Academic literature on the topic 'Benzene – Synthesis'

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Journal articles on the topic "Benzene – Synthesis"

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Maraval, Valérie, Remi Chauvin, Kévin Cocq, Cécile Barthes, and Arnaud Rives. "Synthesis of Functional Carbo-benzenes with Functional Properties: The C2 Tether Key." Synlett 30, no. 01 (2018): 30–43. http://dx.doi.org/10.1055/s-0037-1610269.

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Beyond demonstration of conceptual relevance and synthetic feasibility of aryl/alkyl-substituted representatives, carbo-benzene molecules started to gain prospects of broader impact through the emergence of alkynyl derivatives. This is first illustrated by examples of di- and hexaalkynyl-carbo-benzenes, a carbo-naphthalene, a carbo-biphenyl, and two carbo-terphenyls. A focus is then given to dialkynyl derivatives by reference to the peripherally C2-extruded parents. In the centro­symmetric quadrupolar series, the C2 expansion or ethynylogation effect is more particularly considered for 9H-fluo
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Zhu, Tingshun, Ke Xu, and Ziyuan Wang. "N-Heterocyclic Carbene-Organocatalyzed Arene Formation: Application in Atroposelective Synthesis of Polysubstituted Benzenes." Synlett 31, no. 10 (2020): 925–32. http://dx.doi.org/10.1055/s-0039-1690814.

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In recent decades, organocatalysis by N-heterocyclic carbenes (NHCs) has emerged as a versatile and powerful method in organic synthesis. As a result of the power of NHC organocatalysis to produce cyclic compounds, polysubstituted benzenes, which are among the most important cyclic compounds in organic chemistry, can be synthesized efficiently and selectively. This article briefly summarizes the history of NHC organocatalysis, including recent developments in benzene-formation methods, and highlights our recent work in atroposelective arene formation by carbene-catalyzed formal [4+2] cyclo­add
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Ajenjo, Javier, Martin Greenhall, Camillo Zarantonello, and Petr Beier. "Synthesis and nucleophilic aromatic substitution of 3-fluoro-5-nitro-1-(pentafluorosulfanyl)benzene." Beilstein Journal of Organic Chemistry 12 (February 3, 2016): 192–97. http://dx.doi.org/10.3762/bjoc.12.21.

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3-Fluoro-5-nitro-1-(pentafluorosulfanyl)benzene was prepared by three different ways: as a byproduct of direct fluorination of 1,2-bis(3-nitrophenyl)disulfane, by direct fluorination of 4-nitro-1-(pentafluorosulfanyl)benzene, and by fluorodenitration of 3,5-dinitro-1-(pentafluorosulfanyl)benzene. The title compound was subjected to a nucleophilic aromatic substitution of the fluorine atom with oxygen, sulfur and nitrogen nucleophiles affording novel (pentafluorosulfanyl)benzenes with 3,5-disubstitution pattern. Vicarious nucleophilic substitution of the title compound with carbon, oxygen, and
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Iakobson, George, Junyi Du, Alexandra M. Z. Slawin, and Petr Beier. "Pyridine-promoted dediazoniation of aryldiazonium tetrafluoroborates: Application to the synthesis of SF5-substituted phenylboronic esters and iodobenzenes." Beilstein Journal of Organic Chemistry 11 (August 26, 2015): 1494–502. http://dx.doi.org/10.3762/bjoc.11.162.

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Pyridine promotes dediazoniation of aryldiazonium tetrafluoroborates. The formed aryl radicals were trapped with B2pin2, iodine, or tetrahydrofuran to afford boronic esters, iodobenzenes and benzenes, respectively. The application to the synthesis of (pentafluorosulfanyl)phenylboronic esters, iodo(pentafluorosulfanyl)benzenes and (pentafluorosulfanyl)benzene is shown.
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Hocek, Michal, Irena G. Stará, Ivo Starý, and Hana Dvořáková. "Covalent Analogues of DNA Base-Pairs and Triplets IV. Synthesis of Trisubstituted Benzenes Bearing Purine and/or Pyrimidine Rings by Cyclotrimerization of 6-Ethynylpurines and/or 5-Ethynyl-1,3-dimethyluracil." Collection of Czechoslovak Chemical Communications 67, no. 8 (2002): 1223–35. http://dx.doi.org/10.1135/cccc20021223.

