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Journal articles on the topic 'Pentacyanoferrate'

Author: Grafiati

Published: 4 June 2021

Last updated: 26 July 2025

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1

Shi, Cheng-Hsiang, Shiao-Tsun Wang, Shiao-Yun Yang, Andrew Yeh, and Hsien-Ju Tien. "Sydnone Complexes of Pentacyanoferrate(II)." Journal of the Chinese Chemical Society 45, no. 1 (1998): 77–81. http://dx.doi.org/10.1002/jccs.199800013.

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2

Bratskaya, S. Yu, Yu O. Privar, O. V. Korjakova, A. V. Mechaev, and A. V. Pestov. "Pentacyanoferrate(II) complexes with chitosan." Polymer Engineering & Science 54, no. 10 (2013): 2392–97. http://dx.doi.org/10.1002/pen.23787.

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3

Fuller, MW, KMF Lebrocq, E. Leslie, and IR Wilson. "The Photolysis of Aqueous-Solutions of Potassium Hexacyanoferrate(III)." Australian Journal of Chemistry 39, no. 9 (1986): 1411. http://dx.doi.org/10.1071/ch9861411.

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The photolysis of aqueous solutions of potassium hexacyanoferrate(III) at 254 and 366 nm forms aqua- or hydroxo-pentacyanoferrate(III) in both acidic and alkaline solutions, with quantum yields between 0.02 and 0.06. Subsequent thermal reactions form the decacyanodiferrate(III) and/or decacyanodiferrate(III,II) species, especially in weakly acidic solutions, and, in alkaline solutions, may precipitate hydrated iron(III) oxides.

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4

Tetianec, Lidija, Marius Dagys, Juozas Kulys, Arturas Ziemys, and Rolandas Meskys. "Study of the reactivity of quinohemoprotein alcohol dehydrogenase with heterocycle-pentacyanoferrate(III) complexes and the electron transfer path calculations." Open Life Sciences 2, no. 4 (2007): 502–17. http://dx.doi.org/10.2478/s11535-007-0033-y.

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AbstractThe reactivity of alcohol dehydrogenase IIG (ADH IIG) from Pseudomonas putida HK5 with new heterocycle-pentacyanoferrate(III) complexes and hexacyanoferrate(III) was determined at pH 7.2. The pentacyanoferrate(III) complexes contained imidazole, pyrazole, pyridine, their derivatives and 2-aminobenzothiazole as the sixth ligand. The largest reactivity of the complexes with ADH IIG was estimated for the complex containing pyridine. An apparent bimolecular constant (k ox) for this complex was 8.7 × 105 M−1s−1. The lowest value of k ox was estimated for the complex with benzotriazole (k ox

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5

Macartney, Donal Hugh, and Lauren Jean Warrack. "Ligand substitution reactions of pentacyanoferrate(II) complexes with N-heterocyclic cations in aqueous solution." Canadian Journal of Chemistry 67, no. 11 (1989): 1774–79. http://dx.doi.org/10.1139/v89-274.

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Kinetic and spectroscopic studies have been carried out in aqueous solution on the formation (from Fe(CN)5OH23−) and dissociation of pentacyanoferrate(II) complexes containing 1-(4-pyridyl)pyridinium and the neutral, protonated, and N-methylated forms of 4,4′-bipyridine (BPY), 1,2-bis(4-pyridyl)ethane (BPA), and trans-1,2-bis(4-pyridyl)ethylene (BPE). The pH dependences of the formation kinetics have been analyzed in terms of the specific rate and acid dissociation constants for these ligands. The rate constants (25.0 °C, I = 0.10 M) for the formation of the dinuclear complexes (NC)5FeLFe(CN)5

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6

Lopez, Vicenta, Javier Catalan, Rosa Ma Claramunt, Concepcion Lopez, Eduardo Cayon, and Jose Elguero. "On the relationship between thermodynamic pKa's of azoles and the oxidation potentials of their pentacyanoferrate(II) complexes." Canadian Journal of Chemistry 68, no. 6 (1990): 958–59. http://dx.doi.org/10.1139/v90-149.

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The comparison between thermodynamic pKa values and oxidation potentials of the pentacyanoferrate(II) complexes of a series of azoles shows the existence of two parallel lines: one for pyrazoles and another one for benzazoles. Using the equation corresponding to the second one, the pKa value of 1-methylbenzotriazole (2.49) can be estimated from the E1/2 value of its complex. Keywords: azole basicity, oxidation potentials, pyrazoles, benzotriazoles.

