Relevant bibliographies by topics / Thionyl chloride

Contents

  1. Journal articles
  2. Dissertations / Theses
  3. Books
  4. Book chapters
  5. Conference papers
  6. Reports

Academic literature on the topic 'Thionyl chloride'

Author: Grafiati
Published: 4 June 2021
Last updated: 25 July 2025

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Journal articles on the topic "Thionyl chloride"

1

Janků, Josef, Jiří Burkhard, and Luděk Vodička. "Reaction of adamantanone, diamantanone, and their derivatives with thionyl chloride." Collection of Czechoslovak Chemical Communications 52, no. 8 (1987): 2028–34. http://dx.doi.org/10.1135/cccc19872028.

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In reaction of adamantanone, diamantanone, and their chloro or oxo derivatives with thionyl chloride the oxo group is replaced with two chlorine atoms under formation of geminal dichloro derivatives. The presence of a chlorine atom or an oxo group in both ketones reduces the reaction rate. The reaction rate decreases with decreasing distance between the substituent and the carbonyl group. Ketones with chlorine atom in α- or β-axial position do not react with thionyl chloride. The reaction is accelerated by hydrogen chloride whereas in the presence of pyridine no reaction was observed.
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Bell, KH, and LF Mccaffery. "Chlorosulfination With Thionyl Chloride of Aromatic Methyl Ethers Containing Other Functional Groups." Australian Journal of Chemistry 45, no. 8 (1992): 1213. http://dx.doi.org/10.1071/ch9921213.

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Further studies on the direct chlorosulfination with thionyl chloride of aromatic methyl ethers are described. In some cases (e.g. 1,6-dimethoxynaphthalene, 1,2,4 trimethoxybenzene, ethyl 3,5- and 3,7-dimethoxy-2-naphthoate, 3,5-dimethoxyphenyl benzoate) good yields of the sulfinyl chlorides were obtained but in others (e.g. 1,2-dimethoxybenzene, 3,5-dimethoxybenzyl acetate) the products (e.g. thiosulfonates, sulfides) were those from further reactions of the initial sulfinyl chloride. Aromatic methyl ethers containing functional groups which normally undergo reaction with thionyl chloride (e.
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Burmistrov, K. S., B. V. Murashevych, M. V. Toropin, D. O. Stepanskyi, and V. V. Yarovyi. "Synthesis of polymeric sodium N-chlorosulphonamide with increased active chlorine content." Voprosy Khimii i Khimicheskoi Tekhnologii, no. 6 (December 2024): 25–29. https://doi.org/10.32434/0321-4095-2024-157-6-25-29.

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Treatment of styrene-divinylbenzene sulfonated cation exchangers with a small amount of thionyl chloride prior to reaction with chlorosulfonic acid significantly facilitates the production of sulfochlorides from polymeric sulfonic acids and their salts. Polymeric sulfochlorides were synthesized by sequential treatment of gel and macroporous styrene-divinylbenzene cation exchangers in Na and H forms with thionyl chloride and chlorosulfonic acid. Transformation of these sulfochlorides into sulfamides via reaction with ammonia, followed by treatment with gaseous chlorine, yielded polymeric sodium
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Janků, Josef, Jiří Burkhard, and Luděk Vodička. "Reaction of 5-oxo-4-oxahomoadamantane with thionyl chloride." Collection of Czechoslovak Chemical Communications 52, no. 3 (1987): 752–55. http://dx.doi.org/10.1135/cccc19870752.

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On reaction with thionyl chloride 5-oxo-4-oxahomoadamantane gives rise to a mixture of 4a-chloro- and 4e-chloro-2-adamantanone. The carbonyl group of chloroadamantane further reacts with thionyl chloride under formation of 2,2,4e-trichloroadamantane. In the same way adamantanone reacts with thionyl chloride, giving rise to 2,2-dichloroadamantane.
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Sari, Asdani Muatika, Ani Suryani, Puspa Dewi Lotulung, and Silvester Tursiloadi. "Preparation of Alkyl Halide as Intermediate Compound in Synthesis Cationic Surfactant Alkyl Trimethyl Ammonium Chloride." Jurnal Kimia Terapan Indonesia 19, no. 1 (2017): 25–28. http://dx.doi.org/10.14203/jkti.v19i1.327.