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Ni-Catalyzed cyclotrimerizations of 6-ethynylpurines 3 or 5-ethynyl-1,3-dimethyluracil (4) afforded the 1,2,4-tris(purin-6-yl)benzenes 7 or 1,2,4-tris(1,3-dimetyhyluracil-5-yl)benzene (9), respectively. The symmetrical 1,3,5-tris(purin-6-yl)benzenes 8 were also formed as minor products in very low yields. Co-cyclotrimerization of 9-benzyl-6-ethynylpurine (3a) with 4 afforded the tris(purinyl)benzene 7a as a major product along with 1,2-bis(9-benzylpurin-6-yl)-4-(1,3-dimethyluracil-5-yl)benzene (10) and a complex mixture of other derivatives and isomers. Compounds 7-10 are analogues of Hoogstee
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Shimizu, Tomoe, Takayuki Maeda, Katsuhiro Hida, and Takehiko Yamato. "Synthesis and conformational studies of 9-methoxy- and 9-methyl-2,11-dithia[3.3]metacyclophanes." Journal of Chemical Research 2009, no. 8 (2009): 515–19. http://dx.doi.org/10.3184/030823409x12474221035244.

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A series of 9-methoxy- and 9-methyl-2,11-dithia[3.3]metacyclophanes are obtained by the coupling reaction of the corresponding 1,3-bis(bromomethyl)benzenes and bis(sulfanylmethyl)benzenes in ethanol under the high dilution conditions. The conformational studies of 2,11-dithia[3.3]metacyclophanes as well as the ring current interactions derived from benzene ring are also described.
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Donchak, Volodymyr, and Khrystyna Harhay. "Synthesis of fluorinated polystyrene." Chemistry & Chemical Technology 2, no. 1 (2008): 11–14. http://dx.doi.org/10.23939/chcht02.01.011.

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Acylation of polystyrene with trifluoroacetic anhydride in a solution of aprotonic solvents, namely 1,2-dichloroethane, chlorobenzene at the presence of Lewis acid as catalyst results in obtaining of fluorinated polystyrene, which posses trifluoroacetic fragments in benzoic rings, preferably in position 4. In order to achieve a total substitution of benzene rings in polystyrene macromolecules, the ratio polystyrene : trifluoroacetic anhydride : AlCl3 must be at least 1:10:2.2 mol correspondingly
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Zhao, Long, Wenchao Lu, Musahid Ahmed, et al. "Gas-phase synthesis of benzene via the propargyl radical self-reaction." Science Advances 7, no. 21 (2021): eabf0360. http://dx.doi.org/10.1126/sciadv.abf0360.

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Polycyclic aromatic hydrocarbons (PAHs) have been invoked in fundamental molecular mass growth processes in our galaxy. We provide compelling evidence of the formation of the very first ringed aromatic and building block of PAHs—benzene—via the self-recombination of two resonantly stabilized propargyl (C3H3) radicals in dilute environments using isomer-selective synchrotron-based mass spectrometry coupled to theoretical calculations. Along with benzene, three other structural isomers (1,5-hexadiyne, fulvene, and 2-ethynyl-1,3-butadiene) and o-benzyne are detected, and their branching ratios ar
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Zou, Chunhai, Christine Lepetit, Yannick Coppel, and Remi Chauvin. "Ring carbo-mers: From questionable homoaromaticity to bench aromaticity." Pure and Applied Chemistry 78, no. 4 (2006): 791–811. http://dx.doi.org/10.1351/pac200678040791.

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The title journey is undertaken at the levels of both theory and experiment. Since 1983, homoaromaticity has been shown to play at most a minor role in the stability of Scott's [N]pericyclyne hydrocarbons - the first ring carbo-mers of cycloalkanes. This statement has been systematically refined for N = 3-6 by using both classical theoretical tools and newly designed tools based on electron localization function (ELF) analysis. The compatibility of the [5]- and [6]-pericyclyne cores with vertex functionalities was established by the synthesis of 20 oxy (carbo-cyclitol) derivatives. The stereoi
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Ran, Ningqing, David R. Knop, K. M. Draths, and J. W. Frost. "Benzene-Free Synthesis of Hydroquinone." Journal of the American Chemical Society 123, no. 44 (2001): 10927–34. http://dx.doi.org/10.1021/ja016460p.