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7

Cvijanović, D., V. Damjanović, I. Picek, and B. Foretić. "Spectroscopic Studies of Methimazole Reactivity toward the Aquapentacyanoferrate (II) Ion in Aqueous Solutions." Spectroscopy: An International Journal 27 (2012): 509–14. http://dx.doi.org/10.1155/2012/136058.

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Methimazole (2-mercapto-1-methylimidazole, MMI) and its pentacyanoferrate (II) complex have been characterized by means of UV/Vis, Raman, and NMR spectroscopy. The reaction of MMI with aquapentacyanoferrate (II), [Fe(CN)5(H2O)]3−, in buffered aqueous solutions yielded the [Fe(CN)5(MMI)]3−complex. It was found that only thione tautomer of MMI coordinates to the iron (II). The exceptionally stabile and inert complex was produced.

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8

Parwate, D. V., and A. N. Garg. "Unusual Quadrupole Splitting in D i- and Trialkylamine Substituted Pentacyanoferrate(II) Complexes." Zeitschrift für Naturforschung B 40, no. 11 (1985): 1495–99. http://dx.doi.org/10.1515/znb-1985-1113.

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A series of pentacyanoferrate complexes, Na3[Fe(CN)5L] ·nH2O, where L = (CH3)2NH, (C2H5)2NH, (C2H5)3N, (C3H7)2NH, (C4H9)2NH, (C4H9)3N and (C6H5)2NH were studied by Mössbauer and infrared spectroscopy. All the complexes exhibited two line spectra with ⊿ EQ = 0.73-1.92 mms-1 and δ = −0.04−0.49 mms-1 (w.r.t. SNP) and can be divided into two groups with well defined parameters. Partial isomer shift and partial quadrupole splitting values were correlated with bonding characteristics.

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9

Funai, Irene A., Miguel A. Blesa, and José A. Olabe. "Hydrazine autoxidation in solution: catalysis by pentacyanoferrate(II)." Polyhedron 8, no. 4 (1989): 419–26. http://dx.doi.org/10.1016/s0277-5387(00)80736-6.

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10

Macartney,, D. H. "Properties and Reactions of Substituted Pentacyanoferrate (II) Complexes." Reviews in Inorganic Chemistry 9, no. 2-3 (1988): 101–52. http://dx.doi.org/10.1515/revic.1988.9.2-3.101.

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11

Vasconcellos, Luiz C. G., Keila S. M. Ferreira, Lidia M. A. Plicas, et al. "Properties of triethylphosphite complexes of pentacyanoferrate(II) and (III). Cyanide photolabilization in a pentacyanoferrate(II) complex with a monodentate ligand." Inorganica Chimica Acta 214, no. 1-2 (1993): 23–28. http://dx.doi.org/10.1016/s0020-1693(00)87521-0.

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12

Li, Jian-Rong, Li-Zhen Cai, Guo-Cong Guo, Xian-He Bu та Jin-Shun Huang. "Pentacyanoferrate(III)-μ-cyano-[triaquatetrakis(dimethylformamide)gadolinium(III)] monohydrate". Acta Crystallographica Section E Structure Reports Online 60, № 3 (2004): m259—m261. http://dx.doi.org/10.1107/s160053680400193x.

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13

Lin, Ching-Lung, Kenneth Hung, Andrew Yeh, Hsiu-Tun Tsen, and Chan-Cheng Su. "4,4‘-Dipyridylamine-Bridged Binuclear Complexes of Pentacyanoferrate and Pentaammineruthenium." Inorganic Chemistry 38, no. 2 (1999): 411–14. http://dx.doi.org/10.1021/ic980087d.

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14

Chen, Chang-nan, Ming-chu Wu, Andrew Yeh, and Thomas Y. R. Tsai. "4- and 3-Hydroxypyridine complexes of pentacyanoferrate(II, III)." Inorganica Chimica Acta 267, no. 1 (1998): 81–86. http://dx.doi.org/10.1016/s0020-1693(97)05557-6.

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15

Li, Jian-Rong, Li-Zhen Cai, Ru-Qiang Zou та ін. "Pentacyanoferrate(III)-μ-cyano-triaquatetrakis(dimethylformamide)europium(III) hydrate". Acta Crystallographica Section E Structure Reports Online 58, № 12 (2002): m686—m687. http://dx.doi.org/10.1107/s1600536802019578.

