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1

Janků, Josef, Jiří Burkhard, and Luděk Vodička. "Reaction of adamantanone, diamantanone, and their derivatives with thionyl chloride." Collection of Czechoslovak Chemical Communications 52, no. 8 (1987): 2028–34. http://dx.doi.org/10.1135/cccc19872028.

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In reaction of adamantanone, diamantanone, and their chloro or oxo derivatives with thionyl chloride the oxo group is replaced with two chlorine atoms under formation of geminal dichloro derivatives. The presence of a chlorine atom or an oxo group in both ketones reduces the reaction rate. The reaction rate decreases with decreasing distance between the substituent and the carbonyl group. Ketones with chlorine atom in α- or β-axial position do not react with thionyl chloride. The reaction is accelerated by hydrogen chloride whereas in the presence of pyridine no reaction was observed.
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2

Bell, KH, and LF Mccaffery. "Chlorosulfination With Thionyl Chloride of Aromatic Methyl Ethers Containing Other Functional Groups." Australian Journal of Chemistry 45, no. 8 (1992): 1213. http://dx.doi.org/10.1071/ch9921213.

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Further studies on the direct chlorosulfination with thionyl chloride of aromatic methyl ethers are described. In some cases (e.g. 1,6-dimethoxynaphthalene, 1,2,4 trimethoxybenzene, ethyl 3,5- and 3,7-dimethoxy-2-naphthoate, 3,5-dimethoxyphenyl benzoate) good yields of the sulfinyl chlorides were obtained but in others (e.g. 1,2-dimethoxybenzene, 3,5-dimethoxybenzyl acetate) the products (e.g. thiosulfonates, sulfides) were those from further reactions of the initial sulfinyl chloride. Aromatic methyl ethers containing functional groups which normally undergo reaction with thionyl chloride (e.
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3

Burmistrov, K. S., B. V. Murashevych, M. V. Toropin, D. O. Stepanskyi, and V. V. Yarovyi. "Synthesis of polymeric sodium N-chlorosulphonamide with increased active chlorine content." Voprosy Khimii i Khimicheskoi Tekhnologii, no. 6 (December 2024): 25–29. https://doi.org/10.32434/0321-4095-2024-157-6-25-29.

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Treatment of styrene-divinylbenzene sulfonated cation exchangers with a small amount of thionyl chloride prior to reaction with chlorosulfonic acid significantly facilitates the production of sulfochlorides from polymeric sulfonic acids and their salts. Polymeric sulfochlorides were synthesized by sequential treatment of gel and macroporous styrene-divinylbenzene cation exchangers in Na and H forms with thionyl chloride and chlorosulfonic acid. Transformation of these sulfochlorides into sulfamides via reaction with ammonia, followed by treatment with gaseous chlorine, yielded polymeric sodium
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4

Janků, Josef, Jiří Burkhard, and Luděk Vodička. "Reaction of 5-oxo-4-oxahomoadamantane with thionyl chloride." Collection of Czechoslovak Chemical Communications 52, no. 3 (1987): 752–55. http://dx.doi.org/10.1135/cccc19870752.

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On reaction with thionyl chloride 5-oxo-4-oxahomoadamantane gives rise to a mixture of 4a-chloro- and 4e-chloro-2-adamantanone. The carbonyl group of chloroadamantane further reacts with thionyl chloride under formation of 2,2,4e-trichloroadamantane. In the same way adamantanone reacts with thionyl chloride, giving rise to 2,2-dichloroadamantane.
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5

Sari, Asdani Muatika, Ani Suryani, Puspa Dewi Lotulung, and Silvester Tursiloadi. "Preparation of Alkyl Halide as Intermediate Compound in Synthesis Cationic Surfactant Alkyl Trimethyl Ammonium Chloride." Jurnal Kimia Terapan Indonesia 19, no. 1 (2017): 25–28. http://dx.doi.org/10.14203/jkti.v19i1.327.

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Cationic surfactant alkyl trimethyl ammonium chloride was synthesized by quartenerisation of tertiary amines. Materials used in quartenerization are tertiary amine and alkyl halide. Alkyl halide is a hydrocarbon derivative in which one or more hydrogen is replaced with halogen. In this research, thionyl chloride is used as a reactant . Thionyl chloride (SOCl2) is often used because it is easier to make, the yield is greater and byproducts are volatile. Alkyl halide is synthesized from the reaction of hexadecyl alcohol with thionyl chloride (SOCl2) at a temperature of 80 C for 24 hours in a ref
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6

Merke, Ilona, and Helmut Dreizler. "Nuclear Quadrupole Coupling in the Rotational Spectrum of Thionyl Chloride." Zeitschrift für Naturforschung A 47, no. 11 (1992): 1150–52. http://dx.doi.org/10.1515/zna-1992-1111.

