Academic literature on the topic 'Stereoselective reaction'

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Journal articles on the topic "Stereoselective reaction"

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Misra, Anup Kumar, Arin Gucchait, and Monalisa Kundu. "Synthesis of Pentasaccharide Repeating Unit Corresponding to the Cell Wall O-Polysaccharide of Salmonella enterica O55 Strain Containing a Rare Sugar 3-Acetamido-3-deoxy-d-fucose." Synthesis 53, no. 19 (2021): 3613–20. http://dx.doi.org/10.1055/s-0037-1610777.

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AbstractA pentasaccharide repeating unit corresponding to the cell wall O-antigen of Salmonella enterica O55 containing a rare sugar, 3-acetamido-3-deoxy-d-fucose has been synthesized as its p-methoxyphenyl glycoside using a sequential stereoselective glycosylation strategy. A suitably functionalized 3-azido-3-deoxy-d-fucose thioglycoside derivative was prepared in very good yield and used in the stereoselective glycosylation reaction. Functionalized monosaccharide intermediates were prepared judiciously and stereoselectively assembled to get the desired pentasaccharide derivative in excellent
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M, Heravi; Majid, and A.T. Kal-Koshvandi. "Applications of Dainshefsky's Dienes in the Asymmetric synthesis of Aza-Diels-Alder Reaction." Chemical Record 19, no. 2 (2018): 550–600. https://doi.org/10.1002/tcr.201800066.

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Asymmetric hetero-Diels-Alder (AHDA) reactions provide a multitude of opportunities for the highly efficient, regio- and stereoselective construction of various heterocycles in enantiomerically pure form. The asymmetric aza-Diels-Alder (A-aza-DA) reaction using diversely hetero-dienophiles and hetero-dienes have been increasingly developed as a valuable method for the synthesis of functionalized nitrogen ring systems. The purpose of this review is to give a detailed discussion of the A-aza-DA reaction particularly, the stereoselective reactions of imines as dienophiles with Dainshefsky dienes
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Rossi, Sergio, Tiziana Benincori, Laura Maria Raimondi, and Maurizio Benaglia. "3,3′-Bithiophene-Based Chiral Bisphosphine Oxides as Organocatalysts in Silicon-Derived Lewis Acid Mediated Reactions." Synlett 31, no. 06 (2020): 535–46. http://dx.doi.org/10.1055/s-0039-1690777.

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This account summarizes the development of new biheteroaromatic chiral bisphosphine oxides. 3,3′-Bithiophene-based phosphine oxides (BITIOPOs) have been successfully used as organocatalysts to promote Lewis base catalyzed, Lewis acid mediated stereoselective transformations. These highly electron-rich compounds, in combination with trichorosilyl derivatives (allyltrichlorosilane and silicon tetrachloride), generate hypervalent silicon species that act as chiral Lewis acids in highly diastereo- and enantioselective organic reactions. Several relevant examples related to these applications are d
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Klegraf, Ellen, and Horst Kunz. "Stereoselective Synthesis of 3-Substituted and 3,4-Disubstituted Piperidine und Piperidin-2-one Derivatives." Zeitschrift für Naturforschung B 67, no. 4 (2012): 389–405. http://dx.doi.org/10.1515/znb-2012-0413.

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The stereoselective synthesis of 3-substituted and 3,4-disubstituted piperidine and piperidin-2-one derivatives was achieved starting from 2-pyridone. After N-galactosylation and subsequent O-silylation, nucleophilic addition of organometallic reagents proceeded with high regio- and stereoselectivity at 4-position. Substituents at position 3 were stereoselectively introduced by reaction of electrophiles with amide enolates of the N-galactosyl-2-piperidones.
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Penumati, Nageshwar Rao, та Nagaiah Kommu. "Stereoselective Synthesis of (+)-α-Conhydrine from R-(+)-Glyceraldehyde". Organic Chemistry International 2014 (20 жовтня 2014): 1–7. http://dx.doi.org/10.1155/2014/982716.

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Stereoselective synthesis of (+)-α-Conhydrine was accomplished from protected (R)-(+)-glyceraldehyde, a familiar carbohydrate predecessor. Our synthetic strategy featured the following two key reactions. One is Zn-mediated stereoselective aza-Barbier reaction of imine 6 with allyl bromide to afford chiral homoallylic amine 7, and the other is ring-closing metathesis.
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Woo, Simon, Masood Parvez, and Brian A. Keay. "Regio- and stereoselective ring openings of unsymmetrical oxatricyclo adducts." Canadian Journal of Chemistry 75, no. 6 (1997): 665–80. http://dx.doi.org/10.1139/v97-081.

