Academic literature on the topic 'Furan Oxidation'

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Journal articles on the topic "Furan Oxidation"

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Uchuskin, Maxim, Igor Trushkov, and Anton Makarov. "Furan Oxidation Reactions in the Total Synthesis of Natural Products." Synthesis 50, no. 16 (2018): 3059–86. http://dx.doi.org/10.1055/s-0037-1610021.

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Recent developments on the transformations of furans under oxidative conditions toward the total synthesis of complex natural compounds are discussed. Reactions and methods are classified according to the type of oxidant used. Comparisons are then made between all the strategies to provide a comprehensive overview. This review covers the most prominent work published from 2011 until 2017.1 Introduction2 Reagents and Methods for Oxidation of the Furan Ring2.1 Singlet Oxygen2.2 Peroxides and Hydroperoxides2.3 Quinones2.4 Halogen-Based Oxidants2.5 Chromium-Based Oxidants3 The Achmatowicz Reaction
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Gui, Jinghan, and Jiachen Deng. "Alkyne-Forming Furan Fragmentation: A General Method to Convert Furans into Alkynoic Acids." Synlett 30, no. 06 (2019): 642–46. http://dx.doi.org/10.1055/s-0037-1611943.

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Furans are readily available and highly reactive heterocycles that serve as versatile four-carbon synthons in organic synthesis. Recently, we discovered that furans, upon oxidation with singlet oxygen, can be transformed into alkynes via dual C–C double-bond cleavage. This Synpacts article presents an overview of the historical context and the development of this furan fragmentation reaction. We also discuss its application in natural product synthesis and a plausible reaction mechanism.1 Introduction2 Background of Alkyne-Forming Furan Fragmentation3 Reaction Development4 Conclusion
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Coggon, Matthew M., Christopher Y. Lim, Abigail R. Koss, et al. "OH chemistry of non-methane organic gases (NMOGs) emitted from laboratory and ambient biomass burning smoke: evaluating the influence of furans and oxygenated aromatics on ozone and secondary NMOG formation." Atmospheric Chemistry and Physics 19, no. 23 (2019): 14875–99. http://dx.doi.org/10.5194/acp-19-14875-2019.

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Abstract. Chamber oxidation experiments conducted at the Fire Sciences Laboratory in 2016 are evaluated to identify important chemical processes contributing to the hydroxy radical (OH) chemistry of biomass burning non-methane organic gases (NMOGs). Based on the decay of primary carbon measured by proton transfer reaction time-of-flight mass spectrometry (PTR-ToF-MS), it is confirmed that furans and oxygenated aromatics are among the NMOGs emitted from western United States fuel types with the highest reactivities towards OH. The oxidation processes and formation of secondary NMOG masses measu
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El Mais, Abd El Rahman, Barbara D'Anna, Luka Drinovec, et al. "Insights into secondary organic aerosol formation from the day- and nighttime oxidation of polycyclic aromatic hydrocarbons and furans in an oxidation flow reactor." Atmospheric Chemistry and Physics 23, no. 23 (2023): 15077–96. http://dx.doi.org/10.5194/acp-23-15077-2023.

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Abstract. Secondary organic aerosols (SOAs) formed by oxidation of typical precursors largely emitted by biomass burning, such as polycyclic aromatic hydrocarbons (PAHs) and furans, are still poorly characterized. We evaluated and compared the formation yields, effective density (ρeff), absorption Ångström exponent (α), and mass absorption coefficient (MAC) of laboratory-generated SOAs from three furan compounds and four PAHs. SOAs were generated in an oxidation flow reactor under day- (OH radicals) or nighttime (NO3 radicals) conditions. The ρeff, formation yields, α, and MAC of the generated
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Vranová, J., and Z. Ciesarová. "Furan in food – a review." Czech Journal of Food Sciences 27, No. 1 (2009): 1–10. http://dx.doi.org/10.17221/2843-cjfs.

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Furan and its derivatives were identified in a small number of heat-treated foods back in the 60’s and 70’s. In May 2004, US Food and Drug Administration published a report on the occurrence of parent furan in a number of thermally treated foods. Since furan has been classified as “possibly carcinogenic to human” by IARC, a great concern has been addressed to the analysis of this substance naturally-occurring in food. This paper gives a short overview on the mechanistic pathways of the parent furan formation in food by degradation of amino acids and/or reducing sugars, and oxidation of ascorbi
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Maranzana, Andrea, and Glauco Tonachini. "Mechanism of the Photochemical Isomerization and Oxidation of 2-Butenedial: A Theoretical Study." Molecules 28, no. 13 (2023): 4994. http://dx.doi.org/10.3390/molecules28134994.