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7

El-Sakka, Ibrahim A., and Nasser A. Hassan. "Synthetic uses of thionyl chloride." Journal of Sulfur Chemistry 26, no. 1 (2005): 33–97. http://dx.doi.org/10.1080/17415990500031187.

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8

Li, Mingdong. "Thionyl Chloride - A Versatile Reagent." Synlett 2007, no. 16 (2007): 2605–6. http://dx.doi.org/10.1055/s-2007-986648.

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9

Hepburn, Timothy W., and Gordon Lowe. "Synthesis of [18O]thionyl chloride." Journal of Labelled Compounds and Radiopharmaceuticals 28, no. 5 (1990): 617–20. http://dx.doi.org/10.1002/jlcr.2580280512.

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10

Bailey, Jean Boyd. "Investigation of Thionyl Chloride Decomposition and Open‐Circuit Potential in Lithium‐Thionyl Chloride Cells." Journal of The Electrochemical Society 136, no. 10 (1989): 2794–97. http://dx.doi.org/10.1149/1.2096288.

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11

Boyandin, Anatoly Nikolayevich. "Reaction of Bacterial Poly-3-Hydroxybutyrate with Thionyl Chloride in the Presence of Zinc Chloride, and the Preparation of Chlorine-Containing Oligomers." Macromol 3, no. 3 (2023): 421–30. http://dx.doi.org/10.3390/macromol3030025.

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The degradation patterns of bacterial poly-3-hydroxybutyrate (PHB) in chloroform solution under the action of thionyl chloride in the presence of zinc chloride were studied. When 2.5.mol of zinc chloride and 100 mmol of thionyl chloride were introduced into the solution of 25 mmol PHB, a decrease in the molecular weight of the polymer was observed. During the reaction, a relatively rapid decrease in the molecular weight of the polymer was noted in the first hour of the experiment; thus, the values of the weight-average molecular weight decreased from 840 kDa to 483, 167, 58.6, and 16.7 kDa aft
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12

Borys, Andryj M., Ewan R. Clark, Paul J. Saines, Antonio Alberola, and Jeremy M. Rawson. "A short, versatile route towards benzothiadiazinyl radicals." Chemical Science 13, no. 1 (2022): 149–58. http://dx.doi.org/10.1039/d1sc04248c.

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A family of 1,2,4-benzothiadiazinyl radicals are accessible from 1,2,4-benzothiadiazine 1-chlorides which can be prepared in a single step by treatment of N-arylamidines in neat thionyl chloride at reflux.
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13

Архипов, В. А., А. И. Коноваленко, В. Т. Кузнецов та А. С. Жуков. "Экспериментальная оценка взрыво- и пожароопасности литиевых источников тока". Письма в журнал технической физики 45, № 15 (2019): 25. http://dx.doi.org/10.21883/pjtf.2019.15.48082.17561.

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The method of quantitative assessment of explosion and fire hazard of lithium - thionyl chloride elements is proposed, the experimental setup is described and the results of experiments with lithium-thionyl chloride elements of sizes D and DD are presented.
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14

Bernstein, P. A., and A. B. P. Lever. "Two-electron oxidation of cobalt phthalocyanines by thionyl chloride. Implications for lithium/thionyl chloride batteries." Inorganic Chemistry 29, no. 4 (1990): 608–16. http://dx.doi.org/10.1021/ic00329a013.

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15

Bell, KH. "Chlorosulfination of Aromatic Methyl Ethers with Thionyl Chloride." Australian Journal of Chemistry 38, no. 8 (1985): 1209. http://dx.doi.org/10.1071/ch9851209.

