products." Materials Science Forum 757 (May 2013): 1–24. http://dx.doi.org/10.4028/www.scientific.net/msf.757.1.

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Oleochemicals offer viable choices to replace petrochemicals in a wide range of applications such as fuels, lubricants and surfactants. Many of the conversions require the use of suitable solid acids as the catalysts. The chemical and physical properties of the feedstock in oleochemical processes often result in difficulties and challenges that limit the success. Large amount of free fatty acids and high water content create barriers towards the successful use of broad range of oleochemicals as raw materials. To overcome this problem, efforts have been dedicated to the development of new techn
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Villemin, Didier, Nathalie Bar, Mohamed Hammadi, and Messaoud Hachemi. "Liquid and Solid Acids as Catalysts for the Thiele–Winter reaction of Menadione." Journal of Chemical Research 2000, no. 7 (2000): 356–58. http://dx.doi.org/10.3184/030823400103167642.

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Liquid acid such as perchloric acid, chlorosulfonic or triflic acid can effectively replace sulfuric acid as a catalyst in Thiele–Winter reaction of menadione. Solid acids like zeolites and heteropolyacids are described for the first time as catalysts in Thiele–Winter reaction. The two step sequence (Thiele–Winter), saponification–oxidation) constitutes a new synthesis of the antibiotic phthiocol from menadione.
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Alsalme, Ali, Aliyah A. Alsharif, Hamda Al-Enizi, et al. "Probing the Catalytic Efficiency of Supported Heteropoly Acids for Esterification: Effect of Weak Catalyst Support Interactions." Journal of Chemistry 2018 (July 24, 2018): 1–10. http://dx.doi.org/10.1155/2018/7037461.

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Supported heteropoly acids are an interesting class of solid acid catalysts which possess flexible structure and super acidic properties essentially required for the oil-based biodiesel production. In this study, a series of catalysts containing 25 wt.% of heteropolytungstate (HPW) supported on various clays or SiO2 were prepared, and their catalytic efficiency was evaluated for esterification of acetic acid with heptanol. The as-prepared catalysts were characterized by various techniques including FT-IR spectroscopy, thermogravimetric analysis, X-ray diffraction, scanning electron microscopy,
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Xie, Wenlei, Chunli Gao, and Hongyan Wang. "Biodiesel Production from Low-Quality Oils Using Heterogeneous Cesium Salts of Vanadium-Substituted Polyoxometalate Acid Catalyst." Catalysts 10, no. 9 (2020): 1060. http://dx.doi.org/10.3390/catal10091060.

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This research aims at developing an efficient and reusable catalyst to improve biodiesel production processes. To achieve this, a vanadium-substituted polyoxometalate (POM) acid, namely H6PV3MoW8O40, was firstly prepared, and then the heterogenzation of the homogeneous Keggin-type heteropoly acids was performed by the partial proton substitution by monovalent large cesium cations with the formation of solid Cs2H4PV3MoW8O40 catalysts. Several techniques, such as X-ray diffractometer, Fourier transform infrared, coupled plasma–atomic emission spectrometry, Diffuse reflectance ultraviolet–visible
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Noda, Hiroto, Ken Motokura, Wang-Jae Chun, Akimitsu Miyaji, Sho Yamaguchi, and Toshihide Baba. "Heterogeneous double-activation catalysis: Rh complex and tertiary amine on the same solid surface for the 1,4-addition reaction of aryl- and alkylboronic acids." Catalysis Science & Technology 5, no. 5 (2015): 2714–27. http://dx.doi.org/10.1039/c5cy00133a.

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Dissertations / Theses on the topic "Solid Acids Catalyst"

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Gomes, Glaucio José. "Estudo experimental e teórico de zeólitas H-BETA e H-ZSM-5 na produção de ésteres alquílicos." Universidade Estadual do Oeste do Parana, 2016. http://tede.unioeste.br:8080/tede/handle/tede/809.

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Made available in DSpace on 2017-07-10T15:14:40Z (GMT). No. of bitstreams: 1 Glaucio_J_Gomes.pdf: 2760994 bytes, checksum: ed1586b3de70d1981cd1f4c6b68eb593 (MD5) Previous issue date: 2016-04-07<br>Coordenação de Aperfeiçoamento de Pessoal de Nível Superior<br>The application of zeolites in catalytic processes is of great interest in several chemical reactions that involves transformation of biomass into higher value-added products. In a similar sense, conversion of fatty acids into esters catalyzed by Hzeolites have sprouted a widely-varied academic and industrial attention due to it providi
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Alsalme, Ali Mohammed. "Solid acid catalysts based on heteropoly acids for conversion of renewable feedstocks." Thesis, University of Liverpool, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.539488.