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Dissertations / Theses on the topic "Benzene – Synthesis"

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Kankam, Kofi. "Alkylation of Benzene on Immobilized Phosphotungstic Acid." Digital Commons @ East Tennessee State University, 2020. https://dc.etsu.edu/etd/3847.

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Linear alkylbenzenes (LAB) are key intermediates in the synthesis of linear alkylbenzene sulfonate surfactants that are used in the manufacture of detergents. Production of LAB with traditional Lewis acids as catalysts, such as hydrofluoric acid, results in the formation of large amounts of toxic wastes and corrosion of industrial equipment. Phosphotungstic acid (PTA) has gained much attention in recent years as a solid catalyst for various alkylation reactions. This research work aims to develop a novel material based on PTA-containing silica gel, which can effectively catalyze LAB synthesis.
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Johnson, Charles Andrew. "Synthesis, characterization, and materials properties of benzocyclynes and metallabenzocyclynes /." view abstract or download file of text, 2007. http://proquest.umi.com/pqdweb?did=1400962601&sid=1&Fmt=2&clientId=11238&RQT=309&VName=PQD.

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Thesis (Ph. D.)--University of Oregon, 2007.<br>Typescript. Includes vita and abstract. Includes bibliographical references (leaves 243-262). Also available for download via the World Wide Web; free to University of Oregon users.
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Duffey, John. "Chemical and enzyme catalysed hydroxylation pathways in the synthesis of arene oxides and quinoline alkaloids." Thesis, Queen's University Belfast, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.295411.

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Kerley, Nuala Anne. "Study of bacterial metabolites of arenes and derivatives and their role in synthesis." Thesis, Queen's University Belfast, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.239008.

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Gibson, Shane. "The synthesis of (+) and (-) fortamine utilising the 1,4-photoamination of benzene." Thesis, University of Reading, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.415519.

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Bentley, Philip. "Synthesis and characterisation of materials for polarised electroluminescence." Thesis, University of Sheffield, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.310820.

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Yang, Jinsong. "Convenient synthesis of caprolactam from lysine alternative of current benzene-based caprolactam production /." Diss., Connect to online resource - MSU authorized users, 2007.

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Ivie, Jimmy John. "A numerical model of the synthesis of carbon black by benzene pyrolysis." Thesis, Georgia Institute of Technology, 1986. http://hdl.handle.net/1853/10954.

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Kumar, Siddhartha. "Synthesis and Characterization of π-Extended Benzoporphyrins". Thesis, University of North Texas, 2019. https://digital.library.unt.edu/ark:/67531/metadc1505216/.

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Porphyrins offer a very synthetically flexible template which can be modified in numerous ways to synthesize molecules with very useful properties applicable in areas such as non-linear optical properties, photodynamic therapy, dye-sensitized solar cells, chemical sensors and organic electronic devices. β-Substituted π-extended porphyrins offer unique capabilities in tuning the properties of the molecule towards practical applications. Increased π-conjugation allows the HOMO-LUMO gap to decrease and hence to redshift the absorption into the near-IR region. β-Fused benzoporphyrins offer additio
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Ambadapadi, Sriram Braterman Paul S. "Study of substituted benzenesulfonate-containing layered double hydroxides and investigation of the hexamethylenetetramine route of LDH synthesis." [Denton, Tex.] : University of North Texas, 2007. http://digital.library.unt.edu/permalink/meta-dc-3709.

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Books on the topic "Benzene – Synthesis"

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1974-, Taboada Jerome Bolabola. Direct oxidation of benzene to phenol: Investigation of the active iron species in (Fe,Al)MFI catalysts by 57Fe Mössbauer spectroscopy. IOS Press, 2005.