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Aromatic sulfinyl chlorides have been prepared in high yield by direct chlorosulfination of some aromatic ethers (1,3-dimethoxybenzene, 2- methyl- and 4-chloro-1,3-dimethoxybenzene, 1,2,3-trimethoxybenzene, 1- and 2-methoxynaphthalene, 1,5-, 1,7-, 2,6- and 2,7- dimethoxynaphthalene ) with thionyl chloride alone at or below room temperature. Under the same conditions, 1,4-dimethoxynaphthalene and 1,3-dimethoxy-5-methylbenzene yield chlorinated starting materials and sulfides. 1,3,5-Trimethoxybenzene yields chlorinated starting material, sulfide, and a chlorinated disulfide. Some other ethers (e
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16

Boughdady, NM, KR Chynoweth, and DG Hewitt. "Regioselective Synthesis of Secondary Allyl Chlorides." Australian Journal of Chemistry 40, no. 4 (1987): 767. http://dx.doi.org/10.1071/ch9870767.

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We have developed high-yielding regiospecific conversions of internal secondary allylic alcohols into rearranged or unrearranged allylic chlorides using thionyl chloride in ether at -70�C or hexachloroacetone /triphenylphosphine at - 70�C respectively. The mechanisms of the reactions are discussed.
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17

Umesh Patil, Bharat Sonawane, Balaji Madje, and Sayujjata Vaidya. "One Pot Synthesis of Alkyl Nitriles." International Journal of Scientific Research in Science, Engineering and Technology 11, no. 5 (2024): 05–09. http://dx.doi.org/10.32628/ijsrset2411415.

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A one-pot synthesis method to produce alkyl nitriles using the corresponding aliphatic carboxylic acid has been developed. The process involves treating the aliphatic acid with thionyl chloride to obtain the corresponding aliphatic acid chloride, which is then further treated with anhydrous ammonia gas to yield the respective aliphatic acid amide. The intermediate corresponding amide is dehydrated with thionyl chloride to obtain alkyl nitrile with a quantitative yield.
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18

Abulimiti, Bumaliya, Qiao-li Hao, Chen Qin, Mei Xiang, and Bing Zhang. "Three-Body photodissociation of thionyl chloride." Chinese Journal of Chemical Physics 31, no. 3 (2018): 257–62. http://dx.doi.org/10.1063/1674-0068/31/cjcp1711218.

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19

Metwally, Saoud A. M. "Reaction of hydroxymethylanthraquinones with thionyl chloride." Journal of Applied Chemistry and Biotechnology 25, no. 3 (2007): 161–68. http://dx.doi.org/10.1002/jctb.5020250302.

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20

Buscaglione, I., C. Stables, and H. Sutcliffe. "The reaction of zirconium oxide chloride octahydrate with thionyl chloride." Inorganica Chimica Acta 128, no. 1 (1987): 7–9. http://dx.doi.org/10.1016/s0020-1693(00)84686-1.

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21

Kotali, Antigoni, and Ioannis S. Lafazanis. "Reactions of N-acylhydrazones with thionyl chloride." Arkivoc 2003, no. 6 (2003): 91–94. http://dx.doi.org/10.3998/ark.5550190.0004.611.

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22

Changming, Li, and Zha Quanxin. "THE TAFEL PLOT OF THIONYL CHLORIDE REDUCTION." Acta Physico-Chimica Sinica 5, no. 02 (1989): 243–45. http://dx.doi.org/10.3866/pku.whxb19890224.

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23

Anderson, Stephen, Darren J. Cook, Anthony F. Hill, John M. Malget, Andrew J. P. White, and David J. Williams. "Reactions of Tungsten Alkylidynes with Thionyl Chloride." Organometallics 23, no. 11 (2004): 2552–57. http://dx.doi.org/10.1021/om030691i.

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24

Burkhard, Jiří, Josef Janků, and Luděk Vodička. "Reaction of 1-acetyladamantane with thionyl chloride." Collection of Czechoslovak Chemical Communications 53, no. 1 (1988): 110–13. http://dx.doi.org/10.1135/cccc19880110.

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1-Acetyladamantane (I) reacts with thionyl chloride in the presence of pyridine to give 1-(1’-chloroetenyl)adamantane (IV). In the absence of pyridine, the same reaction affords a more complex mixture containing 1-adamantanecarboxylic acid (VI), its ethyl ester (VII), and 1-chloroacetyladamantane (V).
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25

McDonald, Robert C. "Fluorescence Spectroscopy of Electrochemically Reduced Thionyl Chloride." Journal of The Electrochemical Society 135, no. 2 (1988): 403–5. http://dx.doi.org/10.1149/1.2095624.