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SN2′ ring-opening reactions of a number of substituted 11-oxatricyclo[6.2.1.01,6]undec-9-en-5-ones prepared via the intramolecular Diels–Alder reaction employing a furan diene (IMDAF) are reported. Primary, secondary, and tertiary organolithium reagents were capable of effecting the ring-opening reaction, while methyllithium required activation before any ring opening was observed. Hydride reagents, organocuprates, and Grignard reagents were generally ineffective. The ring-opening reaction was highly regio- and stereoselective for attack at C9syn to the bridging oxygen atom provided that C8 wa
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Schultz, Jeremy F., Bing Yang, and Nan Jiang. "Direct observation of the geometric isomer selectivity of a reaction controlled via adsorbed bromine." Nanoscale 12, no. 4 (2020): 2726–31. http://dx.doi.org/10.1039/c9nr09857g.

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Liu, Yuxiao, Yongming Deng, Peter Y. Zavalij, Renhua Liu та Michael P. Doyle. "An efficient route to highly enantioenriched tetrahydroazulenes and β-tetralones by desymmetrization reactions of δ,δ-diaryldiazoaceto-acetates". Chemical Communications 51, № 3 (2015): 565–68. http://dx.doi.org/10.1039/c4cc08255a.

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Ross, Günther, та Ivar Ugi. "Stereoselective syntheses of α-amino acid and peptide derivatives by the U-4CR of 5-desoxy-5-thio-D-xylopyranosylamine". Canadian Journal of Chemistry 79, № 12 (2001): 1934–39. http://dx.doi.org/10.1139/v01-186.

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Since 1961, the synthesis of α-amino acids derivatives by the four-component reaction of isocyanides (U-4CR) as a one-pot reaction has been developed. Only recently it was found that a variety of these α-amino acids compounds can be formed stereoselectively by the U-4CR using 1-amino-5-deoxy-5-thio-2,3,4-tri-O-isobutanoyl-β-D-xylopyranose as the amine component. The stereoselectivity inducing auxiliary 5-desoxy-5-thio-D-xylopyranosyl group of the so-formed products can be replaced selectively by hydrogen.Key words: stereoselective U-4CR, chiral amine component, amino carbohydrate, α-amino acid
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Cantin, Michel, Yao-Chang Xu, and Pierre Deslongchamps. "Stereocontrolled construction of A.B.C.[6.6.6] tricycle via transannular Diels–Alder reaction of 14-membered triene macrocycle." Canadian Journal of Chemistry 68, no. 12 (1990): 2144–52. http://dx.doi.org/10.1139/v90-329.

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The synthesis of the four acyclic trienes 11a, b and 20a, b is reported. The tandem macrocyclization and stereoselective transannular Diels–Alder reaction of acyclic trienes 11b (trans-trans-cis) and 20b (trans-trans-trans) were observed in the presence of Cs2CO3 at 85 °C to give tricycles 30 (TST) and 32 (CAT) respectively. However, treatment of acyclic trienes 11a (cis-trans-cis) and 20a (cis-trans-trans) under the same conditions yielded the 14-membered macrocycles 21 and 23, which were stereoselectively transformed at 250 °C into tricycles 22 (CST) and 24 (CAT) respectively in excellent yi
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Dissertations / Theses on the topic "Stereoselective reaction"

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Millet, Julien. "Approaches towards a stereoselective Nicholas reaction." Thesis, Kingston University, 2006. http://eprints.kingston.ac.uk/20379/.

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This programme of work has focused on developing ways of inducing stereoselectivity into the Nicholas reaction towards the synthesis of natural products. The first chapter of the thesis reviews the developments ofthe Nicholas reaction since its discovery in 1972 as well as other applications of cobalt clusters. The following chapter describes chirality and various approaches towards asymmetric synthesis. Chapter 3 details our investigations as well as the results that we achieved in the two ' areas we explored. The first part of the project attempted to determine which oxazolidinone derivative
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Rutherford, Alistair Peter. "Stereoselective synthesis of #Beta#-hydroxycyclohexanones using the anionic oxy-cope rearrangement." Thesis, University of Glasgow, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.299981.