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The aim of this work is to investigate homogeneous and heterogeneous catalysis by HPAs for the conversion of renewable feedstocks. This includes the preparation, characterisation and testing of a range of acidic solid materials such as bulk HPAs, CS2.sHo.sPW12040and the acidic composites comprising H3PW12040 (HPW) supported on Nb20s, Zr02 and Ti02. The HPW supported on Ti02, Zr02 and Nb20s were prepared by impregnation method and then characterised regarding their acid properties and the chemical structure of HPA on the catalyst surface, compared to "standard" HPA catalysts such as bulk and si
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Yamamoto, Takashi. "Studies on the Catalysis by New Solid Acid Catalysts and the Characterization." Kyoto University, 1999. http://hdl.handle.net/2433/77922.

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Hart, Mark Peter. "Solid acid catalysts for liquid phase reactions." Thesis, University of Huddersfield, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.270434.

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Cholerton, Mary. "Dehydration of alcohols using solid acid catalysts." Thesis, University of Southampton, 2014. https://eprints.soton.ac.uk/362638/.

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Solid acid catalysts were prepared through silicon substitution into aluminophosphate frameworks. Silicon incorporation was confirmed using solid state nuclear magnetic resonance spectroscopy. The nature of the acid sites generated was determined using Fourier Transform infrared spectroscopy. These materials were tested as catalysts for the dehydration of ethanol to ethylene at low operating temperatures. The materials were active for dehydration of ethanol to ethylene with significant differences observed between aluminophosphate frameworks both in terms of selectivity to the desired product
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Kaur, Jaspalne. "Friedel-Crafts acylation catalysed by heteropoly acids." Thesis, University of Liverpool, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.272747.

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Koster, Remko Misja. "Solid acid catalysed conversions of oleochemicals." [S.l. : Amsterdam : s.n.] ; Universiteit van Amsterdam [Host], 2003. http://dare.uva.nl/document/87387.

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Price, Peter Mark. "Aromatic alkylations catalysed by aluminium chloride modified mesoporous silica." Thesis, University of York, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.298443.

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Chambon, Flora. "Transformation de la cellulose par catalyse hétérogène." Phd thesis, Université Claude Bernard - Lyon I, 2011. http://tel.archives-ouvertes.fr/tel-00829774.

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La cellulose, bio-polymère composé d'unités glucose, est un composé largement disponible au sein de la biomasse lignocellulosique. Sa dépolymérisation sélective en synthons se heurte cependant à sa forte résistance aux transformations chimiques du fait de sa structure semi-cristalline. L'objectif de la thèse est d'étudier la transformation de la cellulose par catalyse hétérogène. Il a été montré qu'une dépolymérisation partielle de la cellulose en milieu aqueux était promue par les protons issus de l'autoprotolyse de l'eau à 190°C. L'ajout d'un catalyseur solide ayant une acidité de BrØnsted f
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Frattini, Lucia. "Polyoxometalates as solid acid catalysts for sustainable chemistry." Thesis, Aston University, 2017. http://publications.aston.ac.uk/33384/.

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Polyoxometalates, also known as heteropolyacids (HPA), are solid acids widely utilised in heterogeneous catalysis. The physicochemical properties of HPAs facilitate surface-type or bulk-type reactions, dependent on substrate polarity. For the latter, the gas-phase dehydration of ethanol was investigated representing an environmentally friendly solution to produce bio-ethylene, a key compound to the chemical industry; while for the former, the solventless liquid-phase isomerisation of α-pinene was studied due to the widespread applications of its derivates. Supported HPAs, exhibiting the Keggin
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Books on the topic "Solid Acids Catalyst"

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Elings, Jacob Antonius. Solid-acid catalysed reactions with epoxides and allyl aryl ethers. Delft University Press, 1997.

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Kōzō, Tanabe, ed. New solid acids and bases: Their catalytic properties. Kodansha, 1989.

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Li, Xiaohong. Preparation and characterization of sulfated ZrO₂ solid acid catalysts. 1994.

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Solid Acid Catalysis From Fundamentals To Applications. Pan Stanford Publishing Pte Ltd, 2014.

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New solid acids and bases: Their catalytic properties (Studies in surface science and catalysis). [Distributors] for the U.S.A. and Canada, Elsevier Science Pub. Co, 1989.

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United States. National Aeronautics and Space Administration., ed. Active sites and roles of solid acid base catalysts. National Aeronautics and Space Administration, 1988.