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26

Berg, R. W., H. A. Hjuler, A. P. L. So̸ndergaard, and N. J. Bjerrum. "Conductivity of Thionyl Chloride‐Lithium Tetrachloroaluminate Solutions." Journal of The Electrochemical Society 136, no. 2 (1989): 323–28. http://dx.doi.org/10.1149/1.2096629.

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27

Oae, Shigeru. "Thionyl Chloride-A Good Ligand Coupling Reagent-." Phosphorus, Sulfur, and Silicon and the Related Elements 95, no. 1-4 (1994): 361–65. http://dx.doi.org/10.1080/10426509408034238.

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28

Oae, Shigeru, Yoichi Inubushi, Masakuni Yoshihara, and Yuzuru Uchida. "Thionyl Chloride -a Good Ligand Coupling Reagent-." Phosphorus, Sulfur, and Silicon and the Related Elements 95, no. 1 (1994): 361–65. http://dx.doi.org/10.1080/10426509408545377.

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29

Oae, Shigeru, Yoichi Inubushi, and Masakuni Yoshihara. "THIONYL CHLORIDE—A GOOD LIGAND COUPLING REAGENT." Phosphorus, Sulfur, and Silicon and the Related Elements 103, no. 1-4 (1995): 101–10. http://dx.doi.org/10.1080/10426509508027369.

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30

Vanderpool, Richard A., and Harmon B. Abrahamson. "Reaction of Vaska's complex with thionyl chloride." Inorganic Chemistry 24, no. 19 (1985): 2985–89. http://dx.doi.org/10.1021/ic00213a023.

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31

Kim, Bum-Soo, and Su-Moon Park. "Aggregation of Thionyl Chloride in Organic Solvents." Journal of Physical Chemistry 99, no. 24 (1995): 9918–23. http://dx.doi.org/10.1021/j100024a039.

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32

Mokrushina, G. A., S. K. Kotovskaya, and G. A. Yurchenko. "Reaction of 2-thiobenzazoles with thionyl chloride." Chemistry of Heterocyclic Compounds 21, no. 8 (1985): 872–75. http://dx.doi.org/10.1007/bf00519812.

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33

Cohen, R., J. Kimel, E. Elster, E. Peled, and S. Efrima. "Properties of thionyl chloride solutions (extended abstract)." Journal of Power Sources 26, no. 1-2 (1989): 5–7. http://dx.doi.org/10.1016/0378-7753(89)80009-6.

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34

Masters, Andrew P., Ted S. Sorensen, and Phu Manh Tran. "A new procedure for the insitu generation of methylene ketenes." Canadian Journal of Chemistry 65, no. 7 (1987): 1499–502. http://dx.doi.org/10.1139/v87-256.

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The reaction of pentacarbonylmanganate anion 3 and 2-bromopropenoyl chlorides 2 leads to 2,4-alkylidenecyclobutane-1,3-diones 5. The latter are formed from dimerization of the corresponding methylene ketenes 1 so that the reaction of 2 and 3 constitutes a new synthetic procedure for the insitu generation of these very reactive intermediates. Acid chlorides 2 are readily available from α,β-unsaturated acids via bromination–dehydrobromination – thionyl chloride sequences.
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35

Zhu, Hen Ga, Xiao Yan Lin, Xue Gang Luo, and Jian Ping Zhang. "Synthesis and Characterization of Aminoalky Cellulose." Materials Science Forum 658 (July 2010): 396–99. http://dx.doi.org/10.4028/www.scientific.net/msf.658.396.

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Aminoalky cellulose (AmAC) had been synthesized from chloro-deoxy- hydroxyethylcellulose (CDHC), which was prepared from hydroxyethyl cellulose (HEC) chlorinated with thionyl chloride and then aminated by ethylenediamine. The structures of HEC and AmAC were characterized by FT-IR and SEM. The results showed that amino groups from ethylenediamine were grafted onto the HEC after a series of reactions. Compared with the HEC, AmAC had a rougher surface. Effects of experimental parameters on yield and chlorine content of CDHC, yield of AmAC and adsorption quantity for trinitrotoluene (TNT) of AmAC
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36

Zyk, N. V., E. K. Beloglazkina, and I. D. Titanyuk. "ChemInform Abstract: Sulfenylation Reactions Activated by Thionyl Chloride and Sulfuryl Chloride." ChemInform 30, no. 15 (2010): no. http://dx.doi.org/10.1002/chin.199915075.