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Under tropospheric conditions, 2-butenedial is photochemically removed to produce secondary organic aerosol. Upon solar irradiation in the lower troposphere, the main photochemical products are ketene-enol (a key intermediate product), furanones, and maleic anhydride. The oxidative reaction mechanism was studied using the multireference method CASSCF to explore the hypersurface of the two most accessible singlet excited states, and by DFT for the ground state. Photoisomerization of 2-butenedial in the first excited state directly produces ground state ketene-enol upon nonradiative relaxation.
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Zhou, Yuefeng, Jun Ma, Kai Chen, Huanfeng Jiang, and Shifa Zhu. "Selectivity-switchable oxidation of tetraarylethylenes to fused polycyclic compounds." Chemical Communications 52, no. 91 (2016): 13345–48. http://dx.doi.org/10.1039/c6cc08155j.

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Carrette, L. L. G., E. Gyssels, N. De Laet, and A. Madder. "Furan oxidation based cross-linking: a new approach for the study and targeting of nucleic acid and protein interactions." Chemical Communications 52, no. 8 (2016): 1539–54. http://dx.doi.org/10.1039/c5cc08766j.

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Chen, Xiaoyu, Andrew Thomas Holm, and Philip Wai Hong Chan. "Gold Catalysed 1,4-Enyne Acetate Strategy for the Synthesis of 1H-Indenes and Partially Hydrogenated Methanonaphtho[1,2-c]furan-1,3(4H)-diones." Australian Journal of Chemistry 73, no. 12 (2020): 1165. http://dx.doi.org/10.1071/ch20175.

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A synthetic method to prepare 1H-indenes and partially hydrogenated methanonaphtho[1,2-c]furan-1,3(4H)-diones from gold(i)-catalysed 1,4-enyne acetate cycloisomerisation and oxidation or Diels–Alder reaction with maleic anhydride is described. The proposed mechanism involves Rautenstrauch rearrangement of the 1,4-enyne motif to give an insitu formed 1,3-cyclopentadiene intermediate. This is followed by 6-endo-dig cyclisation of the cyclic adduct and oxidation to give the aromatic carbocycle or Diels–Alder reaction with maleic anhydride to afford the bridged furan product.
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Schmidt, M., K. Albert, R. Brindle, C. Maichle-Mössmer, and K. Eger. "Zur Struktur von Hydroxy-5-phenyl-furanonen: Lösungs-NMR, Festkörper-13C-NMR und Röntgenstruktur im Vergleich / On the Structure of Hydroxy-5-phenyl-furanone Derivatives: NMR Spectroscopy in Solution and High Resolution Solid State 13C NMR Spectroscopy in Relation to X-Ray Crystallography." Zeitschrift für Naturforschung B 48, no. 10 (1993): 1372–80. http://dx.doi.org/10.1515/znb-1993-1011.

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The structure of (5H)-2-Amino-3-hydroxy-5-phenyl-furan-4-one (lb) was determined by NMR-spectroscopy in solution and in the solid state. The structure of its oxidation product, 3,4-Dihydro-3,3,4,4-tetrahydroxy-5-phenyl-furan-2(5H)-one (7), given in the literature as 5-Phenyl-2,3,4-(5H)-furan-trione, was determined by NMR spectroscopy and crystal structure analysis. The solid state NMR spectrum of 7 was compared to the spectrum of dehydroascorbic acid
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Dissertations / Theses on the topic "Furan Oxidation"

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Brown, Richard Charles Downie. "Furan oxidation applied to the synthesis of salinomycin." Thesis, University of Southampton, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.241243.

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Woollaston, Daniel. "Total synthesis of natural products via the oxidation of furan derivatives." Thesis, University of Oxford, 2009. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.491599.

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Oxidation of furan rings in the presence of hydroxy groups can lead to spirobutenolides. This methodology has been applied in synthetic studies towards three natural products: Pyrenolide 0 - An antileukaemic fungal metabolite. AL-(1) - An antitumor plant natural product. Sawaranospirolides - Four highly oxygenated spiroacetals isolated from the heartwood of the Sawara tree.
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Norley, Mark Colin. "Studies directed towards the synthesis of rapamycin." Thesis, University of Southampton, 1996. https://eprints.soton.ac.uk/406818/.

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Kadam, A. L. "Design & tactics for total synthesis of D2 receptor agonist quinagolide & development and application of on-water oxidation of furan in collective synthesis of bioactive natural products." Thesis(Ph.D.), CSIR-National Chemical Laboratory, 2019. http://dspace.ncl.res.in:8080/xmlui/handle/20.500.12252/5906.