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16

Iha, Neyde Yukie Murakami, Henrique Eisi Toma, and Jailson Farias De Lima. "Ligand field photochemistry of substitutionally inert pentacyanoferrate(II) complexes." Polyhedron 7, no. 18 (1988): 1687–91. http://dx.doi.org/10.1016/s0277-5387(00)80399-x.

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17

Charng-Sheng, Lin, Andrew Yeh, Liu Tsun-Yang, Shin Kwan Keh, Derek J. Hodgson, and Tien Hsien-Ju. "The 3-(3′-pyridyl)sydnone complex of pentacyanoferrate(II)." Inorganica Chimica Acta 192, no. 1 (1992): 81–86. http://dx.doi.org/10.1016/s0020-1693(00)83176-x.

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18

Coelho, A. L., I. S. Moreira, J. H. de Araujo, and M. A. B. de Araujo. "Study of substituted pentacyanoferrate /II/ complexes by Mössbauer spectroscopy." Journal of Radioanalytical and Nuclear Chemistry 136, no. 4 (1989): 299–309. http://dx.doi.org/10.1007/bf02163975.

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19

Francicarlos, V. Cardoso, B. de Limaa Joacy, W.B. Bezerraa Cícero, Kayab Savaş, de S. Dantas Deyse, and F. de Fariasc Robson. "Novel Pentacyanoferrate Complexes with Dinitrile Ligands (Malononitrile and Succinonitrile)." Pharmaceutical and Chemical Journal 5, no. 2 (2018): 45–51. https://doi.org/10.5281/zenodo.13899625.

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In the presente work the complexes Na<sub>3</sub>[Fe(CN)<sub>5</sub>(NC(CH<sub>2</sub>)<sub>n</sub>CN)] (n = 1 = malononitrile and n=  2 = succinonitrile) have been isolated and characterized by cyclic voltammetry, Uv-vis and FTIR spectroscopies. A metal to ligand charge-transfer transition was observed only for Na<sub>3</sub>[Fe(CN)<sub>5</sub>(NCCH<sub>2</sub>CN)] complexe (316 nm, 3,57x10<sup>3</sup> L mol<sup>-1</sup>cm<sup>-1</sup>). The succinonitrile complex of pentacyanoferrate(II) exhibits a band maximum at 370 nm, which was assigned to ligand field transition. The half wave pote

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20

Parwate, D. V., and A. N. Garg. "Synthesis and structural investigations of some alkylamine pentacyanoferrate(II) complexes." Polyhedron 5, no. 4 (1986): 999–1005. http://dx.doi.org/10.1016/s0277-5387(00)80142-4.

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21

Chen, Mei-Ling, and Andrew Yeh. "Acid Catalyzed Dissociation of 4-Aminopyridine Complex of Pentacyanoferrate (II)." Journal of the Chinese Chemical Society 48, no. 5 (2001): 849–53. http://dx.doi.org/10.1002/jccs.200100122.

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22

ISHIBASHI, Kenji, Seiya TSUJIMURA, and Kenji KANO. "Pentacyanoferrate and Bilirubin Oxidase-bound Polymer for Oxygen Reduction Bio-cathode." Electrochemistry 76, no. 8 (2008): 594–96. http://dx.doi.org/10.5796/electrochemistry.76.594.

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23

Huang, Hung Yi, Wen Jang Chen, Chang Chau Yang, and Andrew Yeh. "4- and 3-Cyanopyridine-bridged binuclear complexes of pentacyanoferrate and pentaammineruthenium." Inorganic Chemistry 30, no. 8 (1991): 1862–68. http://dx.doi.org/10.1021/ic00008a034.

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24

Chen, Ming Hung, Sheena Lee, Scott Liu, and Andrew Yeh. "Kinetic Studies of the Reactions of Pentacyanoferrate(II) Complexes with Peroxydisulfate." Inorganic Chemistry 35, no. 9 (1996): 2627–29. http://dx.doi.org/10.1021/ic9505920.

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25

ALSHEHRI,, SAAD, and JOHN BURGESS,. "Salt Effects on Reactivity for Substitution Reactions of Pentacyanoferrate(II) Complexes." BioInorganic Reaction Mechanisms 5, no. 1 (2003): 59–64. http://dx.doi.org/10.1515/irm.2003.5.1.59.

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26

Lanjewar, R. B., S. Kawata, S. Kitagawa, and M. Katada. "Mössbauer spectroscopic studies of thermal decomposition of substituted pentacyanoferrate(II) complexes." Journal of thermal analysis 50, no. 3 (1997): 375–91. http://dx.doi.org/10.1007/bf01980498.