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Wiktelius, Daniel. Asymmetric synthesis of dipeptidomimetics and phosphine-boranes: Routes involving stereoselective olefination, expoxidation, and lipase-catalysed reactions. Göteborg University, 2007.

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Grant, Ewart H. Synthesis of bis (3,3,3-trifluoropropynyl) benzenes. National Library of Canada, 1990.

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Yarwood, Thomas David. The synthesis and reactions of lightly fluorinated benzenes. University of Birmingham, 1992.

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Rozen, B. I͡A. Soperniki nefti i benzina. "Nedra", 1985.

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Dünkelmann, Pascal. Entwicklung eines Donor/Akzeptor-Konzeptes für die asymmetrische Synthese unsymmetrischer Benzoine mit Hilfe ThDP-abhängiger Enzyme. Forschungszentrum Jülich GmbH, Zentralbibliothek, 2005.

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Book chapters on the topic "Benzene – Synthesis"

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Cleary, James W. "Polymers from Benzene and Sulfur: Friedel and Crafts Revisited." In Advances in Polymer Synthesis. Springer US, 1985. http://dx.doi.org/10.1007/978-1-4613-2121-7_7.

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Lorcy, Dominique, Philippe Hascoat, Roger Carlier, André Tallec, and Albert Robert. "Electrochemical Cyclooligomerization of 1,4-Bis(1,4-Dithiafulven-6-yl)Benzene and Analogues." In Novel Trends in Electroorganic Synthesis. Springer Japan, 1998. http://dx.doi.org/10.1007/978-4-431-65924-2_44.

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Butler, Ian S., Ann M. English, Keith R. Plowman, Ruth A. Pickering, and Robert J. Angelici. "1. Synthesis of (η6 -Benzene)Dicarbonyl(Selenocarbonyl)Chromium(0) and Pentacarbonyl(Selenocarbonyl)Chromium(0)." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132524.ch1.

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Zhang, Xinsheng, Ping Ding, and Wei-Kang Yuan. "Experimental and Theoretical Studies on Preparation of Hydroquinone from Benzene in a Paired Packed-Bed Electrode Reactor." In Novel Trends in Electroorganic Synthesis. Springer Japan, 1998. http://dx.doi.org/10.1007/978-4-431-65924-2_12.

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Kalf, George F., Robert Snyder, and Gloria B. Post. "Inhibition of RNA Synthesis in Mouse Macrophages and Lymphocytes by Benzene and Its Metabolites." In Biological Reactive Intermediates III. Springer US, 1986. http://dx.doi.org/10.1007/978-1-4684-5134-4_62.

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Segal, John A., and William E. Silverthorn. "(η6-Benzene)(η5-Cyclopentadienyl)Molybdenum and (η6-Benzene) (η5-Cyclopentadienyl)-Molybdenum Derivatives." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132517.ch43.

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MacNicol, D. D., P. R. Mallinson, A. Murphy, and C. D. Robertson. "Synthesis and Structure of Hexakis(p-Hydroxyphenyloxy)Benzene: A Versatile Analogue of the Hydrogen-Bonded Hexameric Unit of β-Hydroquinone." In Inclusion Phenomena in Inorganic, Organic, and Organometallic Hosts. Springer Netherlands, 1987. http://dx.doi.org/10.1007/978-94-009-3987-5_39.

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Klabunde, K. J., H. F. Efner, T. O. Murdock, J. A. Gladysz, and J. G. Fulcher. "Bis[1,3-Bis(Trifluoromethyl)Benzene] Chromium-(0), [1,3-(Cf3 )2 C6 h4 ]2 Cr." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132500.ch12.

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Elliott, Gregory P., Nicola M. Mcauley, Warren R. Roper, and Patricia A. Shapley. "An Osmium Containing Benzene Analog, Os(CSCHCHCHC H)(CO)(Pph3 )2 , Carbonyl(5-Thioxo-1, 3-Pentadiene-1, 5-Diyl-C 1 , C 5 , S )-Bis(Triphenylphosphine)Osmium, and its Precursors." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132579.ch33.