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Finlay, James William. "Applications of synthesis of furan oxidations." Thesis, Queen's University Belfast, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.263395.

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Brennan, Joseph J. "Applications in synthesis of furan oxidations." Thesis, Queen's University Belfast, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.239003.

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Feng, Pingyun. "Hydroboration-oxidation of styrene, 2,3-dihydrofuran and quadricyclene dimethylester promoted by Wilkinson's catalyst /." Online version of thesis, 1991. http://hdl.handle.net/1850/10959.

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Macnaughton, Sarah. "The Aza-Bohlmann cyclisation and the synthesis of Pandanus alkaloids." Thesis, University of Oxford, 2011. http://ora.ox.ac.uk/objects/uuid:2c91155f-0c0d-47b4-b8dc-f5e32fb2a8f9.

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Bohlmann et al. reported the oxidative spirocyclisation of 2-(ω-hydroxyalkyl)furans under Clauson-Kaas conditions to furnish 1,6-dioxaspiro[4.5]dec-3-enes, thereafter termed the “Bohlmann cyclisation.” This thesis describes the development of an analogous aza-Bohlmann cyclisation. Treatment of 2-(ω-aminoalkyl)furans with m-CPBA or singlet oxygen generates hydroxy- or methoxybutenolides, respectively, which undergo spirocyclisation upon treatment with H₂SO₄ to generate [4.4]- and [4.5]-spiroaminoacetals. The axial/equatorial preferences of N-sulfonylspiroaminoacetals featuring a 3-O-isovaleryl
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Ait, Rass Hicham. "Transformation chimique du furfural en acide 2,5-furane dicarboxylique par catalyse hétérogène." Thesis, Lyon 1, 2014. http://www.theses.fr/2014LYO10198/document.

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Ces travaux de thèse portent sur la conversion par catalyse hétérogène du furfural (produit biosourcé produit, par déshydratation du xylose issu de l'hydrolyse acide de l'hémicellulose) en acide 2,5-furane dicarboxylique (FDCA, substituant potentiel de l'acide téréphtalique, monomère de polyesters et polyamides, issu du pétrole). Cette transformation a été envisagée en deux étapes catalytiques: 1) l'hydroxyméthylation du furfural en 5-hydroxyméthylfurfural (HMF) par le formaldéhyde aqueux ou le trioxane en présence d'un catalyseur acide. Les rendements maxima de 40% ont été obtenus en utilisan
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Egunlusi, Ayodeji Olatunde. "Novel tricycloundecane derivatives as potential N-methyl-Daspartate receptor and calcium channel inhibitors for neuroprotection." Thesis, University of the Western Cape, 2014. http://hdl.handle.net/11394/3904.

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>Magister Scientiae - MSc<br>This study focused on the synthesis of a series of novel tricycloundecane derivatives and evaluation of these compounds for neuroprotection using the fluorescent ratiometric calcium assay that indicates the ability of the test compounds to inhibit NMDA receptors and VGCC. The cycloaddition reaction between p-benzoquinone and monomerised dicyclopentadiene yielded tricycloundeca- 4,9-diene-3,6-dione which was used as the base structure and further derivatised. These derivatives were conjugated with benzylamine to form a series of imines and amines. A total of 10 comp
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Books on the topic "Furan Oxidation"

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Dolara, Piero, ed. TOX: lezioni di tossicologia. Firenze University Press, 2006. http://dx.doi.org/10.36253/88-8453-412-7.

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TOX is a manual aimed primarily at the Toxicology courses of the Faculty of Pharmacy and Science, that can also be profitably utilised by students following different degree courses in other Faculties (Medicine, Agriculture, Engineering)and by anyone else looking for a thorough but succinct overview of toxicological questions. TOX covers the principal sectors of general toxicology (acute and chronic toxicity, mutagenesis, teratogenesis, carcinogenesis, reproductive toxicity, oxidative damage, epidemiological methods), specialist toxicology(dietary toxicity, tobacco smoke, pesticides, N-nitroso
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Book chapters on the topic "Furan Oxidation"

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Arican, Yagmur Emre. "Furan." In Food Safety. Nobel Tip Kitabevleri, 2024. http://dx.doi.org/10.69860/nobel.9786053358787.13.