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LOPS, CARMINE. "Development of organocatalytic and stereoselective reactions." Doctoral thesis, Università degli Studi di Trieste, 2018. http://hdl.handle.net/11368/2918472.

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Il focus di questo dottorato è stato lo sviluppo di due reazioni organocatalitiche e stereoselettive: le addizioni di sulfa-Michael e le condensazioni di Darzens poiché rappresentano degli approcci sintetici interessanti per la sintesi di farmaci chirali e, nell’ambito farmaceutico, ci sono pochi principi attivi (API) sintetizzati con reazioni di SMAs e/o di Darzens organocatalitiche e stereoselettive. Nell’ambito delle addizioni di sulfa-Michael (SMAs), la catalisi mediata da molecole bifunzionali donatrici di legami ad idrogeno (HBD) rappresenta un approccio interessante per l'attivazione si
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Thomas, Jermaine D. O. "Highly regio and stereoselective hydroxy-directed Diels-Alder reaction." Thesis, University of Ottawa (Canada), 2002. http://hdl.handle.net/10393/6123.

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The Diels-Alder reaction has proven to be an invaluable tool in the arsenal of the synthetic organic chemist for the relatively facile construction of cyclic cores. However, the utility of this reaction is not without its shortcomings. Lack of regio and stereoselectivity are two problems that are often encountered with asymmetric dienophiles. Although Lewis acids have been successfully employed to control the selectivity of Diels-Alder reactions involving activated dienophiles, there is little precedent in the literature for their use with dienes containing a tertiary alcohol functionality, du
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Dawson, Graham John. "Studies on the stereoselective palladium-catalysed allylic substitution reaction." Thesis, Loughborough University, 1995. https://dspace.lboro.ac.uk/2134/31866.

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This thesis contains the preparation of a new design of ligand for the palladium catalysed allylic substitution reaction. The phosphine oxazoline ligands detailed in the thesis give high levels of enantiocontrol when used in conjunction with symmetrical allyl systems in the palladium catalysed allylic substitution reaction. For unsymmetrical allyl systems the palladium catalysed allylic substitution process proceeds with complete regiocontrol and high levels of stereocontrol are again observed. The products from the palladium catalysed allylic substitution reaction can be readily converted to
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Beligny, Samuel Daniel Charles. "Stereoselective synthesis of tetrahydropyridines using the Diels-Alder reaction." Thesis, Imperial College London, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.414751.

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Takano, Toshiyuki. "SYNTHESIS OF CELLO-OLIGOSACCHARIDES -INFLUENCE OF SUBSTITUENT GROUPS ON STEREOSELECTIVE GLYCOSYLATION REACTION-." Kyoto University, 1990. http://hdl.handle.net/2433/78226.

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Cresswell, Mark. "The stereoselective Pictet-Spengler reaction and studies towards the total synthesis of ajmaline." Thesis, Keele University, 2013. http://eprints.keele.ac.uk/3816/.

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Due to their extensive and important medicinal properties, the indole alkaloids are an important class of natural products. A key step towards the total synthesis of indole alkaloids is the diastereoselective Pictet-Spengler reaction, which has enabled the total syntheses of a number of these natural products to be reported, one of which is the medicinally-important alkaloid ajmaline. Ajmaline is well studied and the previous attempts towards its synthetic preparation are described. During our investigations towards the asymmetric syntheses of ajmaline and other related indole alkaloids, it wa
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Herlé, Bart. "Stereoselective Cyclopropanations via Gold(I)-Catalyzed Retro-Buchner Reactions." Doctoral thesis, Universitat Rovira i Virgili, 2017. http://hdl.handle.net/10803/454770.

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La formació de carbens bencílics d’or(I) a partir de cicloheptatriens substituïts en la posició 7, a través de la reacció de retro-Buchner, ha aparegut recentment com una alternativa segura i versàtil a la descomposició de diazocompostos. No obstant, la formació de dits carbens requereix altes temperatures, limitant la seva aplicació. El treball d’aquest tesi doctoral s’ha dedicat a superar aquesta desavantatge i millorar la versatilitat de la transformació. Els derivats de 1H-ciclopropa[l]fenantrè, que s’assemblen al tautòmer norcaradiè del cicloheptatriè, es descomponen per donar lloc a
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Peace, Simon. "The stereoselective nitro-Mannich reaction and its application towards the synthesis of vicinal diamines." Thesis, University of Sheffield, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.287661.