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37

Greenberg, Jacob A., and Tarek Sammakia. "The Conversion of tert-Butyl Esters to Acid Chlorides Using Thionyl Chloride." Journal of Organic Chemistry 82, no. 6 (2017): 3245–51. http://dx.doi.org/10.1021/acs.joc.6b02931.

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38

Aitken, R. Alan, Alexandra H. Campbell, Chloé E. Fletcher, and Alexandra M. Z. Slawin. "2,2′-Trisulfanediyldibenzoyl Chloride." Molbank 2023, no. 3 (2023): M1731. http://dx.doi.org/10.3390/m1731.

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The X-ray structure of the title compound, formed at low conversion in the reaction of thiosalicylic acid with thionyl chloride, has been determined. The acid chloride groups are oriented to permit an attractive non-bonding O…S interaction. Mechanisms are suggested for the formation of this unexpected product. 1H and 13C NMR data are also reported for the first time for the major reaction product, 2-mercaptobenzoyl chloride.
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39

Fedotov, Dmitrii B., Nikolai I. Yalyushev, Aleksandr N. Maftey, and Dmitrii V. Makovetsky. "DIAGNOSTIC OF LITHIUM-THIONYL CHLORIDE CELLS SELF-DISCHARGE." Electrochemical Energetics 17, no. 1 (2017): 9–18. http://dx.doi.org/10.18500/1608-4039-2017-17-1-9-18.

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40

Roth, Melanie, Christof Maul, and Karl-Heinz Gericke. "Competitive channels in the photodissociation of thionyl chloride." Physical Chemistry Chemical Physics 4, no. 13 (2002): 2932–40. http://dx.doi.org/10.1039/b111587a.

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41

Walker, Charles W., William L. Wade, Michael Binder, and Sol Gilman. "Cathode Performance Improvement in Calcium‐Thionyl Chloride Cells." Journal of The Electrochemical Society 133, no. 8 (1986): 1555–58. http://dx.doi.org/10.1149/1.2108967.

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42

Waheed, Noor Ahmed, Noora Thamer Abdulaziz, Sawsan Hasan Hammodi, and Yasser Fakri Mustafa. "Thionyl Chloride: A Catalyst of Synthetic Chemical Interest." Iraqi Journal of Pharmacy 20, no. 2 (2023): 111–25. https://doi.org/10.33899/iphr.2023.142271.01053.

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43

Creary, Xavier, та Jennifer Tricker. "Reaction of Benzylic α-Hydroxythioamides with Thionyl Chloride". Journal of Organic Chemistry 63, № 22 (1998): 8080. http://dx.doi.org/10.1021/jo984019k.

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44

Kanevskii, L. S. "Impedance diagnostics of lithium—thionyl chloride power sources." Russian Journal of Electrochemistry 43, no. 1 (2007): 85–91. http://dx.doi.org/10.1134/s1023193507010120.

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45

Creary, Xavier, та Jennifer Tricker. "Reaction of Benzylic α-Hydroxythioamides with Thionyl Chloride". Journal of Organic Chemistry 63, № 15 (1998): 4907–11. http://dx.doi.org/10.1021/jo971590v.

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46

Bashir-Hashemi, A., Paritosh R. Dave, Herman L. Ammon, and Theodore Axenrod. "Novel reaction of amidocubanes with thionyl chloride; secocubanes." Tetrahedron Letters 31, no. 34 (1990): 4835–36. http://dx.doi.org/10.1016/s0040-4039(00)97745-1.

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47

Smesko, Sally Ann, and Esther Sans Takeuchi. "Prismatic thionyl chloride cell characterization through parametric analysis." Journal of Power Sources 52, no. 2 (1994): 173–78. http://dx.doi.org/10.1016/0378-7753(94)01959-2.

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48

Russell, P. G., and F. Goebel. "High rate lithium/thionyl chloride bipolar battery development." Journal of Power Sources 54, no. 2 (1995): 180–85. http://dx.doi.org/10.1016/0378-7753(94)02063-9.

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49

Sutter, P., and C. D. Weis. "The chlorination of 1,4-dihydroxyanthraquinone with thionyl chloride." Dyes and Pigments 6, no. 6 (1985): 435–43. http://dx.doi.org/10.1016/0143-7208(85)80024-3.

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50

Kim, Bum‐Soo, and Su‐Moon Park. "Spectroelectrochemical Studies on the Reduction of Thionyl Chloride." Journal of The Electrochemical Society 142, no. 1 (1995): 34–40. http://dx.doi.org/10.1149/1.2043921.

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