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Furan, a volatile compound with a strong etheric odor and flammability, is a crucial component in the industrial context, producing various chemicals such as pyrrole, thiophene, tetrahydrofuran, pharmaceuticals, and pesticides. It is also used as a solvent for resins in organic synthesis and is present in many foods, including carbohydrates, unsaturated fatty acids, carotenoids, vitamin C, and amino acids, due to thermal processes and high-energy radiation used in the food manufacturing industry. Furan and its derivatives are utilized in the refining of tobacco and as flavoring agents in speci
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Smith, L. H. S., S. C. Coote, and D. J. Procter. "Variation 2: Oxidation of Furan Derivatives." In Science of Synthesis Knowledge Updates KU 2010/4. Georg Thieme Verlag KG, 2010. http://dx.doi.org/10.1055/sos-sd-129-00219.

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Zoretic, P. A., M. Wang, Y. Zhang, and Z. Shen,. "Total Synthesis of d,l-Isospongiadiol." In Exercises in Synthetic Organic Chemistry. Oxford University PressOxford, 1997. http://dx.doi.org/10.1093/oso/9780198559443.003.0047.

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Abstract Discussion Points What kind of nOe would be expected to confirm the relative trans stereochemistry around the ring junctions in 5? Suggest a mechanism for the formation of the furan ring upon treatment of the epoxy-aldehyde derived from 7 with acid. What is the mechanism of the Rubottom oxidation? Further Reading For a review on manganese(lll)-based oxidative free-radical cyclisations, see: B. M. Snider, Chem. Rev.,1996, 96,339.
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Nubbemeyer, U. "Oxidation of 3,4-Dibromo-2,5-bis(phenylsulfanyl)furan." In X-Ene-X (X=F, Cl, Br, I, O, S, Se, Te, N, P), Ene-Hal, and Ene-O Compounds. Georg Thieme Verlag KG, 2008. http://dx.doi.org/10.1055/sos-sd-032-00076.

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Taber, Douglass. "Preparation of Heteroaromatics." In Organic Synthesis. Oxford University Press, 2011. http://dx.doi.org/10.1093/oso/9780199764549.003.0068.

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Masahiro Yoshida of the University of Tokushima described (Tetrahedron Lett. 2008, 49, 5021) the Pt-mediated rearrangement of alkynyl oxiranes such as 1 to the furan 2. Roman Dembinski of Oakland University reported (J. Org. Chem. 2008, 73, 5881) a related zinc-mediated rearrangement of propargyl ketones to furans. The cyclization of aryloxy ketones such as 3 to the benzofuran 4 developed (Tetrahedron Lett. 2008, 49, 6579) by Ikyon Kim of the Korea Research Institute of Chemical Technology is likely proceeding by a Friedel-Crafts mechanism. Sandro Cacchi and Giancarlo Fabrizi of Università deg
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Ito, Masumi, Shigeru Terada, Yasuko Higashino, and Yukio Koyasu. "124 Selective oxidation of 1, 3-butadiene to furan over molybdenum based catalysts." In Science and Technology in Catalysis 2002, Proceedings of the Fourth Tokyo conference on Advance Catalytic Science and Technology. Elsevier, 2003. http://dx.doi.org/10.1016/s0167-2991(03)80281-1.

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Taber, Douglass F. "C–O Natural Products: DihomoIsoF (Lee/Galano), Pyrenolide D (Gracza), Clavilactone A (Li), Psoracorylifol A (Tong), Bermudenynol (Kim), Aspercyclide C (Hirama)." In Organic Synthesis. Oxford University Press, 2017. http://dx.doi.org/10.1093/oso/9780190646165.003.0050.

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Dihomo-Isofurans, produced in vivo by oxidation of adrenic acid, are potential mark­ers of neuronal oxidative damage. Jetty Chung-Yung Lee of the University of Hong Kong and Jean-Marie Galano of Université de Montpellier I and II described (Angew. Chem. Int. Ed. 2014, 53, 6249) the cyclization of 1 to 2, opening what should be a gen­eral route to these furans.
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Moreau, C., R. Durand, C. Pourcheron, and D. Tichit. "Selective oxidation of 5-hydroxymethylfurfural to 2,5-furan-dicarboxaldehyde in the presence of titania supported vanadia catalysts." In Studies in Surface Science and Catalysis. Elsevier, 1997. http://dx.doi.org/10.1016/s0167-2991(97)80930-5.

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Taber, Douglass F. "Preparation of Heterocycles: The Boukouvalas Synthesis of (−)-Auxofuran." In Organic Synthesis. Oxford University Press, 2017. http://dx.doi.org/10.1093/oso/9780190646165.003.0065.