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Cationic surfactant alkyl trimethyl ammonium chloride was synthesized by quartenerisation of tertiary amines. Materials used in quartenerization are tertiary amine and alkyl halide. Alkyl halide is a hydrocarbon derivative in which one or more hydrogen is replaced with halogen. In this research, thionyl chloride is used as a reactant . Thionyl chloride (SOCl2) is often used because it is easier to make, the yield is greater and byproducts are volatile. Alkyl halide is synthesized from the reaction of hexadecyl alcohol with thionyl chloride (SOCl2) at a temperature of 80 C for 24 hours in a ref
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Merke, Ilona, and Helmut Dreizler. "Nuclear Quadrupole Coupling in the Rotational Spectrum of Thionyl Chloride." Zeitschrift für Naturforschung A 47, no. 11 (1992): 1150–52. http://dx.doi.org/10.1515/zna-1992-1111.

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El-Sakka, Ibrahim A., and Nasser A. Hassan. "Synthetic uses of thionyl chloride." Journal of Sulfur Chemistry 26, no. 1 (2005): 33–97. http://dx.doi.org/10.1080/17415990500031187.

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Li, Mingdong. "Thionyl Chloride - A Versatile Reagent." Synlett 2007, no. 16 (2007): 2605–6. http://dx.doi.org/10.1055/s-2007-986648.

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Hepburn, Timothy W., and Gordon Lowe. "Synthesis of [18O]thionyl chloride." Journal of Labelled Compounds and Radiopharmaceuticals 28, no. 5 (1990): 617–20. http://dx.doi.org/10.1002/jlcr.2580280512.

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Bailey, Jean Boyd. "Investigation of Thionyl Chloride Decomposition and Open‐Circuit Potential in Lithium‐Thionyl Chloride Cells." Journal of The Electrochemical Society 136, no. 10 (1989): 2794–97. http://dx.doi.org/10.1149/1.2096288.

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Dissertations / Theses on the topic "Thionyl chloride"

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Bradley, Jonathan. "Optimisation of anode characteristics of calcium thionyl chloride cells." Thesis, Loughborough University, 1991. https://dspace.lboro.ac.uk/2134/10399.

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In the field of high performance primary battery systems lithium anoded cells have been shown to have an excellent performance and extremely good shelf life. The major drawback with the lithium technology is one of safety, whereby abuse conditions (such as charging of the cell) lead to an unstable system with the very real possibility of a cell explosion. For a commercially available cell consideration of safety issues would preclude the marketing of a high performance lithium cell for general use, rather, it will be reserved for specialist e.g. Military use where the personnel having contact
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Pell, Wendy. "Temperature dependent transport properties of aluminum chloride in thionyl chloride solutions: A non-aqueous battery electrolyte study." Thesis, University of Ottawa (Canada), 1991. http://hdl.handle.net/10393/7954.

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This thesis is a physical chemical study of the AlCl$\sb3$/SOCl$\sb2$ system. Conductivity, viscosity, and density were determined for AlCl$\sb3$ concentrations ranging from 0 to 35 weight percent in SOCl$\sb2$, and over the temperature range $-$35 to 20$\sp\circ$C. The measured conductivity was in the $\mu$Scm$\sp{-1}$ range, indicating the solution to be a weak electrolyte. Viscosities ranging from 0.7 cP for pure SOCl$\sb2$, to 3.0 cP for 4.0M AlCl$\sb3$ were found, with viscosity increasing with increasing salt concentration. The solution densities for all concentrations considered were ap
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Saunders, Tim G. "The performance evaluation of lithium thionyl chloride batteries for long-life meter applications." Thesis, Loughborough University, 1998. https://dspace.lboro.ac.uk/2134/13855.

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A research project has been carried out to provide BG plc with service life predictions of lithium primary batteries capable of supplying a continuous pulsed power supply to two new electronic domestic gas meters over a desired design life of 11.5 years, in UK weather conditions. The paper study includes investigations of the range of suitable lithium technologies and test methods, and detailed reviews of the discharge processes, polarisation and self-discharge failure modes of the lithium thionyl chloride system. A new multi-channel load test rig and a high resolution measurement system, and
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Barbeiro, Cristiane de Souza. "Síntese de 4-cloro-1-hidroxinaftaleno-2-oxazolinas a partir do ácido 1-hidroxi-2-naftóico: ciclização e halogenação one-pot empregando cloreto de tionila." Universidade de São Paulo, 2017. http://www.teses.usp.br/teses/disponiveis/9/9138/tde-30012017-094539/.

