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Dissertations / Theses on the topic 'Furan Oxidation'

Author: Grafiati

Published: 4 June 2021

Last updated: 26 July 2025

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1

Brown, Richard Charles Downie. "Furan oxidation applied to the synthesis of salinomycin." Thesis, University of Southampton, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.241243.

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2

Woollaston, Daniel. "Total synthesis of natural products via the oxidation of furan derivatives." Thesis, University of Oxford, 2009. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.491599.

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Oxidation of furan rings in the presence of hydroxy groups can lead to spirobutenolides. This methodology has been applied in synthetic studies towards three natural products: Pyrenolide 0 - An antileukaemic fungal metabolite. AL-(1) - An antitumor plant natural product. Sawaranospirolides - Four highly oxygenated spiroacetals isolated from the heartwood of the Sawara tree.

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3

Norley, Mark Colin. "Studies directed towards the synthesis of rapamycin." Thesis, University of Southampton, 1996. https://eprints.soton.ac.uk/406818/.

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4

Kadam, A. L. "Design & tactics for total synthesis of D2 receptor agonist quinagolide & development and application of on-water oxidation of furan in collective synthesis of bioactive natural products." Thesis(Ph.D.), CSIR-National Chemical Laboratory, 2019. http://dspace.ncl.res.in:8080/xmlui/handle/20.500.12252/5906.

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5

Finlay, James William. "Applications of synthesis of furan oxidations." Thesis, Queen's University Belfast, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.263395.

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6

Brennan, Joseph J. "Applications in synthesis of furan oxidations." Thesis, Queen's University Belfast, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.239003.

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7

Feng, Pingyun. "Hydroboration-oxidation of styrene, 2,3-dihydrofuran and quadricyclene dimethylester promoted by Wilkinson's catalyst /." Online version of thesis, 1991. http://hdl.handle.net/1850/10959.

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8

Macnaughton, Sarah. "The Aza-Bohlmann cyclisation and the synthesis of Pandanus alkaloids." Thesis, University of Oxford, 2011. http://ora.ox.ac.uk/objects/uuid:2c91155f-0c0d-47b4-b8dc-f5e32fb2a8f9.

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Bohlmann et al. reported the oxidative spirocyclisation of 2-(ω-hydroxyalkyl)furans under Clauson-Kaas conditions to furnish 1,6-dioxaspiro[4.5]dec-3-enes, thereafter termed the “Bohlmann cyclisation.” This thesis describes the development of an analogous aza-Bohlmann cyclisation. Treatment of 2-(ω-aminoalkyl)furans with m-CPBA or singlet oxygen generates hydroxy- or methoxybutenolides, respectively, which undergo spirocyclisation upon treatment with H₂SO₄ to generate [4.4]- and [4.5]-spiroaminoacetals. The axial/equatorial preferences of N-sulfonylspiroaminoacetals featuring a 3-O-isovaleryl

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9

Ait, Rass Hicham. "Transformation chimique du furfural en acide 2,5-furane dicarboxylique par catalyse hétérogène." Thesis, Lyon 1, 2014. http://www.theses.fr/2014LYO10198/document.

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Ces travaux de thèse portent sur la conversion par catalyse hétérogène du furfural (produit biosourcé produit, par déshydratation du xylose issu de l'hydrolyse acide de l'hémicellulose) en acide 2,5-furane dicarboxylique (FDCA, substituant potentiel de l'acide téréphtalique, monomère de polyesters et polyamides, issu du pétrole). Cette transformation a été envisagée en deux étapes catalytiques: 1) l'hydroxyméthylation du furfural en 5-hydroxyméthylfurfural (HMF) par le formaldéhyde aqueux ou le trioxane en présence d'un catalyseur acide. Les rendements maxima de 40% ont été obtenus en utilisan

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10

Egunlusi, Ayodeji Olatunde. "Novel tricycloundecane derivatives as potential N-methyl-Daspartate receptor and calcium channel inhibitors for neuroprotection." Thesis, University of the Western Cape, 2014. http://hdl.handle.net/11394/3904.

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>Magister Scientiae - MSc<br>This study focused on the synthesis of a series of novel tricycloundecane derivatives and evaluation of these compounds for neuroprotection using the fluorescent ratiometric calcium assay that indicates the ability of the test compounds to inhibit NMDA receptors and VGCC. The cycloaddition reaction between p-benzoquinone and monomerised dicyclopentadiene yielded tricycloundeca- 4,9-diene-3,6-dione which was used as the base structure and further derivatised. These derivatives were conjugated with benzylamine to form a series of imines and amines. A total of 10 comp

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11

Ayoub, Nadim. "Synthèse et valorisation des dérivés furaniques issus de la biomasse par oxydations sélectives." Electronic Thesis or Diss., Compiègne, 2022. http://www.theses.fr/2022COMP2677.

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La biomasse fait partie des ressources renouvelables qui peuvent répondre durablement à nos besoins de production de carburants, de produits chimiques et de matériaux. En effet, la biomasse non comestible telle que la lignocellulose a attiré l'attention des chercheurs et des scientifiques au cours des dernières décennies en tant qu'alternative renouvelable. Le furfural et le 5-hydroxyméthylfurfural (HMF), dérivés de la déshydratation des pentoses et des hexoses respectivement, sont produits à plusieurs millions de tonnes par an. Ces derniers composés sont donc des molécules plateformes et repr

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12

Charles, I. "Transition metal mediated halogen atom transfer radical cyclisation in furan synthesis:chemoselective estrification and amine oxidation." Thesis, 2000. http://localhost:8080/iit/handle/2074/3583.