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27

Kamaluddin, Mala Nath, and Sushama W. Deopujari. "Chemical evolution of dehydrogenases: Amino acid pentacyanoferrate (II) as possible intermediates." Origins of Life and Evolution of the Biosphere 19, no. 2 (1989): 119–32. http://dx.doi.org/10.1007/bf01808146.

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28

Kamaluddin, Mala Nath, and Sushama W. Deopujari. "Chemical evolution of peroxidase — amino acid pentacyanoferrate (II) complexes as model." Origins of Life and Evolution of the Biosphere 18, no. 3 (1988): 267–80. http://dx.doi.org/10.1007/bf01804673.

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29

Bratskaya, Svetlana Yu, Veniamin V. Zheleznov, Yuliya O. Privar, Alexandr V. Mehaev, and Alexandr V. Pestov. "Cesium uptake by pentacyanoferrate(II) complexes with O-containing derivatives of chitosan." Separation Science and Technology 51, no. 4 (2015): 594–600. http://dx.doi.org/10.1080/01496395.2015.1119844.

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30

Tomaxy, Henrique E., and Americo T. Meenochite. "Analytical Determination of Methionine by Complex Formation with the Pentacyanoferrate(II) Ion." Analytical Letters 22, no. 9 (1989): 2105–14. http://dx.doi.org/10.1080/00032718908051240.

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31

Kulys, J., L. Tetianec, and A. Ziemys. "Probing Aspergillus niger glucose oxidase with pentacyanoferrate(III) aza- and thia-complexes." Journal of Inorganic Biochemistry 100, no. 10 (2006): 1614–22. http://dx.doi.org/10.1016/j.jinorgbio.2006.05.017.

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32

Stochel, Graż;yna. "High-pressure mechanistic studies on thermal and photochemical reactions of pentacyanoferrate complexes." Coordination Chemistry Reviews 114, no. 2 (1992): 269–95. http://dx.doi.org/10.1016/0010-8545(92)85005-b.

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33

Tsaur, Grace, Ming-Chu Wu, and Andrew Yen. "Mixed Valence Chemistry of Pyrimidine Bridged Binuclear Complex of Pentacyanoferrate and Pentaammineruthenium." Journal of the Chinese Chemical Society 41, no. 4 (1994): 431–39. http://dx.doi.org/10.1002/jccs.199400057.

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34

Lin, Lu-Ming, Ming-Huei Lien, and Andrew Yeh. "Kinetic studies of the reactions of pentacyanoferrate(III) complexes withL-ascorbic acid." International Journal of Chemical Kinetics 37, no. 3 (2005): 126–33. http://dx.doi.org/10.1002/kin.20052.

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35

Lima, Jailson Farias De, and Neyde Yukie Murakami Iha. "Wavelength dependence and solvent effects on the ligand field photochemistry: the ring closure process in the excited [Fe(CN)5(tn)]3− complex." Canadian Journal of Chemistry 74, no. 4 (1996): 476–80. http://dx.doi.org/10.1139/v96-052.

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The solvent composition and wavelength effects on the quantum yield of the photoinduced ring closure process of the [Fe(CN)5(tn)]3− complex (tn = 1,3-diaminopropane) were investigated. The reactivity was shown to be controlled by the macroscopic properties of water–glycerol mixtures. A sharp decrease in quantum yields with increasing medium viscosity was observed for all the irradiation wavelengths employed (313, 334, 365, 404, and 434 nm). The observed quantum yields ranged from 0.24 (λirr = 313 nm, 66.48 wt.% of acetonitrile) to 0.010 (λirr = 404 or 434 nm, 61.85 wt.% of glycerol). The overa

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36

Tejera, Ignacio, Amalia Rodriguez, Francisco Sánchez, María Luisa Moyá, and John Burgess. "Substitution reactions at pentacyanoferrate(II) complexes: linear free-energy relationships in mixed solvents." J. Chem. Soc., Faraday Trans. 87, no. 16 (1991): 2573–77. http://dx.doi.org/10.1039/ft9918702573.

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37

Hung, C. H., H. Y. Huang, J. Y. Liao, and A. Yeh. "Characterization of pentacyanoferrate(II) and -(III) complexes of adenosine and related aminopyridine ligands." Inorganic Chemistry 29, no. 16 (1990): 2940–44. http://dx.doi.org/10.1021/ic00341a017.