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No presente trabalho, foi desenvolvida uma metodologia one-pot para obtenção de produtos 4-cloro-1-hidroxinaftaleno-2-oxazolinas (Cl-HNO) 4, utilizando um excesso de SOCl2 a partir da amida 3a. Para a formação do produto de interesse 4 foi desenvolvida uma proposta mecanística para a simultânea ciclização do anel 2- oxazolina e halogenção na porção do anel naftóico através de espectrometria de massas de alta resolução, difração de raios-x e cálculos teóricos. Em seguida, a hidrólise de 4 levou ao produto 5 com nova inversão de configuração no C4. Para funcionalização do ácido 5, foram reagidos
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Carmier, Delphine. "Comportement et évolution morphologique d'électrodes de carbone poreuses au cours de la décharge de piles lithium - chlorure de thionyle." Mulhouse, 1999. http://www.theses.fr/1999MULH0572.

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Les performances des piles Li/SOCl2 étant limitées par des phénomènes intervenant dans leur cathode de carbone poreuse, la compréhension du rôle des différentes tailles de pores dans les mécanismes de fonctionnement de la pile, et en particulier la localisation du chlorure de lithium insoluble issu de la réaction électrochimique, sont primordiaux. L'objectif de ce travail est donc de caractériser la structure poreuse de différentes électrodes en corrélation avec les performances électrochimiques obtenues et de suivre son évolution après décharge dans différentes conditions (température, couran
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Chénebault, Philippe. "Etude de la passivation du lithium dans les piles à cathode liquide Li/SOCl2 : action synergique de SO2 et LiAl(SO3Cl4) sur les propriétés de la couche passivante." Paris 6, 1986. http://www.theses.fr/1986PA066362.

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On montre que le phénomène de retard de montée en tension peut être significativement réduit par addition à l'électrolyte d'additifs tels que SO2 et LiAl(SO3Cl4). En stockage, ces additifs agissent de façon synergique sur le processus de croissance de la couche passivante de chlorure de lithium. Par spectroscopie d'impédance, on montre que les propriétés résistives de cette couche sont alors modifiées. Sous polarisation anodique, l'action des additifs étudiés se traduit par la prédominance d'un processus de diffusion dans la couche passivante. Ce processus est décrit à partir d'un modèle dit d
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COUSSEAU, JEAN-FRANCOIS. "Fonctionnement des electrodes poreuses de carbone lors de la reduction du chlorure de thionyle dans les piles li/socl 2." Paris 6, 1999. http://www.theses.fr/1999PA066131.

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L'object de ce travail est l'etude du fonctionnement des electrodes poreuses de carbone dans les piles lithium/chlorure de thionyle dans le but de determiner les phenomenes responsables des pertes de capacite a basse temperature et a courant fort. Nous avons pour cela analyse a l'aide de la spectroscopie d'impedance complexe le fonctionnement de diverses electrodes de carbone lors de la reduction du chlorure de thionyle. Sur une electrode de carbone vitreux, les produits de la reaction precipitent lors des tout derniers instants de la decharge, diminuant la surface electrochimiquement active d
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Braun, Alexander. "The Interaction between a Thiol Specific Probe (OPA) and the Single Channel Characteristics of the Reconstituted Ca++ Release Protein from Skeletal Muscle Sarcoplasmic Reticulum." PDXScholar, 1995. https://pdxscholar.library.pdx.edu/open_access_etds/4869.

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One advantage of higher life-forms over less developed organisms is their ability to respond to signals from their environment with motion. This requires highly specialized contractile cells and a whole locomotion apparatus. In vertebrates, the cells responsible for movement are the skeletal muscle cells. They receive signals from the autonomic nervous system in the form of an action potential, and they contract in an appropriate manner. Calcium is a vital intracellular passenger whose role in muscular function is to initiate contraction. It is released via specific channel proteins from an in
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Chen, Bo-Jung, and 陳柏仲. "Photodissociation of Thionyl Chloride by Using Cavity Ring-Down Spectroscopy." Thesis, 2014. http://ndltd.ncl.edu.tw/handle/81799547899976281921.

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SUN, XIN-WEI, and 孫心偉. "The study of carbon electrode in lithium thionyl chloride cell by micro-and macro-electrochemical probes." Thesis, 1988. http://ndltd.ncl.edu.tw/handle/05382616262507947550.

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Books on the topic "Thionyl chloride"

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G, Halpert, Stein Irving, and Jet Propulsion Laboratory (U.S.), eds. Safety considerations of lithium-thionyl chloride cells. National Aeronautics and Space Administration, Jet Propulsion Laboratory, California Institute of Technology, 1986.

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White, Ralph E. Optimization of the lithium/thionyl chloride battery: A final report. Dept. of Chemical Engineering, Texas A&M University, 1987.

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White, Ralph E. Optimization of the lithium/thionyl chloride battery: A final report for NASA GRANT NAG 9-177, for the period January 1, 1988 to December 31, 1988. National Aeronautics and Space Administration, 1989.