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13

Pawar, Amit Balkrishna. "Total Synthesis Of Palmerolide A, Dihydroconduritols And Lentiginosine." Thesis, 2012. https://etd.iisc.ac.in/handle/2005/2333.

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The thesis entitled “Total synthesis of palmerolide A, dihydroconduritols and lentiginosine” is divided into two chapters. First chapter of the thesis describes the formal total synthesis of bioactive marine macrolide palmerolide A. Palmerolide A was isolated by Baker and co-workers from an Antarctic tunicate Synoicum adareanum. Palmerolide A is a 20-membered macrolactone containing five chiral centers and seven unsaturations. Palmerolide A was found to be potent and selectively cytotoxic against human melanoma cancer cell lines and was also shown to inhibit vacuolar V-ATPase. In section

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14

Pawar, Amit Balkrishna. "Total Synthesis Of Palmerolide A, Dihydroconduritols And Lentiginosine." Thesis, 2012. http://hdl.handle.net/2005/2333.

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The thesis entitled “Total synthesis of palmerolide A, dihydroconduritols and lentiginosine” is divided into two chapters. First chapter of the thesis describes the formal total synthesis of bioactive marine macrolide palmerolide A. Palmerolide A was isolated by Baker and co-workers from an Antarctic tunicate Synoicum adareanum. Palmerolide A is a 20-membered macrolactone containing five chiral centers and seven unsaturations. Palmerolide A was found to be potent and selectively cytotoxic against human melanoma cancer cell lines and was also shown to inhibit vacuolar V-ATPase. In section A

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15

Procko, Kristen Jean. "Functionalization of C-aryl glycals and studies toward the total synthesis of 5-hydroxyaloin A." Thesis, 2009. http://hdl.handle.net/2152/28464.

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In the context of ongoing efforts toward C-aryl glycoside synthesis, a recently developed approach to form C-aryl glycals from 2-deoxysugar lactones was expanded to form novel substrates. This approach has been applied to the synthesis of various furyl glycals, allowing access to C-aryl glycals via a benzyne furan (4+2) cycloaddition methodology. The hydroboration-oxidation of said C-aryl glycals has allowed access to C(2)-oxygenated C-aryl glycosides via the benzyne cycloaddition approach. An approach to the total synthesis of 5-hydoxyaloin A is detailed, in which regioselective benzyne fura

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16

Harn, Piin-Jye, and 韓品杰. "Oxidation of 3-Substituted Furans with Bromine." Thesis, 1995. http://ndltd.ncl.edu.tw/handle/56086114504368500774.

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碩士<br>國立交通大學<br>應用化學系<br>83<br>3-夫喃甲醇類化合物,在丙酮與水之溶液系統下,加入溴會產生氧化重排之2-取代-3-夫喃醛類化合物.此種新反應可以將夫喃第三位置的取代基 ,轉移到夫喃的第二位置,如此就可以引進平常不易在夫喃第二位置出現的取代基.若在夫喃2位置引進取代基,即使用2-烷基-3-夫喃甲醇類化合,同樣在丙酮與水之系統下,加溴也會產生氧化重排之2-烷基-3-夫喃酮類化合物,但在其酮基之α位置有溴取代發生.若把醇類的OH基換成胺,即使用3- 夫喃甲胺類化合物,在同樣條件之下,會產生3-比各醛類化物,這是一種從夫喃直接合成比各類化合物的新穎方法. Reaction of 3-furylcarbinols with bromine in acetone-waterystem gave the 2-substituted-3-furylaldehyde. Reaction of 2-alkyl-3- furylcarbinols with bromin

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17

XIE, HUAN-JIA, and 謝煥佳. "Oxidation of cyclopenladiene derivatives and furans with PCC,and its synthetic applications." Thesis, 1988. http://ndltd.ncl.edu.tw/handle/72900619763521543234.

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18

Lin, Zhu-Qiang, and 林助強. "Oxidation of cyclopentadiene derivatives and furans with PCC, and its synthetic applications." Thesis, 1988. http://ndltd.ncl.edu.tw/handle/71182763486756890880.

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19

Chen, Yu-Chun, and 陳宇鈞. "Hypervalent Iodine(III)-Induced Domino Oxidative Cyclization for the Synthesis of Cyclopenta[b]furans." Thesis, 2017. http://ndltd.ncl.edu.tw/handle/h946y4.

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碩士<br>國立彰化師範大學<br>化學系<br>105<br>The synthesis of heterocyclic compounds has been an important issue in organic synthesis. Organic chemists tend to use mild conditions, more environmentally friendly reagents, and shorter reaction pathways to obtain heterocyclic compounds. Many natural substances and drugs contain a heterocyclic structure in which cyclopenta[b]furan can bind to a G-protein coupled receptor in monocyte chemoattractant protein-1 (MCP-1), allowing monocytes or Macrophages can not come to the immune response, it can alleviate some autoimmune diseases, such as: rheumatoid arthritis,

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