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Books on the topic "Stereoselective reaction"

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Mahrwald, Rainer, ed. Modern Methods in Stereoselective Aldol Reactions. Wiley-VCH Verlag GmbH & Co. KGaA, 2013. http://dx.doi.org/10.1002/9783527656714.

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Ozawa, Yu. Copper(I)-Catalyzed Stereoselective Borylation Reactions. Springer Nature Singapore, 2023. http://dx.doi.org/10.1007/978-981-99-1098-4.

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Rodriguez, Jean, and Damien Bonne. Stereoselective multiple bond-forming transformations in organic synthesis. John Wiley & Sons, Inc., 2015.

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Wiktelius, Daniel. Asymmetric synthesis of dipeptidomimetics and phosphine-boranes: Routes involving stereoselective olefination, expoxidation, and lipase-catalysed reactions. Göteborg University, 2007.

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Dr, Werner Helmut Prof, and Sundermeyer Jörg, eds. Stereoselective reactions of metal-activated molecules: Proceedings of the second symposium held in Würzburg, September 21-23, 1994. Vieweg, 1995.

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Dawson, Graham John. Studies on the stereoselective palladium catalysed allylic substitution reaction. 1995.

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de Vries, J. G., K. Muñiz, G. Franciò, et al. Stereoselective Synthesis 1 Stereoselective Reactions of Carbon—Carbon Double Bonds. Georg Thieme Verlag KG, 2011. http://dx.doi.org/10.1055/sos-sd-201-00000.

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Aggarwal, V. K., Erick M. Carreira, P. Andrew Evans, Gary A. Molander, and Gary A. Molander. Stereoselective Synthesis 2: Stereoselective Reactions of Carbonyl and Imino Groups. Thieme Medical Publishers, Incorporated, 2011.

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Vries, Johannes de, Gary Molander, P. Andrew Evans, and Alois Fürstner. Stereoselective Synthesis Set: Stereoselective Reactions of Carbon-Carbon Double Bonds. Thieme Medical Publishers, Incorporated, 2011.

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Mahrwald, Rainer. Modern Methods in Stereoselective Aldol Reactions. Wiley & Sons, Incorporated, John, 2013.

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Book chapters on the topic "Stereoselective reaction"

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Gryko, Dorota, and Dominika Walaszek. "C-C Bond Formation by Aldol Reaction." In Stereoselective Organocatalysis. John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118604755.ch03.

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Zhang, Yong, and Wei Wang. "CC Bond Formation by Michael Reaction." In Stereoselective Organocatalysis. John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118604755.ch05.

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Khiar, Noureddine, Inmaculada Fernández, Ana Alcudia, Maria Victoria García, and Rocío Recio. "Reaction of Enolates." In Carbohydrates - Tools for Stereoselective Synthesis. Wiley-VCH Verlag GmbH & Co. KGaA, 2013. http://dx.doi.org/10.1002/9783527654543.ch3.

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Quinkert, G., and M. Grosso. "Progress in the Diels/Alder Reaction Means Progress in Steroid Synthesis." In Stereoselective Synthesis. Springer Berlin Heidelberg, 1994. http://dx.doi.org/10.1007/978-3-642-78496-5_6.

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Gallego, Mar Gómez, and Miguel A. Sierra. "Level 2 — Case 29 Stereoselective Debromination of Vicinal Dibromides." In Organic Reaction Mechanisms. Springer Berlin Heidelberg, 2004. http://dx.doi.org/10.1007/978-3-642-18788-9_29.

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Gallego, Mar Gómez, and Miguel A. Sierra. "Level 2 — Case 31 Stereoselective Synthesis of 2-Acylaziridines." In Organic Reaction Mechanisms. Springer Berlin Heidelberg, 2004. http://dx.doi.org/10.1007/978-3-642-18788-9_31.

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Cordes, Martin, and Markus Kalesse. "The Vinylogous Mukaiyama Aldol Reaction in Natural Product Synthesis." In Modern Methods in Stereoselective Aldol Reactions. Wiley-VCH Verlag GmbH & Co. KGaA, 2013. http://dx.doi.org/10.1002/9783527656714.ch2.

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Fujino, Haruka, and Masayuki Inoue. "Convergent Total Synthesis of Hikizimycin: Development of New Radical-Based and Protective Group Strategies." In Modern Natural Product Synthesis. Springer Nature Singapore, 2024. http://dx.doi.org/10.1007/978-981-97-1619-7_6.