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Paydar-Moghadam, D. Replacement of hydroxy group by chlorine using thionyl chloride. 1986.

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Bradley, Jonathan. Optimisation of anode characteristics of calcium thionyl chloride cells. 1991.

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A mathematical model of a lithium thionyl chloride primary cell. National Aeronautics and Space Administration, 1987.

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Saunders, Tim G. The performance evaluation of lithium thionyl chloride batteries for long-life meter applications. 1998.

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Book chapters on the topic "Thionyl chloride"

1

Levy, Samuel C., and Per Bro. "Lithium/Thionyl Chloride Batteries." In Battery Hazards and Accident Prevention. Springer US, 1994. http://dx.doi.org/10.1007/978-1-4899-1459-0_10.

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Page, E. M. "By Chlorination by Thionyl Chloride." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145180.ch118.

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Herber, R. H., and Floyd B. Baker. "Chlorine(Cl36 )-Labeled Thionyl Chloride, Silicon Tetrachloride, Boron Chloride, Germanium(IV) Chloride, and Phosphorus(III) Chloride." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132388.ch44.

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Margaretha, P. "With Thionyl Chloride." In Chlorine, Bromine, and Iodine. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-035-00199.

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Margaretha, P. "Synthesis Using Thionyl Chloride." In Chlorine, Bromine, and Iodine. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-035-00177.

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"Chlorination Using Thionyl Chloride." In Greener Organic Transformations. The Royal Society of Chemistry, 2022. http://dx.doi.org/10.1039/9781837670895-00045.

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Thionyl chloride, SOCl2, is a widely used reagent in organic syntheses, especially for halogenations. Per year, approximately 50 000 tons of this reagent are produced. This chapter looks at the traditional methods of chlorination, including the formation of a chlorosulfite intermediate, nucleophilic second order substitution, Darzens halogenation and nucleophilic substitution. It then discusses greener approaches using triphasic systems, microreactor systems, the Verbund system and ionic liquids.
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Weaver, G. W. "Dehydration Using Thionyl Chloride." In Five-Membered Hetarenes with Three or More Heteroatoms. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-013-00347.

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Leung, M. k., and T. Y. Luh. "Catalyzed by Thionyl Chloride." In Acetals: O/N, S/S, S/N, and N/N and Higher Heteroatom Analogues. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-030-00227.

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Aitken, R. A. "Reactions with Thionyl Chloride." In Five-Membered Hetarenes with Three or More Heteroatoms. Georg Thieme Verlag KG, 2012. http://dx.doi.org/10.1055/sos-sd-113-00018.

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Drabowicz, J., P. Kiełbasiński, P. Łyżwa, A. Zając, and M. Mikołajczyk. "Reaction with Thionyl Chloride." In Sulfur, Selenium, and Tellurium. Georg Thieme Verlag KG, 2008. http://dx.doi.org/10.1055/sos-sd-039-00029.

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Conference papers on the topic "Thionyl chloride"

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Tracy, R. P., and D. C. Totaro. "Process Control of Cure Cycle for Phenolic Linings." In CORROSION 1992. NACE International, 1992. https://doi.org/10.5006/c1992-92360.

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Abstract Materials Engineers conducted a failure analysis on five baked phenolic lined rail cars in Thionyl Chloride service. The cause of the failure in each case was inadequate final cure of the lining. We conducted laboratory immersion testing in Thionyl Chloride. The results established 400°F as the minimum metal temperature required during cure for optimum lining life. Rail car maintenance engineers worked with coating manufacturers and lining applicators on process control methods. We reduced metal temperature deviation on the rail car around a set point of 413°F ± 13°F during cure. The
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Li, Xianhuai, Shihua Yi, Yinghai Xie, et al. "Lithium Thionyl Chloride Battery RP Estimation Mechanism Based on Wavelet Framework and Neural Networks." In 2024 10th International Conference on Big Data and Information Analytics (BigDIA). IEEE, 2024. https://doi.org/10.1109/bigdia63733.2024.10808190.

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Sweeny, P. G., and F. J. Himpler. "A Novel Nonoxidizing Biocide for Cooling Water Systems." In CORROSION 1994. NACE International, 1994. https://doi.org/10.5006/c1994-94450.

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Abstract Quaternary ammonium biocides are commonly used in cooling water systems to control organisms associated with microbiologically induced corrosion and microbial fouling. These compounds while being highly efficacious and low cost have, in general, high foaming tendencies which can limit their range of application. A new quaternary ammonium compound, decylisononyldimethylammonium chloride (DIDMAC), was developed to prevent foam problems while maintaining the advantages of standard quat treatments. Laboratory evaluations showed DIDMAC to produce significantly less foam than a standard alk
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"Development of a 250 Ah lithium thionyl chloride battery." In Intersociety Energy Conversion Engineering Conference. American Institute of Aeronautics and Astronautics, 1994. http://dx.doi.org/10.2514/6.1994-4111.