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Andrews, Susan A., S. Peldszus, C. Moralejo, W. A. Anderson, and P. M. Huck. "Stable Intermediates in the Photooxidative Treatment of Synthetic Groundwaters Containing Benzene." In Chemical Water and Wastewater Treatment V. Springer Berlin Heidelberg, 1998. http://dx.doi.org/10.1007/978-3-642-72279-0_4.

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Conference papers on the topic "Benzene – Synthesis"

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Hessler, Filip, and Martin Kotora. "Synthesis and rearrangements of Dewar benzene deoxyribosides." In XVth Symposium on Chemistry of Nucleic Acid Components. Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, 2011. http://dx.doi.org/10.1135/css201112334.

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Efimov, A. V., and E. V. Babaev. "Computer synthesis of benzene derivatives from cyclic and acyclic precursors." In The first European conference on computational chemistry (E.C.C.C.1). AIP, 1995. http://dx.doi.org/10.1063/1.47786.

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Yan, Peijian, Shouzhi Pu, Gang Liu, and Shiqiang Cui. "Synthesis and Properties of a Novel Diarylethene with a Benzene Unit." In 2011 Symposium on Photonics and Optoelectronics (SOPO 2011). IEEE, 2011. http://dx.doi.org/10.1109/sopo.2011.5780589.

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Dinh Thanh, Nguyen, and Hoang Thi Kim Van. "SYNTHESIS OF SOME (HEPTA-O-ACETYL-b-LACTOSYL)THIOSEMICARBAZONES CONTAINING BENZENE RING." In The 14th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2010. http://dx.doi.org/10.3390/ecsoc-14-00450.

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Geng, Weiwei, Shiqiang Cui, and Shouzhi Pu. "Synthesis and Properties of a Novel Unsymmetrical Diarylethene with Thiophene and Benzene Unit." In 2012 Symposium on Photonics and Optoelectronics (SOPO 2012). IEEE, 2012. http://dx.doi.org/10.1109/sopo.2012.6271053.

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Manteghi, Faranak, and Targol Rahimi Masale Nezhad. "Synthesis of an alkaline-earth metal organic frameworks (MOF) based on benzene-1,2,4,5 tetracarboxylic acid." In The 22nd International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2018. http://dx.doi.org/10.3390/ecsoc-22-05703.

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Zhang, Chao, Yueli Liu, Jie Yang, Zhuoyin Peng, Jing Zhou, and Wen Chen. "Hydrothermal Synthesis of Porous SiO2@TiO2 Microspheres and Their Photocatalytic Degradation of Gaseous Benzene." In Nanophotonics, Nanoelectronics and Nanosensor. OSA, 2013. http://dx.doi.org/10.1364/n3.2013.nsa4b.5.

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Takahiro Nakamura, Yuzuru Mochidzuki, and Shunichi Sato. "Synthesis of monodispersed DLC nanoparticles in intense optical field by femtosecond laser ablation of liquid benzene." In 2007 Quantum Electronics and Laser Science Conference. IEEE, 2007. http://dx.doi.org/10.1109/qels.2007.4431168.

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Nakamura, Takahiro, Yuzuru Mochidzuki, and Shunichi Sato. "Synthesis of monodispersed DLC nanoparticles in intense optical field by femtosecond laser ablation of liquid benzene." In CLEO 2007. IEEE, 2007. http://dx.doi.org/10.1109/cleo.2007.4453391.

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Štefko, Martin, and Michal Hocek. "A modular methodology for the synthesis of 3- and 4-substituted benzene and aniline C-ribonucleosides." In XIVth Symposium on Chemistry of Nucleic Acid Components. Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, 2008. http://dx.doi.org/10.1135/css200810455.

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Reports on the topic "Benzene – Synthesis"

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Prengle, H. W. Jr, F. A. Bricout, and S. Alam. Synthesis of cresols and xylenols from benzene and methanol. Office of Scientific and Technical Information (OSTI), 1992. http://dx.doi.org/10.2172/10148157.

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Prengle, Jr, H. W., F. A. Bricout, and S. Alam. Synthesis of cresols and xylenols from benzene and methanol. Office of Scientific and Technical Information (OSTI), 1992. http://dx.doi.org/10.2172/5247896.

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