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AbstractHikizimycin (1) is an architecturally complex nucleoside antibiotic with potent anthelmintic and antibacterial activities. Its unique 4-amino-4-deoxyundecose core (hikosamine) includes a C1–C11 linear chain with ten contiguous stereocenters flanked with nucleobase (cytosine) and 3-amino-3-deoxyglucose (kanosamine) at the C1 and C6O positions, respectively. These structural features make its chemical construction exceptionally challenging. This chapter describes our successful efforts leading to convergent total synthesis of 1 from three hexose derivatives (5b, 11-β, and 12) and bis-TMS
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"Stereoselective Reaction." In Organic Stereochemistry. Wiley-VCH Verlag GmbH & Co. KGaA, 2015. http://dx.doi.org/10.1002/9783527688166.ch9.

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Robinson, Michael J. T. "Stereospecific and stereoselective reactions." In Organic Stereochemistry. Oxford University Press, 2000. http://dx.doi.org/10.1093/hesc/9780198792758.003.0006.

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This chapter displays a number of ways in which the terms stereospecific and stereoselective have been used by some chemists. It contends that a reaction is stereospecific if two stereoisomeric reactants give distinct stereoisomeric products. In contrast, a reaction is stereoselective if stereoisomeric products are formed in unequal amounts irrespective of any stereoisomerism in the reactant(s). The chapter uses stereospecific to describe reactions in which the stereochemical outcome is determined by the orbitals of the functional group(s) necessarily involved in the reaction. The chapter then
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Conference papers on the topic "Stereoselective reaction"

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Gonçalves, Vanessa P., Rodrigo M. S. Justo, and Giovanni W. Amarante. "Chiral Brønsted Acid Catalyzed Highly Stereoselective Mannich-type reaction of Azlactone with Aldimines." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_20139216537.

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Netscher, Thomas, and Ann-Christine Loesche. "On the Mechanism of the Acid-Catalyzed Stereoselective Chroman Cyclization Reaction." In The 20th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2016. http://dx.doi.org/10.3390/ecsoc-20-b005.

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Marini, Francesca, Valentina Frullini, Silvia Sternativo, Luana Bagnoli, and Claudio Santi. "Stereoselective synthesis of cyclopropanes from vinyl selenones via a Michael-initiated ring closure reaction." In The 17th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2013. http://dx.doi.org/10.3390/ecsoc-17-a011.

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Fernandes, Alessandra A. de G., Bruna L. Papa, and Alessandro Rodrigues. "Virtual Screening of New Potential Organocatalysts for Stereoselective Nitroaldol Reactions." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_201391516283.

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Fulas, Marcia, Jéssica de S. Figueiredo, and Alessandro Rodrigues. "Organocatalysts: Design, Synthesis and Application in Stereoselective Domino-Michael/Henry Reactions." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_2013915201517.

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Oliveira, Caio C., Emerson Andrade Ferreira dos Santos, and Carlos Roque Duarte Correia. "Substrate Directable Heck-Matsuda Reactions: A Short and Stereoselective Total Synthesis of S1P1 Agonist." In 14th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-14bmos-r0163-1.

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Bhushan, Indu. "Efficient media for high production of microbial lipase from Bacillus subtilis (BSK-L) using response surface methodology for enantiopure synthesis of drug molecules." In 2nd International Scientific Conference "Plants and Microbes: the Future of Biotechnology". PLAMIC2020 Organizing committee, 2020. http://dx.doi.org/10.28983/plamic2020.044.

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Lipases are a multipurpose enzyme that holds a significant position in industrial applications due to its ability to catalyse a large number of reactions such as hydrolysis, esterification, interesterification, transesterification which makes it a potential candidate. It is also used for the separation of chiral drugs from the racemic mixture and this property of lipase is considered very important in pharmaceutical industries for the synthesis of enantiopure bioactive molecules. Assuming the tremendous importance of lipases, as stereoselective biocatalysts, in pharmaceuticals and various othe
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Reports on the topic "Stereoselective reaction"

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Brown, Herbert C., and Ashok M. Salunkhe. Stereoselective Synthesis of cis-and trans-Beta,Gamma-Unsaturated Carboxylic Esters via Reaction of Alkenyldichloroboranes with Ethyl Diazoacetate. Defense Technical Information Center, 1991. http://dx.doi.org/10.21236/ada239049.

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