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Nabyl Merbouh and Robert Britton of Simon Fraser University developed (Eur. J. Org. Chem. 2013, 3219) a general route to a 2,5-disubstituted furan 3 by taking advantage of the ready α-chlorination of an aldehyde 1, followed by coupling with a ketone eno­late 2. Jérôme Waser of the Ecole Polytechnique Fédérale de Lausanne used (Angew. Chem. Int. Ed. 2013, 52, 6743) 5 to oxidize the allene 4 to the furan 6. Qian Zhang and Xihe Bi of Northeast Normal University used (Angew. Chem. Int. Ed. 2013, 52, 6953) Ag catalysis to prepare the pyrrole 9 by coupling the alkyne 7 with the isonitrile 8. Aiwen L
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Taber, Douglass F. "Heteroaromatic Construction: The Wipf Synthesis of Cycloclavine." In Organic Synthesis. Oxford University Press, 2013. http://dx.doi.org/10.1093/oso/9780199965724.003.0068.

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Wesley J. Moran of the University of Huddersfield cyclized (Tetrahedron Lett. 2011, 52, 2605) a propargylated ketone 1 with Au to give the furan 2. Shengming Ma of the Shanghai Institute of Organic Chemistry found (Synlett 2011, 931) that tri(2-furyl)phosphine catalyzed the rearrangement of cyclopropene diesters, prepared by the addition of diazomalonate to alkynes, to the corresponding alkoxy furan 4. Xihe Bi and Qian Zhang of Northeast Normal University established (Chem. Commun. 2011, 47, 809) that a simple Fe catalyst effected the condensation of 5 with 6 to give the pyrrole 7. Gianfranco
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Conference papers on the topic "Furan Oxidation"

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Op de Beeck, Marieke, Ellen Gyssels, Diederica Claeys, and Annemieke Madder. "New inducible nucleic acid cross-linking methodology based on oxidation of incorporated furan moieties: scope and limitations." In XVth Symposium on Chemistry of Nucleic Acid Components. Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, 2011. http://dx.doi.org/10.1135/css201112282.

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Carrette, L. L. G., E. Gyssels, N. Delaet, J. Loncke, and A. Madder. "Furan oxidation cross-linking: a versatile approach for the study and targeting of protein and nucleic acid interactions." In XVIth Symposium on Chemistry of Nucleic Acid Components. Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, 2014. http://dx.doi.org/10.1135/css201414178.

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Carrette, Lieselot L. G., Takashi Morii, and Annemieke Madder. "Furan Oxidation Cross-Linking: A New Approach for the Study and Targeting of Peptide/Protein and Nucleic Acid Interactions." In The Twenty-Third American and the Sixth International Peptide Symposium. Prompt Scientific Publishing, 2013. http://dx.doi.org/10.17952/23aps.2013.114.

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Garci´a-Pen˜a, Francisco, Alejandro Mun˜oz-Mozos, and Pedro Casero-Cabezo´n. "MBM (Meat and Bonemeal) Co-Gasification in IGCC Technology." In ASME Turbo Expo 2002: Power for Land, Sea, and Air. ASMEDC, 2002. http://dx.doi.org/10.1115/gt2002-30010.

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The potential use of MBM (Meat and Bone Meal) as fuel in a power plant has been recently originated by the mad cow disease, affecting not only Europe (the origin of the disease) but also other continents. MBM manufacturing companies have been forced to change their traditional ways of distribution due to the current ban of using MBM as cattle feed, therefore using a dumping site or an incinerator. To be considered as a fuel, several studies should be carried out. Preliminary characterisation of MBM showed a heating value higher than existing in coal, and a grain size acceptable to be mixed wit
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Artemenko, S., and V. Mazur. "Thermodynamic and Phase Behavior of Supercritical Water: Environmentally Significant Organic Chemical Mixtures." In ASME 2004 International Mechanical Engineering Congress and Exposition. ASMEDC, 2004. http://dx.doi.org/10.1115/imece2004-59453.

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The importance of equation of state models is fundamental to new technologies such as supercritical water oxidation for the destruction of organic pollutants. In order to be able to perform hazard and risk assessments, the parameters ofthermodynamic models are considered as information characteristics of chemicals that store the knowledge on their thermodynamic, phase and environmental behavior. Considering the extremely large number of existing chemicals, it is obvious that there is need for developing theoretically sound methods for the prompt estimation of their phase behavior in aquatic me
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Reports on the topic "Furan Oxidation"

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Allcock, Harry R., Jeffrey A. Dodge, Leon S. Van Dyke, and Charles R. Martin. Polyphosphazenes Bearing Polymerizable Pyrrole, Thiophene and Furan Side Groups: Synthesis and Chemical Oxidation. Defense Technical Information Center, 1992. http://dx.doi.org/10.21236/ada249747.

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