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38

Warner, L. William, M. Fazlul Hoq, Terry K. Myser, Wayne W. Henderson, and Rex E. Shepherd. "Influence of closed-shell cations on the LMCT transition of pentacyanoferrate(III) complexes." Inorganic Chemistry 25, no. 11 (1986): 1911–14. http://dx.doi.org/10.1021/ic00231a041.

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39

Borges, Simone da S. S., Augusto L. Coelho, and Icaro S. Moreira. "Spectroscopic and substitution kinetic studies of pentacyanoferrate(II) complexes with sulphur heterocyclic ligands." Polyhedron 13, no. 6-7 (1994): 1015–22. http://dx.doi.org/10.1016/s0277-5387(00)83025-9.

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40

Toma, H. "Analytical determination of dimethyl sulphoxide by complex formation with the pentacyanoferrate(II) ion." Talanta 35, no. 4 (1988): 323–25. http://dx.doi.org/10.1016/0039-9140(88)80096-1.

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41

Jannuzzi, Sergio Augusto Venturinelli, Bianca Martins, Maria Isabel Felisberti, and André Luiz Barboza Formiga. "Supramolecular Interactions between Inorganic and Organic Blocks of Pentacyanoferrate/Poly(4-vinylpyridine) Hybrid Metallopolymer." Journal of Physical Chemistry B 116, no. 51 (2012): 14933–42. http://dx.doi.org/10.1021/jp308583a.

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42

Choi, Young-Bong, Won-Yong Jeon, and Hyug-Han Kim. "The Coordination of Pyridyl-N to Pentacyanoferrate for the Electrochemical Detecting Small Organic Molecules." Bulletin of the Korean Chemical Society 34, no. 2 (2013): 595–99. http://dx.doi.org/10.5012/bkcs.2013.34.2.595.

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43

Sabo, Erin M., Rex E. Shepherd, Melinda S. Rau, and Michael G. Elliott. "Pentacyanoferrate(II/III) complexes of 2-substituted imidazoles and imidazolates (R = CH3, CHO, CO2-)." Inorganic Chemistry 26, no. 17 (1987): 2897–907. http://dx.doi.org/10.1021/ic00264a037.

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44

Palaniappan, V., R. M. Singru, and U. C. Agarwala. "Anionic bridging ligands: thiocyanato- and selenocyanato-bridged pentacyanoferrate dimers and their mixed-valence properties." Inorganic Chemistry 27, no. 1 (1988): 181–87. http://dx.doi.org/10.1021/ic00274a037.

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45

Baer, Andrew J., та Donal H. Macartney. "α- and β-Cyclodextrin Rotaxanes of μ-Bis(4-pyridyl)bis[pentacyanoferrate(II)] Complexes". Inorganic Chemistry 39, № 7 (2000): 1410–17. http://dx.doi.org/10.1021/ic990502h.

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46

Luiz, Juciane B., G. Jeffery Leigh, and Fábio S. Nunes. "2-Mercaptobenzoxazole pentacyanoferrate(II/III) complexes—kinetics of formation, substitution and the thermodynamic cycle." Polyhedron 21, no. 21 (2002): 2137–42. http://dx.doi.org/10.1016/s0277-5387(02)01178-6.

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47

Ilkowska, Elwira, Krzysztof Lewiński, Rudi van Eldik, and Grażyna Stochel. "Kinetic, structural and electrostatic aspects of the reduction of pentacyanoferrate(III) complexes by myoglobin." JBIC Journal of Biological Inorganic Chemistry 4, no. 3 (1999): 302–10. http://dx.doi.org/10.1007/s007750050316.

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48

Nieh, Chi-Hua, Seiya Tsujimura, Osamu Shirai, and Kenji Kano. "Amperometric biosensor based on reductive H2O2 detection using pentacyanoferrate-bound polymer for creatinine determination." Analytica Chimica Acta 767 (March 2013): 128–33. http://dx.doi.org/10.1016/j.aca.2012.12.052.

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49

Burger, Nicoletta, and Vladimira Hankonyi. "Spectrophotometric studies, synthesis and properties of pentacyanoferrate(II) complexes with bis-quaternary pyridinium aldoximes." Polyhedron 5, no. 3 (1986): 663–65. http://dx.doi.org/10.1016/s0277-5387(00)84416-2.

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50

Burger, Nicoletta, Vladimira Hankonyi, and Zlata Smerić. "A new cyano-bridged binuclear complex of pyridine-2-aldoxime with pentacyanoferrate(II) ions." Inorganica Chimica Acta 165, no. 1 (1989): 83–85. http://dx.doi.org/10.1016/s0020-1693(00)83404-0.

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