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K, Tanaabe, and United States. National Aeronautics and Space Administration., eds. A new method of determining acid base strength distribution and a new acidity-basicity scale for solid catalysts: The strongest point, Ho. National Aeronautics and Space Administration, 1988.

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Book chapters on the topic "Solid Acids Catalyst"

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Cho, Hyejin, Christian Schäfer, and Béla Török. "Microwave-Assisted Solid Acid Catalysis." In Microwaves in Catalysis. Wiley-VCH Verlag GmbH & Co. KGaA, 2015. http://dx.doi.org/10.1002/9783527688111.ch10.

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Tanabe, Kozo. "Acid-Base Bifunctional Catalysis." In Acidity and Basicity of Solids. Springer Netherlands, 1994. http://dx.doi.org/10.1007/978-94-011-0986-4_16.

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Toba, Makoto, Atsuhiko Katayama, Genki Takeuchi, Shu-ichi Niwa, Fujio Mizukami, and Shuichi Mitamura. "Isopropylation of Naphthalene over Solid Acid Catalysts." In ACS Symposium Series. American Chemical Society, 1999. http://dx.doi.org/10.1021/bk-2000-0738.ch021.

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Pai, Shivanand M., Raj Kumar Das, S. A. Kishore Kumar, Lalit Kumar, Ashvin L. Karemore, and Bharat L. Newalkar. "Emerging Trends in Solid Acid Catalyst Alkylation Processes." In Catalysis for Clean Energy and Environmental Sustainability. Springer International Publishing, 2021. http://dx.doi.org/10.1007/978-3-030-65021-6_4.

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Xu, Jun, Qiang Wang, Shenhui Li, and Feng Deng. "Solid-State NMR Characterization of Acid Properties of Zeolites and Solid Acid Catalysts." In Lecture Notes in Chemistry. Springer Singapore, 2019. http://dx.doi.org/10.1007/978-981-13-6967-4_5.

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Takagaki, Atsushi, Shun Nishimura, and Kohki Ebitani. "Mechanistic Studies of Solid Acids and Base-Catalyzed Clean Technologies." In Heterogeneous Catalysts for Clean Technology. Wiley-VCH Verlag GmbH & Co. KGaA, 2013. http://dx.doi.org/10.1002/9783527658985.ch6.

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Corma, Avelino, and Agustín Martínez. "Transformation of Alkanes on Solid Acid and Bifunctional Catalysts." In Catalytic Activation and Functionalisation of Light Alkanes. Springer Netherlands, 1998. http://dx.doi.org/10.1007/978-94-017-0982-8_2.

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Ngaosuwan, Kanokwan. "Solid Acid Catalyst Derived from Coffee Residue for Biodiesel Production." In Renewable Energy in the Service of Mankind Vol I. Springer International Publishing, 2015. http://dx.doi.org/10.1007/978-3-319-17777-9_5.

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Shanbhag, G. V., Ankur Bordoloi, Suman Sahoo, B. M. Devassy, and S. B. Halligudi. "Supported Heteropoly Acids and Multicomponent Polyoxometalates as Eco-Friendly Solid Catalysts for Bulk and Fine Chemicals Synthesis." In Environmentally Benign Catalysts. Springer Netherlands, 2013. http://dx.doi.org/10.1007/978-94-007-6710-2_5.

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Petkovic, Lucia M., Daniel M. Ginosar, David N. Thompson, and Kyle C. Burch. "Application of Supercritical Fluids to Solid Acid Catalyst Alkylation and Regeneration." In ACS Symposium Series. American Chemical Society, 2007. http://dx.doi.org/10.1021/bk-2007-0959.ch013.

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Conference papers on the topic "Solid Acids Catalyst"

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"Esterification of Free Fatty Acids in Waste Oil Using a Carbon-based Solid Acid Catalyst." In 2nd International Conference on Emerging Trends in Engineering and Technology. International Institute of Engineers, 2014. http://dx.doi.org/10.15242/iie.e0514546.

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Kafuku, Gerald, Makme Mbarawa, Man Kee Lam, and Keat Teong Lee. "Optimized Preparation of Moringa Oleifera Methyl Esters Using Sulfated Tin Oxide as Heterogenous Catalyst." In ASME 2010 4th International Conference on Energy Sustainability. ASMEDC, 2010. http://dx.doi.org/10.1115/es2010-90503.