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Takeuchi, E. S., C. F. Holmes, and W. D. K. Clark. "Thermal Properties and Effects for Li/BCX (Thionyl Chloride) Cells." In 22nd Intersociety Energy Conversion Engineering Conference. American Institute of Aeronautics and Astronautics, 1987. http://dx.doi.org/10.2514/6.1987-9064.

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Ehrenreich, Dan. "The Lithium Thionyl Chloride Battery-A New Source for Automotive Applications." In SAE International Congress and Exposition. SAE International, 1986. http://dx.doi.org/10.4271/860571.

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Sun, Qisen, Xuerong Ye, Haoxiang Li, Wenwen Li, Ruiming Yuan, and Guofu Zhai. "Life Prediction of Lithium Thionyl Chloride Battery Based on Pulse Load Test and Accelerated Degradation Test." In 2021 3rd International Conference on System Reliability and Safety Engineering (SRSE). IEEE, 2021. http://dx.doi.org/10.1109/srse54209.2021.00037.

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Chao, Wen, and Frank Winiberg. "THE UV-VIS SPECTRUM OF ClSO RADICAL FROM THE PHOTOLYSIS of THIONYL CHLORIDE AT 248 nm." In 2023 International Symposium on Molecular Spectroscopy. University of Illinois at Urbana-Champaign, 2023. http://dx.doi.org/10.15278/isms.2023.6813.

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Kandarpa, V., R. Mikkelson, T. Shamshoian, J. Karas, J. Anderson, and L. Crosse. "Packaging of a Large (250 AH) Lithium/Thionyl Chloride Battery for Centaur and Other Space Launch Vehicles." In 22nd Intersociety Energy Conversion Engineering Conference. American Institute of Aeronautics and Astronautics, 1987. http://dx.doi.org/10.2514/6.1987-9457.

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McDermott, Joseph, Garrett Olson, and Michael Svaleson. "Air Force Titan IV Centaur launch vehicle 250 ampere-hour lithium-thionyl chloride battery development, qualification and flight status." In Intersociety Energy Conversion Engineering Conference. American Institute of Aeronautics and Astronautics, 1994. http://dx.doi.org/10.2514/6.1994-4110.

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Reports on the topic "Thionyl chloride"

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Counts, T. Calcium/Thionyl Chloride Battery Technology. Defense Technical Information Center, 1985. http://dx.doi.org/10.21236/ada165657.

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LeRoy Whinnery, Steve Goods, George Buffleben, and Tim Sheppodd. Irreversible gettering of thionyl chloride. Office of Scientific and Technical Information (OSTI), 1999. http://dx.doi.org/10.2172/751011.

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Peled, Emanuel. Advanced Calcium-Thionyl Chloride High-Power Battery. Defense Technical Information Center, 1988. http://dx.doi.org/10.21236/ada194401.

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Peled, Emanuel. Advanced Calcium-Thionyl Chloride High-Power Battery. Defense Technical Information Center, 1990. http://dx.doi.org/10.21236/ada229168.

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Dampier, F. W. Lithium-Thionyl Chloride Cell System Safety Hazard Analysis. Defense Technical Information Center, 1985. http://dx.doi.org/10.21236/ada157089.

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Hoier, S. N., and E. T. Eisenmann. The faradaic efficiency of the lithium-thionyl chloride battery. Office of Scientific and Technical Information (OSTI), 1996. http://dx.doi.org/10.2172/219339.

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Eisenmann, E. T. Lithium: Thionyl chloride battery state-of-the-art assessment. Office of Scientific and Technical Information (OSTI), 1996. http://dx.doi.org/10.2172/221912.

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Cieslak, W., F. Delnick, and C. Crafts. Compatibility study of 316L stainless steel bellows for XMC3690 reserve lithium/thionyl-chloride battery. Office of Scientific and Technical Information (OSTI), 1986. http://dx.doi.org/10.2172/6130076.

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Driver, Crystal J., Timothy J. Johnson, Yin-Fong Su, et al. The Impact of Humidity, Temperature and Ultraviolet Light on the Near-Field Environmental Fate of Pinacolyl Alcohol, Methyl Iodide, Methylphosphonic Dichloride (DCMP) and Thionyl Chloride Using an Environmental Wind Tunnel. Office of Scientific and Technical Information (OSTI), 2003. http://dx.doi.org/10.2172/15010107.

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