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Fatty acid methyl esters (biodiesel), prepared from transesterification of vegetable oils or animal fats, have gained great importance in substituting petroleum based diesel for combating environmental problems and higher diesel prices. Moringa oleifera fatty acids are among the newly investigated potentials for biodiesel production in recent years. In getting rid of soap formation and thus large waste washing water from biodiesel produced from homogenous catalysts, the use of heterogeneous catalysts is currently preferred due to easily separation and purification of the final products. In thi
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Bond, Gary, A. Halman, H. Eccles, et al. "A COMPARATIVE STUDY OF MICROWAVE AND BARRIER DISCHARGE PLASMA FOR THE REGENERATION OF SPENT ZEOLITE CATALYSTS." In Ampere 2019. Universitat Politècnica de València, 2019. http://dx.doi.org/10.4995/ampere2019.2019.9936.

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Due to their acid characteristics and pore structure, which can induce high product selectivity; zeolite catalysts are used extensively in industry to catalyse reactions involving hydrocarbons. However, these catalysts can suffer from deactivation due to cracking reactions that result in the deposition of carbon leading to poisoning of the acid sites and blocking of the pores [1]. Depending upon the reaction and the particular catalyst involved this deactivation may take place over several months or even years but in some cases occurs in minutes. Therefore, zeolite catalysts are frequently rea
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Yang, Liao, Li Yan, Tong Peijie, Zhao Shilin, and Liao Xuepin. "A Novel Fibrous Zirconium Sulfate Solid Acid Catalyst for Esterification Reaction." In 2011 International Conference on Computer Distributed Control and Intelligent Environmental Monitoring (CDCIEM). IEEE, 2011. http://dx.doi.org/10.1109/cdciem.2011.114.

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Fong, Y. S., C. H. Ngoo, J. H. Sim, and P. F. Lee. "Esterification of Palm Fatty Acid Distillate (PFAD) for Biodiesel Production Using Heterogeneous Solid Acid Catalysts." In Annual International Conference on Chemistry, Chemical Engineering and Chemical Process (CCECP 2014). GSTF, 2014. http://dx.doi.org/10.5176/2301-3761_ccecp14.09.

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Lim, Steven, Pang Yean Ling, and Leong Weng Jun. "Synthesis and characterisation of carbon-based solid acid catalyst from Jatropha biomass for biodiesel production." In INTERNATIONAL SYMPOSIUM ON GREEN AND SUSTAINABLE TECHNOLOGY (ISGST2019). AIP Publishing, 2019. http://dx.doi.org/10.1063/1.5126587.

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Krishnan, Shamala Gowri, Fei Ling Pua, Kumaran Palanisamy, and Sharifah Nabihah Syed Jaafar. "Oil palm EFB supported solid acid catalyst for esterification reaction: Optimization and parametric effects study." In PROCEEDINGS OF THE 3RD INTERNATIONAL CONFERENCE ON AUTOMOTIVE INNOVATION GREEN ENERGY VEHICLE: AIGEV 2018. Author(s), 2019. http://dx.doi.org/10.1063/1.5085990.

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Jenie, S. N. Aisyiyah, Anis Kristiani, Kustomo, Sabar Simanungkalit, and Dieni Mansur. "Preparation of nanobiochar as magnetic solid acid catalyst by pyrolysis-carbonization from oil palm empty fruit bunches." In PROCEEDINGS OF THE 3RD INTERNATIONAL SYMPOSIUM ON APPLIED CHEMISTRY 2017. Author(s), 2017. http://dx.doi.org/10.1063/1.5011875.

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Diana, Nur Indah Fajar Mukti, and Arif Hidayat. "Performance of Indion ion exchange resin as solid catalyst for the esterification of oleic acid with glycerol." In THE 11TH REGIONAL CONFERENCE ON CHEMICAL ENGINEERING (RCChE 2018). Author(s), 2019. http://dx.doi.org/10.1063/1.5095045.

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Ying Chen, Xue Sun, Baohui Wang, and Hui Li. "The research of rare earth modification on solid acid SO42−/ZrO2 catalysts." In Environment (ICMREE). IEEE, 2011. http://dx.doi.org/10.1109/icmree.2011.5930835.

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Reports on the topic "Solid Acids Catalyst"

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Haw, James F. NMR Computational Studies of Solid Acidity/Fundamental Studies of Catalysis by Solid Acids. Office of Scientific and Technical Information (OSTI), 2008. http://dx.doi.org/10.2172/1049372.

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Williamson, R., J. Holladay, M. Jaffe, and D. Brunelle. Continuous Isosorbide Production From Sorbitol Using Solid Acid Catalysis. Office of Scientific and Technical Information (OSTI), 2006. http://dx.doi.org/10.2172/892556.

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Allenger, V. M. Synthesis of liquid fuels by reacting acetylene over solid acid catalysts. Natural Resources Canada/ESS/Scientific and Technical Publishing Services, 1985. http://dx.doi.org/10.4095/302609.

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